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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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Passivated Contacts for Direct Wafer Product (Final Technical Report)

This TCF project developed a thin-oxide (SiO 2 )/polycrystalline silicon (poly-Si) passivated contact solar cell on CubicPV's (formally 1366 Technologies, Inc.) Direct Wafer® Product (DWP) kerfless wafers. The project used two NREL-developed technologies described in U.S. Patent No. 9,911,873, Hydrogenation of Passivated Contacts and U.S. Patent Application Serial No. 15/890,172, Doped Passivated Contacts . The project was motivated by a potential higher efficiency cell (compared to a PERC cell) using passivated contacts on the ultra-low cost kerfless wafers grown using the Direct Wafer process. The hope was to accelerate market adoption of the cell and wafer by delivering the lowest LCOE in the PV industry. The project tested both n-type and p-type SiO 2 /poly-Si passivated contacts grown by thermal oxidation and plasma enhanced chemical vapor deposition (PECVD) of the poly-Si layer on DWP with varying wafer resistivities. Both deposition techniques are industry standards and thus economically viable methods for commercializing the contacts. The results indicated that both n-type and p-type poly-Si passivated contacts can be formed on polycrystalline DWP wafers, but implied open-circuit voltages (i Voc ) were limited to below 0.65 mV (compared with ~ 730 mV on n-Cz wafers). Diffusion of H to the Si/SiO 2 /poly-Si interface was key to obtaining high i Voc values. In this study, H was diffused from a high-temperature SiN x layer deposited over the poly-Si layer during a high-temperature firing step, similar to one used for screen printed metals. The study concluded that poly-Si passivated contacts on DWP wafers passivated the surface of the wafers as well as PERC passivated surfaces, which use a less expensive dielectric layer stack. The project showed that Direct Wafer Product wafers grown by CubicPV could produce high i Voc values (~0.647 mV), which could produce a cell over 20% efficient with proper processing and metallization. These cells, though not economically viable in 2024 as a stand-alone cell, could be integrated with a wide-bandgap top solar cell to form a two-junction tandem cell that could be viable under certain circumstances. This is because the bottom cell of a 30%, two-terminal tandem only needs to be a 20% cell under one-sun conditions. Thus, the DWP could be an ideal low-cost wafer for tandems. The project also revealed that a TOPCon type cell could be formed on a p-type DWP wafer using a P-diffused emitter and a p-type poly-Si contact. In fact, the p-type version of the poly-Si contact out-performed the n-type version for a variety of wafer resistivities, from highly doped to lowly doped. This curiosity requires more work to understand because on Cz wafers, the n-type poly-Si contact is of much higher quality than the p-type version.

14 SOLAR ENERGY↗

A Comparison of the Automated Meteorological Profiling System High Resolution Flight Element to the Kennedy Space Center 50 MHz Doppler Wind Profiler

Wind profile measurement and the simulation of aerodynamic loads on a launch vehicle play an important role in determining launch capability and post launch assessment of the vehicle's performance. To date, all United States range certified wind profile measurement systems have been based on balloon tracking. Since the 1960's, the standard used by the National Aeronautics and Space Administration and the Air Force at the Cape Canaveral Air Station (CCAS) for detailed wind profile measurements has been the radar tracked, aerodynamically stabilized Jimsphere balloon system. Currently, the Air Force is nearing certification and operational implementation of the Automated Meteorological Profiling System (AMPS) at CCAS and Vandenburg Air Force Base (VAFB). AMPS uses the Global Positioning System for tracking the Jimsphere balloon. It is anticipated that the AMPS/Jimsphere, named the High Resolution Flight Element (HRFE), will have equivalent, or better resolution than the radar tracked Jimsphere, especially when the balloon is far downrange, at a low elevation angle. By the 1980's, the development of Doppler Wind Profilers (DWP) had become sufficiently advanced to justify an experimental measurement program at Kennedy Space Center (KSC). In 1989 a 50 MHz DWP was installed at KSC. In principal, the 50 MHz DWP has the capability to track the evolution of wind profile dynamics within 5 minutes of a launch. Because of fundamental differences in the measurement technique, there is a significant time and space differential between 50 MHz DWP and HRFE wind profiles. This paper describes a study to quantify these differences from a sample of 50 MHz DWP/HRFE pairs obtained during the AMPS certification test program.

Roberts, Barry C.↗

Unconventional domain-wall pairs and interacting Bloch lines in a Dzyaloshinskii-Moriya multilayer thin film

Bloch-lines (BLs) play a key role in determining the static and dynamic behavior of chiral domain walls and skyrmions in multilayer films with a significant Dzyaloshinskii-Moriya interaction (DMI). Here, using in-situ Lorentz phase microscopy, we reveal a new type of spin texture, termed a type-II domain wall pair (DWP), stabilized in DMI multilayer thin films with BLs. For a type-II DWP, the Bloch components of each complementary domain wall are parallel, implying opposite chirality. Additionally, we find that type-II DWPs preferentially form through bifurcation of a type-I DWP and require the formation of at least two BLs. We demonstrate a distinct phase jump associated with type-II DWPs, and further reveal the role they play in the formation of mixed-character skyrmions where the Bloch component that can be of either left- or right-handed chirality.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Highland Lakes Water Resources: Using NASA Earth Observations to Improve Detection Systems for Harmful Algal Events in the Highland Lakes in Central Texas

