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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
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NASA NTRS1978

Meteor ablation spheres from deep-sea sediments

Spheres from mid-Pacific abyssal clays (0 to 500,000 yrs old), formed from particles that completely melted and subsequently recrystallized as they separated from their meteoroid bodies, or containing relict grains of parent meteoroids that did not experience any melting were analyzed. The spheres were readily divided into three groups using their dominant mineralogy. The Fe-rich spheres were produced during ablation of Fe and metal-rich silicate meteoroids. The glassy spheres are considerably more Fe-rich than the silicate spheres. They consist of magnetite and an Fe glass which is relatively low in Si. Bulk compositions and relict grains are useful for determining the parent meteoroid types for the silicate spheres. Bulk analyses of recrystallized spheres show that nonvolatile elemental abundances are similar to chondrite abundances. Analysis of relict grains identified high temperature minerals associated with a fine-grained, low temperature, volatile-rich matrix. The obvious candidates for parent meteoroids of this type of silicate sphere is a carbonaceous chondrite.

Blanchard, M. B.↗
NASA NTRS1976

Ferromagnetic resonance studies of lunar core stratigraphy

We first review the evidence which links the characteristic ferromagnetic resonance observed in lunar fines samples with agglutinatic glass produced primarily by micrometeorite impacts and present new results on Apollo 15, 16, and 17 breccias which support this link by showing that only regolith breccias contribute significantly to the characteristic FMR intensity. We then provide a calibration of the amount of Fe metal in the form of uniformly magnetized spheres required to give our observed FMR intensities and discuss the theoretical magnetic behavior to be expected of Fe spheres as a function of size. Finally, we present FMR results on samples from every 5 mm interval in the core segments 60003, 60009, and 70009. These results lead us to suggest: (1) that secondary mixing may generally be extensive during regolith deposition so that buried regolith surfaces are hard to recognize or define; and (2) that local grinding of rocks and pebbles during deposition may lead to short scale fluctuations in grain size, composition, and apparent exposure age of samples.

Housley, R. M.↗
NASA NTRS1994

Observations of impact-induced molten metal-silicate partitioning

Observations of molten mid-ocean ridge basalt (MORB)-molybdenum (Mo) interactions produced by shock experiments provide insight into impact and differentiation processes involving metal-silicate partitioning. Analysis of fragments recovered from experiments (achieving MORB liquid shock pressures from 0.8 to 6 GPa) revealed significant changes in the composition of the MORB and Mo due to reaction of the silicate and metal liquids on a short time scale (less than 13 s). The FeO concentration of the shocked liquid decreases systematically with increasing pressure. In fact, the most highly shocked liquid (6 GPa) contains only 0.1 wt% FeO compared to an initial concentration of 9 wt% in the MORB. We infer from the presence of micrometer-sized Fe-, Si- and Mo-rich metallic spheres in the shocked glass that the Fe and Si oxides in the MORB were reduced in an estimated oxygen fugacity of 10(exp -17) bar and subsequently alloyed with the Mo. The in-situ reduction of FeO in the shocked molten basalt implies that shock-induced reduction of impact melt should be considered a viable mechanism for the formation of metallic phases. Similar metallic phases may form during impact accretion of planets and in impacted material found on the lunar surface and near terrestrial impact craters. In particular, the minute, isolated Fe particles found in lunar soils may have formed by such a process. Furthermore, the metallic spheres within the shocked glass have a globular texture similar to the textures of metallic spheroids from lunar samples and the estimated, slow cooling rate of less than or equal to 140 C/s for our spheres is consistent with the interpretation that the lunar spheroids formed by slow cooling within a melted target.

Rowan, Linda R.↗
NASA NTRS1981

Magnetization of small iron-nickel spheres

Magnetic properties of small iron-nickel alloy spheres, having compositions which cover the entire Fe-Ni binary, are presented. The spheres were formed during solidification in free fall following the melting of electropolished wires of appropriate composition. The spheres with Ni not greater than 25% acquired a martensitic thermal remanence while those with Ni not less than 30% acquired a thermoremanent magnetization. A magnetic remanence-composition diagram and a coercive force-composition diagram are constructed. Magnetic hysteresis loops and derived parameters demonstrate the difference between metal-bearing and oxide-bearing natural samples. The magnetic remanence varies as the sphere size in conjunction with the microstructure. These results help to explain why coercive force is generally low, remanent coercive force is generally high, and their ratio (R/C) is always large in fine metal dispersions, such as lunar samples and chondrite meteorites.

