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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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11 records
All sourcesNASA NTRSDOE OSTI
DOE OSTI2024

Green buffers near industrial plants, examples in Jefferson County TX

Green buffers between industrial plants and residential areas have multiple purposes in mitigating air pollution and protecting the environment. This study focuses on providing information on examples of green space development by industries near residential areas in Jefferson County, Texas. One represents a full buffer where residences were totally removed, another is a partial buffer where some residences were removed in a neighborhood and the third represents vegetation of a formerly industrial facility. Additional estimates on benefits of buffer spaces with respect to a pollutant plume are also considered. The study used geospatial and property data from 1966 to 2020. The transition from a residential area to a full or partial buffers highlights possible mitigation of air pollution impacts while serving additional functions, such as boosting stormwater infiltration and improving the aesthetic attractiveness of the area. The transformation from oil tanks to forested space may display the potential for environmental remediation, but not all spaces are suitable for fully forested buffers, as safety and other limitations should be considered. With the analysis of the classic Plume Equation insights can be provided regarding the possible impact of green buffers on ground-level pollutant concentrations. The calculations for atmospheric stability classes A-F and for various stack heights provide an understanding of how different conditions may affect the pollutant concentrations. The presence of a green buffer can play a crucial role in controlling ground-level pollution concentrations and reduce a community’s perception of risk.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2020

Assessment of the MACCS Code Applicability for Nearfield Consequence Analysis

Three codes are used for comparisons in this report to evaluate the adequacy of MACCS in the nearfield, AERMOD, ARCON96 and QUIC. Test cases were developed to give a broad range of weather conditions, building dimensions and plume buoyancy. Based on the comparisons of MACCS with AERMOD, ARCON96 and QUIC across the test cases, the following observations are made: MACCS calculations configured with point-source, ground-level, nonbuoyant plumes provide nearfield results that bound the centerline, ground-level air concentrations from AERMOD, ARCON96, and QUIC. MACCS calculations with ground-level, nonbuoyant plumes that include the effects of the building wake (area source) provide nearfield results that bound the results from AERMOD and QUIC and the results from ARCON96 at distances >250 m. If using a point-source is too conservative and it is desired to bound the results from all three codes, another alternative is to use area source parameters in MACCS that are less than the standard values, i.e., an area source intermediate between the standard recommendation and a point source. All these options provide results from MACCS that are bounding for the test cases evaluated. Based on these observations, it appears that MACCS is adequate for use in nearfield calculations, given the correct parameterization.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗
DOE OSTI2020

Assessing outdoor air quality and public health impact attributable to residential black carbon emissions in rural China

Black carbon (BC) is a significant component of particulate matter (PM) that relates to air pollution, climate forcing, and further implications for public health. BC is predominantly released from the combustion of solid fuels. Combustion of low-quality fuels in rural China may induce severe respiratory and cardiopulmonary health outcomes for residents, which have however been inadequately assessed. One major reason for the limited understanding is the lack of a high-resolution inventory. An improved method of estimating the BC-associated public health burden is needed. This work quantified premature mortalities due to residential BC emissions in rural China. Domestic BC emissions at 1×1 km resolution were compiled based on previous field investigation, which were further configured for air quality simulation. A chemistry transport model, WRF–CMAQ v5.2, was employed for simulating BC concentrations. The consequent premature mortalities were quantified by a BC-specific concentration-response function (CRF) derived from an epidemiological study. Results show that residential combustion of solid fuel in rural China emitted 648.0 Gg (95%CI: 361.0–965.9) BC in 2014, after dispersion, accounting for 51.8% of annual mean ground-level BC concentration in China. Such impact was most severe in North and Northeast China, and the Sichuan Basin. The further investigation estimated 171,000 (95%CI: 69,000–387,000) premature mortalities that were attributable to exposure to rural residential BC. These findings reveal the major contribution of rural residential BC emissions to air pollution formation and public health impacts. Our findings are anticipated to provide useful information for enacting the next-stage environmental strategy for the residential sector in China.

63 RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTAN↗
DOE OSTI2026

Ammonia in northeast Colorado is increasing, rising most quickly in regions close to confined animal feeding operations