Beginning in 2019, harmful algal events in Austin, Texas, caused canine deaths in the Lady Bird Lake and Lake Travis reservoirs. These reservoirs are part of the larger Highland Lakes chain, managed by the Lower Colorado River Authority (LCRA) and the City of Austin Department of Watershed Protection (CoA DWP), which fulfill municipal, commercial, and agricultural water demands. Given the recent increase in favorable algal event conditions in central Texas, the LCRA and CoA DWP partnered with NASA DEVELOP to improve algal event early-warning systems through the application of remote sensing and machine learning. An Earth observation-based algal monitoring system will assist the responsible agencies in predicting algal conditions and communicating hazards to the public. The NASA DEVELOP team utilized Landsat 8 Operational Land Imager (OLI) and Sentinel-2 Multispectral Instrument (MSI) data to produce products including chlorophyll-a concentrations, cyanobacteria detections, turbidity, and water surface temperature. Chlorophyll-a concentrations were retrieved with a pre-trained machine learning model (mixture density network) and spectral indices, while the other products were derived from spectral indices. In situ field data were used to validate and quantify uncertainties for each product. The validations show strong correlations for chlorophyll-a and water surface temperature. Time series analyses of chlorophyll-a concentrations show peaks in the severe drought years (2015 and 2016). This project's resulting products enable monitoring of environmental proxies relevant to algal event presence in the Highland Lakes chain and will ultimately support water management, decision making, and risk communication.

Kaitlynn Hietpas↗

The Application of Remote Sensing and Machine Learning to Improve Early Warning Systems for Harmful Algal Events in the Highland Lake Chain, TX

Beginning in 2019, harmful algal events have caused canine deaths in both Lady Bird Lake and Lake Travis located near Austin, Texas. These two reservoirs are part of the larger Highland Lakes chain, managed by the City of Austin Department of Watershed Protection (COA DWP) and the Lower Colorado River Authority (LCRA), which fulfill municipal, commercial, and agricultural water demands. Given the recent increase in favorable environmental conditions for algal events in central Texas, NASA DEVELOP partnered with LCRA and COA DWP to improve monitoring and early detection of algal events, utilizing satellite remote sensing and machine learning. Spatially and temporally varied chlorophyll a concentrations, cyanobacteria detections, turbidity, and water surface temperature products are used as environmental proxies. Landsat 8 Operational Land Imager (OLI) and the Sentinel-2 MultiSpectral Instrument (MSI) data were used to provide a combined revisit time of up to ~3 days and < 30 m per pixel products. Chlorophyll a concentrations were estimated using a pre-trained Mixture Density Network, and cyanobacteria detection was accomplished using the Broad Wavelength Algae Index, which can differentiate algal blooms from algal proliferations (mats). In situ data were used to validate remotely sensed measurements and quantify uncertainties. Preliminary results show a good fit between the modeled output and in situ observations, suggesting that remote sensing data can be used to retrieve biogeochemical properties and/or inherent optical properties (IOPs) of water columns in these inland human-made lakes. Uncertainties were introduced from the sensitivity to atmospheric correction, inherent mismatch between satellite and sampling data, and a relatively lower signal-to-noise ratio over water. The resulting products enable near real-time monitoring of environmental proxies relevant to algal event presence in the Highland Lakes chain, and will ultimately support water management, decision making, and risk communication.

Shuyu Chang↗

Enabling a novel approach to a controlled fabrication of 1D crystalline nanowires on suspended microstructures of arbitrary geometries using two direct-writing technologies

Recent progresses in additive manufacturing have inspired new technologies, such as direct laser writing technique, based on two-photon polymerization (2 PP), which complements and further enriches the nanofabrication tools portfolio. Here, we combine 2 PP and our mask-free scanning probe assisted ‘direct-write patterning’ (DWP) method to allow for: a) the fabrication of micro-bridge structures with sub-micrometer resolution, b) selective synthesis of crystalline ZnO nanowires at predefined locations, respectively. This synergistic approach enables cantilever probe patterning of catalysts directly on suspended micro-bridges for in-situ CVD growth of nanoscale material, in a templated manner. The study reported here represents the first proof-of-concept experiments demonstrating versatile and scalable methodology, which can be applied and straightforwardly extended to grow a variety of other nanomaterials, in a controlled and selective fashion, on freestanding micro/nanoscale structures, whose size and geometry can be conveniently varied via templating of sacrificial 2 PP polymeric scaffolds. Furthermore, the demonstration of the possibility to integrate this new approach with the conventional lithography techniques provides a step forward to the development of the novel class of hybrid polymer-silicon-1D or -2D materials, and systems. The quality of the produced ZnO nanowire assemblies was assessed using several physical characterization methods.

36 MATERIALS SCIENCE↗

Water desalination through the dewpoint evaporative system

This paper presents the first numerical analysis of a novel Dew Point Desalination unit (DPD), which utilizes the phenomenon of the evaporative cooling process to minimize energy consumption. The proposed solution is based on a modular structure, which allows it to obtain any required water production capacity. The analyses for various operational parameters and various climatic conditions are based on the numerical simulations conducted using a validated mathematical model. The system performance was described with different factors, including specific energy consumption (SEC) and daily water production rate respected to 1 m^3*s^-1 of passing air stream (DWP). It is shown that the DPD system can operate in almost every climate zone, and the desalinated water production consumes less than 1.5 kWh*m^-3 of electric energy It is noted the best performance of the DPD system is achieved in the semi-arid, desert and subtropical climate zones. In these climate zones, the 2-stage DPD system allows the production of desalinated water with an electric energy consumption SEC lower than 0.5 kWh*m^-3. The additional benefit of the DPD system is its modularity. The presented DPD system stands as a module, that can be multiplied as needed to achieve the desired size of the desalination plant.

Desalination↗