Wasilewski, P.↗
NASA NTRS2000

Recognizing Leonid Meteoroids Among The Collected Startospheric Dust

Three chemical groups of primary "silicate" spheres <30 micron in diameter of cometary origin were collected in the lower stratosphere between 1981 May and 1994 July. The "silicate" sphere abundances represent an annual background from contributions by sporadic meteor and weak annual meteor shower activities. During two collection periods, from 06/22 until 08/18, 1983 (U2015), and from 09/15-12/15, 1981 (W7027/7029), a higher number of spheres was collected compared to other periods of the year represented by the other collectors studied here. This study links two different data sets, viz. the NASA/JSC Cosmic Dust Catalogs and peak activities of annual meteor showers, and identified high-velocity cometary sources for collected stratospheric "silicate" spheres. The majority of spheres on flag U2015 may originate from comet P/Swift-Tuttle (Perseids), while the majority of spheres on flags W7027/7029 could be from comet P/Halley (Orionids) or comet P/Tempel-Tuttle (Leonids). Variations in relative proportions of the Mg,Si,Ca +/- Al, Mg,Si +/- Fe and Al,Si,Ca spheres may offer a hint of chemical differences among high-velocity comets. Proof for the findings reported here might be obtained by targeted cosmic dust collections in the lower stratosphere including periods of meteor shower and storm activity.

Rietmeijer, Frans J. M.↗
NASA NTRS1972

Particle shape and magnetization of chondrite meteorites, lunar samples, and impactites

Extra terrestrial materials, certain materials which have their origin at the earth's surface due to meteoritic impact, or under highly reducing conditions, such as in the case of basaltic flows in contact with coal beds or serpentenites, all contain Fe and FeNi phases with high magnetization values and spherical shape. Normally, the demagnetizing field (H sub D = NI sub S: where N is the demagnetizing factor and I is the saturation magnetization) is corrected for. In disperse systems, such as most natural materials, the particle shape effects are analyzed in terms of the saturation fields, Hs = H sub D = NI sub S and the magnetization differences (Delta I sub S). Discrete size modes of superparamagnetic (SP), multidomain (MD), and single domain (SD) particles result in reduced coercive force (Hc), increase in the value R sub H (ratio of remanent coercive force, H sub R, to H sub C), and decrease in the value R sub I (ratio of remanent magnetization, I sub R, to saturation magnetization, T sub S). The main distinctions between the various natural materials can be made by this approach. Hysteresis loops for terrestrial basalts, Fe and Ni rods and spheres, chondrite meteorites, lunar samples, impactites, and chondritic fusion crust are presented.

Wasilewski, P.↗
NASA NTRS1978

Growth parameters for aligned microstructures in directionally solidified aluminum-bismuth monotectic

Microstructures are shown for directionally solidified Al-3.4 wt pct Bi alloys with 0.2 wt pct Fe and 0.6 wt pct Fe additions. The third element causes the LI/SI + LII growth interface to become cellular. The bismuth forms at the cell nodes, appearing either as uniformly spaced arrays of spheres in the case of 0.2 wt pct Fe, or as an irregular network in the case of 0.6 wt pct Fe. Changes in the growth conditions which are known to control cellular structure are seen to have a similar effect on the bismuth spacing, with the cross sectional spacing varying as the inverse of G (Temperature gradient) x R(Growth rate).

Parr, R. A.↗
NASA NTRS1977

Solar wind and micrometeorite effects in the lunar regolith

Using available data from the literature, an outline is formulated for the major physical and chemical effects expected during solar-wind bombardment of the lunar regolith. In agreement with results of Auger and other analyses of the composition of lunar grain surfaces, this outline predicts that solar-wind sputtering will tend to clean exposed grain surfaces by ejecting material at velocities exceeding lunar escape velocity. Results are also discussed which show that Fe is partially reduced in the outer few 10 nm of grain surfaces and that this reduced Fe forms 10-nm-diameter metal spheres throughout the glass during agglutinate formation by micrometeorite impacts. These metal spheres give the agglutinates their distinctive optical and magnetic properties and are partially responsible for the decreasing albedo of the lunar surface with exposure age.

