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Detection of a new carbon-chain molecule, CCO

A new carbon-chain molecule, CCO 3Sigma(-), has been detected in the cold dark molecular cloud TMC-1. The excitation temperature and the column density of CCO are, respectively, about 6 K and about 6 x 10 to the 11th/sq cm. This column density corresponds to a fractional abundance relative to H2 of about 6 x 10 to the -11th. This value is two orders of magnitude less than the abundance of the related carbon-chain molecule CCS, and about half that of C3O. The formation mechanism for CCO is discussed.

Ohishi, Masatoshi↗

Recent observations of interstellar molecules - Detection of CCO and a limit on H2C3O

In order to test gas-phase reaction schemes for the production of small oxides of carbon in cold, dense interstellar clouds, we have searched for the radical CCO and for propadienone (H2C3O) in Taurus Molecular Cloud 1, a nearby cloud which exhibits a rich organic chemistry. The radical CCO has been detected with a fractional abundance some two orders of magnitude less than that of CCS, about one order of magnitude less than that of H2CCO, and slightly less than that of C3O. An upper limit has been obtained on the abundance of propadienone which is slightly less than that of its isomer propynal (HC2CHO).

Brown, R. D.↗

Stellar evolution at high mass with convective core overshooting

The transition from stellar evolution models with no convective core overshooting (CCO) at all to models in which homogeneous mixing due to CCO reaches far beyond the formal convective core boundary is systematically explored. Overshooting is parameterized in terms of the ratio d/H(p), where d is the distance of convective overshoot beyond the formal convective core boundary and H(p) is the local pressure scale height. It is concluded that CCO in very massive main sequence stars produces a great expansion of the stellar envelope if d/H(p) is large but not excessively large. CCO does not entirely suppress convective instability above the overshoot zone in the envelopes of main sequence stars more massive than about 15 solar masses. A general comparison of theoretically constructed isochrones for young stars with observed main sequence turnups indicates that the observed turnups are longer, brighter, and cooler at the tip than those expected on thfe basis of standard evolutionary theory.

Stothers, R. B.↗

Discovery of a 105-ms X-ray Pulsar in Kesteven-79: On the Nature of Compact Central Objects in Supernova Remnants

We report the discovery of 105-ms X-ray pulsations from the compact central object (CCO) in the supernova remnant \snr\ using data acquired with the {\it Newton X-Ray Multi-Mirror Mission). Using two observations of the pulsar taken 6-days apart we derive an upper limit on its spin-down rate of $\dot P < 9 \times 10"{-14}$-s-~$~{-l)$,a nd find no evidence for binary orbital motion. The implied energy loss rate is $\dot E < 3 \times 10A{36)$-ergs-s$A{-1)$, polar magnetic field strength is $B-{\rm p) < 3 \times 10A{12)$-G, and spin-down age is $\tau > 18.5$-kyr. The latter exceeds the remnant's estimated age, suggesting that the pulsar was born spinning near its current period. The X-ray spectrum of \psr\ is best characterized as a blackbody of temperature $kT {BB) =, 0.43\pm0.02$ keV, radius $R-{BB) \approx 1.3$-km, and $~I{\rm bol) = 5.2 \times 10A{33)$ ergs-sSA{-1)$ at $d = 7.1$-kpc. The sinusoidal light curve is modulated with a pulsed fraction of $>45\%$, suggestive of a small hot spot on the surface of the rotating neutron star. The lack of a discernible pulsar wind nebula is consistent with an interpretation of \psr\ as a rotation-powered pulsar whose spin-down luminosity falls below the empirical threshold for generating bright wind nebulae, $\dot E-{\rm c) = 4 \times 10A{36)$-ergs-sSA{-I)$. The age discrepancy suggests that its $\dot E$ has always been below $\dot E c$, perhaps a distinguishing property of the CCOs. Alternatively, the X-ray spectrum of \psr\ suggests a low-luminosity AXP, but the weak inferred $B-{\rm p)$ field is incompatible with a magnetar theory of its X-ray luminosity. The ordinary spin parameters discovered from \psr\ highlight the inability of existing theories to explain the high luminosities and temperatures of CCO thermal X-ray spectra.