The Colorado Front Range urban corridor and nearby agricultural operations are important source regions of atmospheric ammonia (NH 3 ). Upslope flows periodically transport these emissions into Rocky Mountain National Park (RMNP), located 50 km west of the urban corridor, where wet and dry deposition of excess reactive nitrogen (N) impacts ecosystems. Here, we use a combination of in situ passive NH 3 measurements and NH 3 vertical column density retrievals from the Infrared Atmospheric Sounding Interferometer (IASI) to assess variability and changes in NH 3 across three land use categories in the northeast Colorado source region (agricultural, urban, and remote) during the period 2013-2023. A strong seasonal cycle is present across the region with increased NH 3 during summer months. Elevated NH 3 is spatially correlated with the number of permitted animal units in confined animal feeding operations (CAFOs) within 12 km. Ground-level NH 3 concentrations are strongly positively correlated with monthly gridded IASI satellite column densities. Satellite retrievals reveal an increasing trend in NH 3 column amounts of ∼3% per year in agricultural and ∼2% per year in urban sub-regions. The magnitude of the trend observed in NH 3 columns averaged over the agricultural sub-region is > 3 times larger than observed near and over Denver. The largest increases in NH 3 are closely aligned with the distribution of CAFOs. Reductions in particle sulfate associated with declining sulfur dioxide (SO 2 ) emissions could account for only ∼0.1% per year increase in gaseous NH 3 . Wildfire smoke across the region has increased but appears unlikely to explain the majority of the observed NH 3 increase.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Transforming US agriculture for carbon removal with enhanced weathering

Abstract Enhanced weathering (EW) with agriculture uses crushed silicate rocks to drive carbon dioxide removal (CDR) 1,2 . If widely adopted on farmlands, it could help achieve net-zero emissions by 2050 2–4 . Here we show, with a detailed US state-specific carbon cycle analysis constrained by resource provision, that EW deployed on agricultural land could sequester 0.16–0.30 GtCO 2 yr −1 by 2050, rising to 0.25–0.49 GtCO 2 yr −1 by 2070. Geochemical assessment of rivers and oceans suggests effective transport of dissolved products from EW from soils, offering CDR on intergenerational timescales. Our analysis further indicates that EW may temporarily help lower ground-level ozone and concentrations of secondary aerosols in agricultural regions. Geospatially mapped CDR costs show heterogeneity across the USA, reflecting a combination of cropland distance from basalt source regions, timing of EW deployment and evolving CDR rates. CDR costs are highest in the first two decades before declining to about US$100–150 tCO 2 −1 by 2050, including for states that contribute most to total national CDR. Although EW cannot be a substitute for emission reductions, our assessment strengthens the case for EW as an overlooked practical innovation for helping the USA meet net-zero 2050 goals 5,6 . Public awareness of EW and equity impacts of EW deployment across the USA require further exploration 7,8 and we note that mobilizing an EW industry at the necessary scale could take decades.

Science & Technology - Other Topics↗
DOE OSTI2024

Measurement report: A comparison of ground-level ice-nucleating-particle abundance and aerosol properties during autumn at contrasting marine and terrestrial locations

Abstract. Ice-nucleating particles (INPs) are an essential class of aerosols found worldwide that have far-reaching but poorly quantified climate feedback mechanisms through interaction with clouds and impacts on precipitation. These particles can have highly variable physicochemical properties in the atmosphere, and it is crucial to continuously monitor their long-term concentration relative to total ambient aerosol populations at a wide variety of sites to comprehensively understand aerosol–cloud interactions in the atmosphere. Hence, our study applied an in situ forced expansion cooling device to measure ambient INP concentrations and test its automated continuous measurements at atmospheric observatories, where complementary aerosol instruments are heavily equipped. Using collocated aerosol size, number, and composition measurements from these sites, we analyzed the correlation between sources and abundance of INPs in different environments. Toward this aim, we have measured ground-level INP concentrations at two contrasting sites, one in the Southern Great Plains (SGP) region of the United States with a substantial terrestrially influenced aerosol population and one in the Eastern North Atlantic Ocean (ENA) region with a primarily marine-influenced aerosol population. These measurements examined INPs mainly formed through immersion freezing and were performed at a ≤ 12 min resolution and with a wide range of heterogeneous freezing temperatures (Ts above −31 °C) for at least 45 d at each site. The associated INP data analysis was conducted in a consistent manner. We also explored the additional offline characterization of ambient aerosol particle samples from both locations in comparison to in situ data. From our ENA data, on average, INP abundance ranges from ≈ 1 to ≈ 20 L−1 (−30 °C ≤ T ≤ −20 °C) during October–November 2020. Backward air mass trajectories reveal a strong marine influence at ENA with 75.7 % of air masses originating over the Atlantic Ocean and 96.6 % of air masses traveling over open water, but analysis of particle chemistry suggests an additional INP source besides maritime aerosols (e.g., sea spray aerosols) at ENA. In contrast, 90.8 % of air masses at the SGP location originated from the North American continent, and 96.1 % of the time, these air masses traveled over land. As a result, organic-rich SGP aerosols from terrestrial sources exhibited notably high INP abundance from ≈ 1 to ≈ 100 L−1 (−30 °C ≤ T ≤ −15 °C) during October–November 2019. The probability density function of aerosol surface area-scaled immersion freezing efficiency (ice nucleation active surface site density; ns) was assessed for selected freezing temperatures. While the INP concentrations measured at SGP are higher than those of ENA, the ns(T) values of SGP (≈ 105 to ≈ 107 m−2 for −30 °C ≤ T ≤ −15 °C) are reciprocally lower than ENA for approximately 2 orders of magnitude (≈ 107 to ≈ 109 m−2 for −30 °C ≤ T ≤ −15 °C). The observed difference in ns(T) mainly stems from varied available aerosol surface areas, Saer, from two sites (Saer,SGP > Saer,ENA). INP parameterizations were developed as a function of examined freezing temperatures from SGP and ENA for our study periods.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2023