Housley, R. M.↗
NASA NTRS2006

Comet Mineralogy as Inferred from Infrared Spectra of Comets

For most comets, infrared (IR) spectroscopy (remote sensing) is the method through which we diagnose the mineralogy and size distribution of dust in their comae. The shape and contrast of the IR spectral features depend on the particle size: optically active minerals (absorbing of visible and near-IR solar photons) and submicron solid grains or highly porous (> 90% vacuum) grains primarily contribute to the shapes of the observed resonances. Comet mineralogies typically are determined by fitting thermal emission models of ensembles of discrete mineral grains to observed IR spectral energy distributions. The absorptivities (Q-abs) and scattering efficiencies (Q-scat) of the discrete mineral grains are computed using Mie scattering, Maxwell-Garnet mixing, Discrete Dipole Approximation, and Multi-Layered Sphere codes. These techniques when applied to crystalline minerals, specifically olivine (Mg_x, Fe_1-x)2 Si04, x>0.9, require the use of ellipsoidal shaped particles with elongated axial ratios or hollow spheres to produce the shapes of the resonances observed both from comet comae and laboratory samples. The wavelength positions of the distinct resonances from submicron-radii crystalline silicates, as well as their thermal equilibrium temperatures, constrain the crystalline olivine to have a relatively high Mg-content (x>0.9, or Fo>90). Only resonances computed for submicron Mg-rich crystalline olivine and crystalline orthopyroxene match the observed IR spectral features. However, this has led to the interpretation that micron-radii and larger crystals are absent from comet comae. Furthermore, the mass fraction of silicate crystals is dependent upon whether just the submicron portion of the size distribution is being compared or the submicron crystals compare to the aggregates of porous amorphous silicates that are computationally tractable as porous spheres. We will discuss the Deep Impact results as examples of these challenges to interpreting mid-IR spectra of short-period comets.

Wooden, Diane H.↗
NASA NTRS2003

Iron catalyst chemistry in modeling a high-pressure carbon monoxide nanotube reactor

The high-pressure carbon monoxide (HiPco) technique for producing single-wall carbon nanotubes (SWNTs) is analyzed with the use of a chemical reaction model coupled with flow properties calculated along streamlines, calculated by the FLUENT code for pure carbon monoxide. Cold iron pentacarbonyl, diluted in CO at about 30 atmospheres, is injected into a conical mixing zone, where hot CO is also introduced via three jets at 30 degrees with respect to the axis. Hot CO decomposes the Fe(CO)5 to release atomic Fe. Then iron nucleates and forms clusters that catalyze the formation of SWNTs by a disproportionation reaction (Boudouard) of CO on Fe-containing clusters. Alternative nucleation rates are estimated from the theory of hard sphere collision dynamics with an activation energy barrier. The rate coefficient for carbon nanotube growth is estimated from activation energies in the literature. The calculated growth was found be about an order of magnitude greater than measured, regardless of the nucleation rate. A study of cluster formation in an incubation zone prior to injection into the reactor shows that direct dimer formation from Fe atoms is not as important as formation via an exchange reaction of Fe with CO in FeCO.

Evaluation Studies↗
NASA NTRS2002

FIP, FIT or MAD? Analysis of High Signal-to-Noise ASCA Spectra of Coronal Stars

ASCA (Advanced Satellite for Cosmology and Astrophysics) and EUVE (Extreme Ultraviolet Explorer) spectra of active late-type stars imply that Fe and other medium-Z elements may be 2-10 times less abundant in the coronae of these stars than in their photo-spheres (the MAD effect). These deficiencies may be related to the solar FIP (First Ionization Potential) effect, in which Fe and other low First Ionization Potential elements appear enriched in the solar corona over their photospheric values. The FIP effect is time variable. As part of this proposal, the K0-2 III star, 29 Draconis, was observed in X rays with the ASCA spacecraft in order to measure the coronal abundances of this star at three different stellar longitudes over its 31-day rotation cycle. The goal of the observations was to learn whether coronal abundances, and hence coronal magnetic structure, vary across the surface of 29 Draconis in phase with the motion of dark star-spots across its disk. A second task included in this project was a systematic reanalysis of 18-20 deep exposures of active coronal stars, which were extracted from the ASCA public archives. New thermal models were computed for each spectrum in order to derive coronal metal abundances for each star. The goal of this survey was to search for possible trends in coronal abundance with various stellar parameters such as rotation, chromospheric activity levels at ultraviolet and optical wavelengths, or evolutionary stage.

