Dynamics of a room temperature ionic liquid under applied pressure
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Abstract This study examines dynamic pressure drag on rising dry buoyant thermals. A theoretical expression for drag coefficient C d as a function of several other nondimensional parameters governing thermal dynamics is derived based on combining the thermal momentum budget with the similarity theory of Scorer. Using values for these nondimensional parameters from previous studies, the theory suggests drag on thermals is small relative to that on solid spheres in laminar or turbulent flow. Two sets of numerical simulations of thermals in an unstratified, neutrally stable environment using an LES configuration of the Cloud Model 1 (CM1) are analyzed. One set has a relatively low effective Reynolds number R e and the other has an order-of-magnitude-higher R e ; these produce laminar and turbulent resolved-scale flows, respectively. Consistent with the theoretical C d , the magnitude of drag is small in all simulations. However, whereas the laminar thermals have C d ≈ 0.01, the turbulent thermals have weakly negative drag ( C d ≈ −0.1). This difference is explained by the laminar thermals having near vertical symmetry but the turbulent thermals exhibiting considerable vertical asymmetry of their azimuthally averaged flows. In the laminar thermals, buoyancy rapidly becomes concentrated around the main centers of rotation located along the horizontal central axis, leading to expansion of thermals via baroclinic vorticity generation but doing little to break vertical symmetry of the flow. Vertical asymmetry of the azimuthally averaged flow of turbulent thermals is attributed mainly to small-scale resolved eddies that are concentrated in the upper part of the thermals.
We report GaAs solar cells grown at rates exceeding 300 um/h by atmospheric-pressure dynamic hydride vapor phase epitaxy (D-HVPE). The surface morphology of the GaAs layers grown at those rates is smooth, with root mean square surface roughness of < 1.4 nm. We grew GaAs solar cells at rates from 35 - 309 um/h with negligible degradation in open circuit voltages (VOC), which ranged from 1.04 - 1.07 V. We showed the slight decrease in VOC is due to lack of doping optimization at higher growth rates. Deep level transient spectroscopy measurements showed low point defect densities that increases slightly with growth rate from 35 - 309 um/h. The low point defect concentrations and the high VOCs indicate that high material quality can be maintained at these extremely high growth rates, enabling the deposition of high efficiency cells in mere seconds instead of hours.
Subsurface formations provide vast resource for energy generation, energy storage, and carbon sequestration. Sustainable energy generation from shale oil/gas and integrity of longterm storage necessitate understanding fluid behavior in nanoporous geomedia (e.g., shale caprock) under dynamic pressure conditions.
This work demonstrates the functionality of the pressurizer using a fast-running three regions, non-equilibrium model and control programs of emulated PLCs. The state variables from an integrated model of primary loop in a representative PWR plant are communicated to the pressurizer’s emulated PLCs using a synchronized data transfer function. In turn, the PLCs communicate back instructions to the pressurizer model to adjust the pressure and water level to remain within preprogramed setpoints. Pressurizer model simultaneously solves the coupled mass and energy conservation equations in the saturated vapor and saturated and subcooled liquid regions using fixed step solver. Results demonstrate the response of the pressurizer model linked to an emulated pressure and water level PLCs in a simulated transient involving surge-in and surge-out events. The 50 ms response delay time for the emulated PLC insignificantly affects operation and predictions of the pressurizer model.
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Dynamic-compression experiments on geological materials are important for understanding the composition and physical state of the deep interior of the Earth and other planets. These experiments also provide insights into impact processes relevant to planetary formation and evolution. Recently, new techniques for dynamic compression using high-powered lasers and pulsed-power systems have been developed. These methods allow for compression on timescales ranging from nanoseconds to microseconds and can often achieve substantially higher pressure than earlier gas-gun-based loading techniques. The capability to produce shockless (i.e., ramp) compression provides access to new regimes of pressure–temperature space and new diagnostics allow for a more detailed understanding of the structure and physical properties of materials under dynamic loading. This review summarizes these recent advances, focusing on results for geological materials at ultra-high pressures above 200 GPa. Implications for the structure and dynamics of planetary interiors are discussed.
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Crystal growth is governed by an interplay between macroscopic driving force and microscopic interface kinetics at the crystal–liquid interface. Unlike the local equilibrium growth condition, the interplay becomes blurred under local nonequilibrium, which raises many questions about the nature of diverse crystal growth and morphological transitions. Here, we systematically control the growth condition from local equilibrium to local nonequilibrium by using an advanced dynamic diamond anvil cell (dDAC) and generate anomalously fast growth of ice VI phase with a morphological transition from three- to two-dimension (3D to 2D), which is called a shock crystal growth. Unlike expected, the shock growth occurs from the edges of 3D crystal along the (112) crystal plane rather than its corners, which implies that the fast compression yields effectively large overpressure at the crystal–liquid interface, manifesting the local nonequilibrium condition. Molecular dynamics (MD) simulation reproduces the faster growth of the (112) plane than other planes upon applying large overpressure. Moreover, the MD study reveals that the 2D shock crystal growth originates from the similarity of the interface structure between water and the (112) crystal plane under the large overpressure. As a result, this study provides insight into crystal growth under dynamic compressions, which makes a bridge for the unknown behaviors of crystal growth between under static and dynamic pressure conditions.
Phase transformations under high strain rates (dynamic compression) are examined in situ on ZrW 2 O 8 , a negative thermal expansion ternary ceramic displaying polymorphism. Amorphization, consistent with prior quasi-static measurements, was observed at a peak pressure of 3.0 GPa under dynamic conditions, which approximate those expected during fabrication. Evidence of partial amorphization was observed at lower pressure (1.8 GPa) that may be kinetically restrained by the short (<~150 ns) time scale of the applied high pressure. The impact of kinetics of pressure-induced amorphization from material fabrication methods is briefly discussed.