Performance Analyses of Supercritical Carbon Dioxide-Based Parabolic Trough Collectors with Double-Glazed Receivers

Supercritical carbon dioxide is becoming a hot research topic as a potential heat transfer fluid in parabolic trough concentrators since it enables operating the solar system at high temperatures for a higher quality of energy. However, the corresponding inflated thermal losses necessitate alternative receiver designs. This work examines four double-glazed receivers, with each annular space being evacuated or non-evacuated, in terms of the absorber tube's diameter (53-80 mm) and the diameter ratios of the two glass shells (1.2-2.0). An analytical model is developed and validated for this purpose, and the four designs are further examined using ground-level solar and meteorological measurements. The results demonstrate higher performance in the case of fully evacuating the receiver and using the smallest possible diameters of the three concentric cylinders, where the energy and exergy efficiencies reach 65.3 and 40.3%, respectively. Yet, evacuating only the inner annular space is sufficient to achieve virtually the same performance level. This energy efficiency decreases to 62% in case of increasing the tube diameter to 80 mm. As the operating temperature increases from 423 to 850 K, the specific thermal losses increase by 3.98-4.34 folds, depending on the receiver design. Double glazing the receivers is favorable only at high operating temperatures of sCO2, where the reduction in thermal losses overcomes the drop in optical efficiency. For an inlet sCO2 temperature of 850 K, thermal losses are reduced by 33.64 and 53.92%, compared to evacuated and non-evacuated single-glazed receivers, respectively. Throughout the year, the fully evacuated and fully non-evacuated double-glazed receivers have energy efficiencies of 54.96 and 52.39%, exergy efficiencies of 33.64 and 32.06%, and thermal losses of 348.8 and 402.5 W/m, respectively.

analytical model↗
DOE OSTI2025

Multi-seasonal measurements of the ground-level atmospheric ice-nucleating particle abundance on the North Slope of Alaska

Atmospheric ice-nucleating particles (INPs) are an important subset of aerosol particles that are responsible for the heterogeneous formation of ice crystals. INPs modulate the arctic cloud phase (liquid vs. ice), resulting in implications for radiative feedbacks. The number of arctic INP studies investigating specific INP episodes or sources increased recently. However, existing studies are based on short-duration field data, and long-term datasets are lacking. Continuous, long-term measurements are key to determining the abundance and variability of ambient arctic INPs and constraining aerosol–cloud interactions, e.g., to verify and/or improve simulations of mixed-phase clouds. Here, we present a new long-duration INP dataset from the Arctic: 2 years of predominantly immersion-mode INP concentrations (n INP ) measured continuously at the National Oceanic and Atmospheric Administration's Barrow Atmospheric Baseline Observatory (BRW) on the North Slope of Alaska. A portable ice nucleation experiment chamber (PINE-03), which simulates adiabatic expansion cooling, was used to directly measure the ground-level INP abundance with an approximately 12 min time resolution from October 2021 to December 2023. We document PINE-03 n INP measurements as well as estimated ice nucleation active surface site density (n s ) over a wide range of heterogeneous freezing temperatures from −16 to −31 °C from which we introduce new season-specific parameterizations suitable for modeling mixed-phase clouds. Collocated aerosol and meteorological data were analyzed to assess the correlation between ambient n INP , air mass origin region, and meteorological variability. Our findings suggest (1) very high freezing efficiency of INPs across the measured temperatures (n s ≈ 2×10 8 –10 10 m −2 for −16 to −31 °C), which is a factor of 10–1000 times greater efficiency as compared to that found in the previous mid-latitude INP measurements in fall using the same instrument; (2) surprisingly high n INP (≥ 1 L −1 at −25 °C) for the examined temperatures throughout the year that were not measured by PINE-03 at other sites; and (3) high n INP in spring, possibly related to arctic haze episodes. Relatively low concentrations of aerosol surface area and contrasting high-INP concentrations at BRW relative to mid-latitude sites are the possible reasons for the observed high freezing efficiency.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2021