Gotthelf, E. V.↗

Charge-coupled device (CCD) television camera for NASA's Galileo mission to Jupiter

The CCD detector under construction for use in the slow-scan television camera for the NASA Galileo Jupiter orbiter to be launched in 1985 is presented. The science objectives and the design constraints imposed by the earth telemetry link, platform residual motion, and the Jovian radiation environment are discussed. Camera optics are inherited from Voyager; filter wavelengths are chosen to enable discrimination of Galilean-satellite surface chemical composition. The CCO design, an 800 by 800-element 'virtual-phase' solid-state silicon image-sensor array with supporting electronics, is described with detailed discussion of the thermally generated dark current, quantum efficiency, signal-to-noise ratio, and resolution. Tests of the effect of ionizing radiation were performed and are analyzed statistically. An imaging mode using a 2-1/3-sec frame time and on-chip summation of the signal in 2 x 2 blocks of adjacent pixels is designed to limit the effects of the most extreme Jovian radiation. Smearing due to spacecraft/target relative velocity and platform instability will be corrected for via an algorithm maximizing spacial resolution at a given signal-to-noise level. The camera is expected to produce 40,000 images of Jupiter and its satellites during the 20-month mission.

Klaasen, K. P.↗

Comets and the origins and evolution of life; Proceedings of the Conference, Univ. of Wisconsin, Eau Claire, Sept. 30-Oct. 2, 1991

Papers are presented on comets and the formation of biochemical compounds on the primitive earth; the cometary origin of carbon, nitrogen, and water on the earth; comets as a possible source of prebiotic molecules; comet impacts and chemical evolution on the bombarded earth; and cometary supply of terrestrial organics (lessons from the K/T and the present epoch). Other papers are on a computational study of radiation chemical processing in comet nuclei, the origin of the polycyclic aromatic hydrocarbons in meteorites, the fate of organic matter during planetary accretion (preliminary studies of the organic chemistry of experimentally shocked Murchison meteorite), recent observations of interstellar molecules (detection of CCO and a limit on H2C3O), terrestrial and extraterrestrial sources of molecular monochirality, and dark matter in the solar system (hydrogen cyanide polymers).

Thomas, Paul J.↗

Organic molecules in the gas phase of dense interstellar clouds

Since a previous Committee on Space Research (COSPAR) review on this subject, the number of molecular species identified by astronomers in dense interstellar clouds or in the envelopes expelled by evolved stars has grown from about eighty to approximately one hundred. Recent detections in stellar envelopes include the radical CP, the second phosphorus-containing astronomical molecule; SiN, the first astronomical molecule with a Si-N bond; and the HCCN radical. In the dense interstellar clouds recent detections or verifications of previous possible identifications include the H3O(+) ion, which is a critical intermediary in the production of H2O and O2; the CCO radical, which is isoelectronic with HCCN; the SO(+) ion, which appears to be diagnostic of shock chemistry; two new isomers of cyanoacetylene, HCCNC and CCCNH; and the two cumulenes H2C3 and H2C4. Some recent work is also described on the mapping of interstellar clouds in multiple molecular transitions in order to separate variations in chemical abundance from gradients in physical parameters.

Irvine, W. M.↗

Computed Minimum Energy Pathway for Isomerization in Ketene

A minimum energy pathway for interchange of the CH groups in ketene via a C2v structure has been obtained using complete active space self consistent field (CASSCF) derivative methods with a polarized valence double zeta basis set to define the reaction pathway followed by multi-reference internally contracted configuration interaction (ICCI) calculations with a [3s3p2d/3s2p] basis set to determine the energetics. Qualitatively, the C2v structure is found to be a shallow minimum on the potential energy surface separated from ketene by a small barrier (0.2 kcal/mol), a second minimum, and a larger barrier (3.0 kcal/mol). The minimum energy pathway leading from the C2v minimum to ketene starts by simultaneous rotation of the farther CH group out of the plane and away from the oxygen followed by increase of the CCO angle and subsequent 1,2-migration of the H of the nearer CH group toward the carbon of the farther CH group.

Walch, Stephen P.↗

Developing and Testing a Common Space Systems Ontology using the Ontological Modeling Language

This paper describes the development and testing of the initial version of a common space systems ontology (CoSSO) for use by the Advanced Concepts Office (ACO) at NASA's Marshall Space Flight Center. The ontology provides a shared conceptualization of concepts of interest to the ACO for modeling aerospace systems concepts in a pre-phase A context to aid with the transition to a more model-based paradigm. The ontological concepts and relations, as well as the anticipated use cases, were developed through interactions with the relevant subject matter experts at the ACO and implemented in the Ontological Modeling Language (OML). The ontology builds on the Basic Formal Ontology (BFO) and the Common Core Ontologies (CCO). While most of the ontology is still in the initial stages, an Environmental Control and Life Support System (ECLSS) ontology is being built on top of the main CoSSO and heavily developed as a proof of concept. The ECLSS ontology is designed with different use cases in mind, namely predicting and diagnosing errors in ECLS systems on long-duration missions, with a focus on the Four-Bed CO$_2$ carbon dioxide scrubber currently on board the ISS. The ECLSS ontology is being developed in a similar manner to the CoSSO, and designed to be compatible with it. The current state of both ontologies is presented and discussed, along with plans for future development and testing.

Conceptual Design↗