Simon, Theodore↗
NASA NTRS1984

Galactic heavy-ion shielding using electrostatic fields

The shielding of spacecraft against galactic heavy ions, particularly high-energy Fe(56) nuclei, by electrostatic fields is analyzed for an arrangement of spherical concentric shells. Vacuum breakdown considerations are found to limit the minimum radii of the spheres to over 100 m. This limitation makes it impractical to use the fields for shielding small spacecraft. The voltages necessary to repel these Fe(56) nuclei exceed present electrostatic generating capabilities by over 2 orders of magnitude and render the concept useless as an alternative to traditional bulk-material shielding methods.

Townsend, L. W.↗
NASA NTRS1996

Regional and Localized Deposits on the Moon

Earth-based telescopic remote sensing studies have provided important information concerning lunar pyroclastic deposits. Combined with the returned lunar sample studies and analyses of lunar photography, we have learned a great deal about the nature and origin of these explosive volcanic materials. Lunar pyroclastic deposits are more numerous, extensive, and widely distributed than previously thought. Two generic classes of lunar pyroclastics have been identified, regional and localized. From the former, two separate spectral compositional groups have been identified; one is dominated by Fe(2+)-bearing glasses, the other is composed of ilmenite-rich black spheres. Comparatively, three separate spectral groups have been identified among the localized deposits: highlands-rich, olivine-rich, and mare-rich. Returned sample studies and the recently collected Galileo and Clementine data also corroborate these findings. Albedo data and multispectral imagery suggest that the thicker core deposits of the regional dark mantle deposits (RDMD) are surrounded by pyroclastic debris and subjacent highlands material. The presence of a major component of pyroclastic debris in the regolith surrounding the core regional deposits has important implications for the resource potential of these materials. Both telescopic and orbital spectra indicate that the regional pyroclastic deposits are rich in iron, titanium and oxygen-bearing minerals. Particle shapes vary from simple glass spheres to compound droplets with quench crystallized textures. Their small grain size and friability make them ideal indigenous feedstock. Compared to other resource feedstock sources on the Moon, these pyroclastic materials may be the best oxygen resource on the Moon.

Coombs, Cassandra R.↗
NASA NTRS2002

The response of a spherical tissue-equivalent proportional counter to iron particles from 200-1000 MeV/nucleon

The radiation environment on board the space shuttle and the International Space Station includes high-Z and high-energy (HZE) particles that are part of the galactic cosmic radiation (GCR) spectrum. Iron-56 particles are considered to be one of the most biologically important parts of the GCR spectrum. Tissue-equivalent proportional counters (TEPCs) are used as active dosimeters on manned space flights. These TEPCs are further used to determine the average quality factor for each space mission. A TEPC simulating a 1-microm-diameter sphere of tissue was exposed as part of a particle spectrometer to (56)Fe particles at energies from 200-1000 MeV/nucleon. The response of TEPCs in terms of mean lineal energy, y(F), and dose mean lineal energy, y(D), as well as the energy deposited at different impact parameters through the detector was determined for six different incident energies of (56)Fe particles in this energy range. Calculations determined that charged-particle equilibrium was achieved for each of the six experiments. Energy depositions at different impact parameters were calculated using a radial dose distribution model, and the results were compared to experimental data.

Non-NASA Center↗
NASA NTRS1997

Self-Consistent Thermal Accretion Disk Corona Models for Compact Objects: Application to Cygnus X-1 - II

We apply our self-consistent accretion disk corona (ADC) model, with two different geometries, to the broadband X-ray spectrum of the black hole candidate Cygnus X-1. As shown in a companion paper, models in which the Comptonizing medium is a slab surrounding the cold accretion disk cannot have a temperature higher than about 140 keV for optical depths greater than 0.2, resulting in spectra that are much softer than the observed 10-30 keV spectrum of Cyg X-1. In addition, the slab-geometry models predict a substantial "soft excess" at low energies, a feature not observed for Cyg X-1, and Fe K-alpha fluorescence lines that are stronger than observed. Previous Comptonization models in the literature have invoked a slab geometry with optical depth tau(sub T) approx. greater than 0.3 and coronal temperature T(sub c) approx. 150 keV, but they are not self-consistent. Therefore, ADC models with a slab geometry are not appropriate for explaining the X-ray spectrum of Cyg X-1. Models with a spherical corona and an exterior disk, however, predict much higher self-consistent coronal temperatures than the slab-geometry models. The higher coronal temperatures are due to the lower amount of reprocessing of coronal radiation in the accretion disk, giving rise to a lower Compton cooling rate. Therefore, for the sphere-plus-disk geometry, the predicted spectrum can be hard enough to describe the observed X-ray continuum of Cyg X-1 while predicting Fe fluorescence lines having an equivalent width of approx. 40 eV. Our best-fit parameter values for the sphere-plus-disk geometry are tau(sub T) approx. equal to 1.5 and T(sub c) approx. equal to 90 keV.