Ice-nucleating particles in precipitation samples from the Texas Panhandle

Ice-nucleating particles (INPs) influence the formation of ice crystals in clouds and many types of precipitation. This study reports unique properties of INPs collected from 42 precipitation samples in the Texas Panhandle region from June 2018 to July 2019. We used a cold stage instrument called the West Texas Cryogenic Refrigerator Applied to Freezing Test system to estimate INP concentrations per unit volume of air (nINP) through immersion freezing in our precipitation samples with our detection capability of >0.006 INP L -1 . A disdrometer was used for two purposes: (1) to characterize the ground-level precipitation type and (2) to measure the precipitation intensity as well as size of precipitating particles at the ground level during each precipitation event. While no clear seasonal variations of n INP values were apparent, the analysis of yearlong ground-level precipitation observation as well as INPs in the precipitation samples showed some INP variations, e.g., the highest and lowest n INP values at -25°C both in the summer for hail-involved severe thunderstorm samples (3.0 to 1130 INP L -1 ), followed by the second lowest at the same temperature from one of our snow samples collected during the winter (3.2 INP L -1 ). Furthermore, we conducted bacteria community analyses using a subset of our precipitation samples to examine the presence of known biological INPs. In parallel, we also performed metagenomics characterization of the bacterial microbiome in suspended ambient dust samples collected at commercial open-lot livestock facilities (cattle feedyards hereafter) in the Texas Panhandle (i.e., the northernmost counties of Texas, also known as “West Texas”) to ascertain whether local cattle feedyards can act as a source of bioaerosol particles and/or INPs found in the precipitation samples. Some key bacterial phyla present in cattle feedyard samples appeared in precipitation samples. However, no known ice nucleation active species were detected in our samples. Overall, our results showed that cumulative n INP in our precipitation samples below -20°C could be high in the samples collected while observing > 10 mm h -1 precipitation with notably large hydrometeor sizes and an implication of cattle feedyard bacteria inclusion.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

Implications of Aerosol Physicochemical Properties Including Ice Nucleation at ARM Mega Sites for Improved Understanding of Microphysical Atmospheric Cloud Processes (Final Technical Report)

Continuous, long-term measurements of atmospheric ice-nucleating particles (INPs) that influence clouds and precipitation were conducted to investigate the abundance and variability of ground-level INPs across the world. Three field campaigns were organized by the DOE Atmospheric Radiation Measurement (ARM) program, including Examining INP from Southern Great Plains (ExINP-SGP, 2019), Examining INP from Eastern North Atlantic (ExINP-ENA, 2020 – 2021), and Examining INP from North Slope of Alaska (ExINP-NSA, 2021 – 2024). Additional small-scale supporting field experiments were performed in 2019 and 2021 to collect airborne particulate matter at SGP for complementary laboratory characterization of the particles’ physical and chemical properties [Aerosol-Ice Formation Closure Pilot Study (AEROICESTUDY), 2019; ExINP-SGP II, 2021]. In these studies, the PI’s team measured INP concentration with both real-time and laboratory measurements in a wide range of freezing temperatures ($T$ from 0 °C to about –30 °C). This project elucidated spatial variability and seasonality in the abundance of immersion mode active INPs across three ARM sites using a single instrument, a Portable Ice Nucleation Experiment (PINE) chamber version 03 (PINE-03 hereafter). Collocated aerosol and meteorological data were analyzed to assess the correlation between ambient INP abundance, air mass origin region, and meteorological variability. Our findings suggest very high freezing efficiency of INPs at the NSA site across the measured temperatures (ice nucleation active surface site density, $n_s(T)$, $\approx 2 \times 10^{8} - 10^{10}$ m -2 for from –16 to –31 °C), which is a factor of 10 – 1000 times greater efficiency as compared to that found in the previous mid-latitude INP measurements in autumn using the same instrument; surprisingly high INP abundance ($\ge 1 \text{ L}^{-1}$ at –25 °C) for the examined temperatures throughout the year that PINE-03 did not measure at other sites; and high INP concentration in spring, possibly related to arctic haze episodes.

58 GEOSCIENCES↗
DOE OSTI2026

Surface ozone and meteorological variables at CoURAGE TBS site during summer IOP

This dataset provides continuous near ground-level in situ ozone and meteorological data at the TBS site (S7) during the CoURAGE summer IOP. The ozone inlet and the weather station were approximately 5 meters above the surface. In situ ozone (ppbv) was collected with a 2BTech Model 205 dual beam ozone monitor. The meteorological data (temperature, pressure, relative humidity, wind speed, and wind direction) was collected with an AIRMAR 220WX WeatherStation Instrument with relative humidity (RH) module. The data has 2-second temporal resolution.

bar_pres↗