Dove, James B.↗
NASA NTRS1988

High-velocity ultraviolet iron, silicon, oxygen, and sulfur absorption features associated with the remnant of SN 1006

New low-dispersion IUE spectra of a faint sdOb star located in a direction near the center of the SN 1006 remnant are presented. The UV spectrum of the star exhibits several strong absorption features which are uncharacteristic of its optical sdOB star classification. The identification by Wu et al. (1983) of very broad absorption features at 1610, 2370, 2600 A as Fe II gas associated with the SN 1006 remnant is supported. The observed Fe II line profiles indicate a concentration of Fe(+) toward the remnant's center with a radial velocity range on the order of + or - 5000 km/s. Strong absorption lines at 1281, 1331, and 1420 A are interpreted as originating from clumps of O-, Si- and S-rich ejecta with central radial velocities in the range 5000-6500 km/s. The presence in the SN 1006 remnant of an expanding sphere of iron-rich ejecta interior to O-, Si-, and S-rich clumps of ejecta having velocities over the maximum seen for the Fe II absorbing gas is consistent with type Ia Sn observations and carbon deflagration models.

Fesen, Robert A.↗
NASA NTRS1998

Experimental Study of Lunar and SNC Magmas

The research described in this progress report involved the study of petrological, geochemical and volcanic processes that occur on the Moon and the SNC parent body, generally accepted to be Mars. The link between these studies is that they focus on two terrestrial-type parent bodies somewhat smaller than earth, and the fact that they focus on the role of volatiles in magmatic processes and on processes of magma evolution on these planets. The work on the lunar volcanic glasses has resulted in some exciting new discoveries over the years of this grant. We discovered small metal blebs initially in the Al5 green glass, and determined the significant importance of this metal in fixing the oxidation state of the parent magma (Fogel and Rutherford, 1995). More recently, we discovered a variety of metal blebs in the Al7 orange glass. Some of these Fe-Ni metal blebs were in the glass; others were in olivine phenocrysts. The importance of these metal spheres is that they fix the oxidation state of the parent magma during the eruption, and also indicate changes during the eruption (Weitz et al., 1997) They also yield important information about the composition of the gas phase present, the gas which drove the lunar fire-fountaining. One of the more exciting and controversial findings in our research over the past year has been the possible fractionation of H from D during shock (experimental) of hornblende bearing samples (Minitti et al., 1997). This research is directed at explaining some of the low H2O and high D/H observed in hydrous phases in the SNC meteorites.

Rutherford, Malcolm J.↗
NASA NTRS1999

Abundances and Distributions of Volatile Elements (Na, S, Cl, K) Within Lunar Volcanic Glass Spheres

This research developed and applied high-precision analytical methods (electron microprobe) to determine the major- and minor-element abundances (Si, Ti, A], Cr, Fe, Mn, Mg, Ca, Na, K) in three suites of Apollo 14 volcanic green glasses. Since the precision of these data was a factor of 5-10 better than previously published results, the data provided the strongest constraints yet achieved on the geochemical processes that operated at depths less than 400 kilometers inside the Moon. The results of this work were submitted to the 29th Lunar and Planetary Science Conference, formed the basis for a Master's Thesis, and were published in the top-tier geochemical journal. Additional high-precision data on the trace abundances of sodium (Na), sulfur (S), and potassium (K) in the Apollo 17 volcanic orange glasses (74220) were also acquired during this grant-period. These data show diffusion profiles within individual 200-micron diameter, glass spherules that were apparently generated during the fire-fountain eruption of this magma in the presence of a transient vapor phase. Although these results have not yet been published, publication is planned in 2001 after additional numerical modeling has been completed. This work has also catalyzed on-going collaborative work with Professor Timothy Grove (MIT) to analyze and understand the origin of the Apollo 15 volcanic green glasses. That work will be completed for publication in 2001.

Delano, John W.↗