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At least 19 records

Microstructural evolution of diamond growth during HFCVD

High resolution transmission electron microscopy (HRTEM) was used to study the nucleation and growth mechanism of diamond by hot filament chemical vapor deposition (HFCVD) process. A novel technique has shown a direct evidence for the formation of the diamond-like carbon layer 8-14 nm thick in which small diamond micro-crystallites were embedded. These diamond micro-crystallites were formed as a result of transformation of diamond-like carbon into diamond. The diamond micro-crystallites present in the amorphous diamond-like carbon layer provided nucleation sites for diamond growth. Large diamond crystallites were observed to grow from these micro-crystallites. The mechanism of diamond growth will be presented based on experimental findings.

TRT-EXPERIMENTAL↗

A Three-Year Program of Micro- and Nano-System Technology Development for X-Ray Astronomy

For many years the work at MIT aimed at the development of new concepts and technologies for space experiments in high-energy astrophysics, but not explicitly supported by flight programs, has been supported. This work has yielded new devices and techniques for X-ray astronomy, primarily low-noise, deep-depletion charge-coupled devices (CCDS) for spectrally-resolved X-ray imaging, and high-performance transmission gratings for high-resolution X-ray spectroscopy. Among the most significant recent achievements have been the development by G. Ricker and associates of the X-ray CCD camera flying on ASCA, and currently in development for AXAF and Astro-E, and the development by C. Canizares and associates of thick, 200 nm-period transmission gratings employing the phenomenon of phase shifting for high-resolution X-ray spectroscopy up to energies of 8- 1 0 keV that is essential for the operation of the AXAF High Energy Transmission Grating Spectrometer (HETGS). Through the current SR&T grant, the latter technology is now being extended successfully to the fabrication of 100 nm-period transmission gratings, which have twice the dispersion of the AXAF gratings. We note that, among other outcomes, the modest investments of past SR&T Grants at MIT resulted in the development of the key technologies for fully one-half of the scientific instrumentation on AXAF. In addition, NASA flight programs that have benefited from previous SR&T support at MIT include the SAS 3 X-ray Observatory, which carried the first rotation modulation collimator, the Focal Plane Crystal Spectrometer (FPCS) on the Einstein Observatory, the CCD cameras on ASCA and planned for Astro-E, the High Energy Transient Experiment (HETE), the Solar EUV Monitor on the Solar and Heliospheric Observatory (SOHO), the Medium Energy Neutral Atom imager (MENA) on the Image for Magnetopause-to-aurora Global Exploration (IMAGE) mission, and the recently-approved Two Wide-Angle Imaging Neutral-atom Spectrometers (TWINS) Mission of Opportunity.

Canizares, Claude R.↗

AXAF: Current Developments and Future Plans for the Scientific Data Analysis

AXAF, the Advanced X-ray Astrophysics Facility, is one of NASA's great observatories scheduled for launch in January of 1999 by a Space Shuttle. This facility will be available to scientists in the United States and to the international astronomical community over an anticipated mission lifetime of at least 5 years. The objective of AXAF is to make astrophysical observations in the 0.09 to 10.0 keV energy range with two imaging detectors, and two sets of transmission gratings giving high spatial (0.5 arcsec) and spectral (E/(Delta)E=100-2000) resolution. The AXAF Science Center (ASC) in Cambridge, MA, USA is responsible for obtaining and reviewing observation proposals submitted by users, providing long range science planning and performing all science data calibration, data analysis, science instrument trend analysis, and science data archiving. The ASC will distribute science data products to the users. We will review here the current developments and future plans for the AXAF scientific data analysis system, its infrastructure and new key features, including the global modelling and fitting environment, integrated data analysis GUIs and new analysis tools.

Fruscione, Antonella↗

High Resolution Imaging and Analysis of Terrestrial Impact Glass: Amorphous Materials, Phyllosilicates and Everything in Between

Introduction: Impact cratering is one of the most ubiquitous geologic processes shaping the surface of all solid bodies in our solar system. Impacts are also a major source of clay minerals, poorly crystalline clay-like phases and amorphous (i.e., lacking long-range atomic order) materials on Earth and Mars. Phyllosilicates and amorphous materials have consistently formed a major component (~20-70 wt%) of every single drilled rock and soil sample in Gale Crater on Mars, as determined by the CheMin instrument on Curiosity. The origin of the amorphous component is speculative, but could be primary impact or volcanic-produced glass(es) deposited via aeolian or fluvial processes, secondary aqueous alteration products or chemical precipitates; it is likely to be a combination of all three possibilities. Efforts to determine the composition of these materials across the rover’s traverse through Gale Crater are ongoing. Naturally occurring amorphous phases are found in a variety of environments on Earth, and terrestrial analogue studies may help shed light on how they may have formed on Mars. Primary and altered impact glass are likely widespread on Mars and may have contributed to the amorphous component found throughout Gale Crater. In its pristine, unaltered state, impact glass (i.e., melt glass) is considered amorphous. However, truly unaltered glass is rarely preserved in crater fill impactites as it quickly alters in the post-impact environ-ment, commonly forming a mixture of hydrated aluminosilicate phases whose structures are not always discernable at the microscale (i.e., they may be amorphous or contain short-range order). These phases are part of an incredibly complex group of materials; differences in their composition and crystalline structure (or lack thereof) and genetic relationship to the more well-crystalline clay minerals are often only discernable at the nanoscale, beyond the resolution of traditional X-ray diffractometers (XRD) and scanning electron microscopes/microprobes (SEM/EPMA) alone. In this contribution, we summarize recent results from ongoing characterization of clay minerals, poorly crystalline clay-like phases, and amorphous materials preserved in altered terrestrial impact glass from the Chicxulub (~66 Ma) and Ries (~15 Ma) impact structures. This work has been performed using a combination of high-resolution transmission electron microscopy (HR-TEM), SEM, microprobe/EPMA, Raman spectroscopy and XRD.

Impact crater↗

Empirical InfraRed Line Lists for Five SO2 Isotopologues: 32/33/34/36S16O2 and 32S18O2

Using the latest published, empirically refined potential energy surface (PES) Ames-1 and purely ab initio CCSD(T)/aug-cc-pVQZ dipole moment surface (DMS), we have computed Infrared line lists for five symmetric isotopologues of sulfur dioxide: 32S16O2 (626), 33S16O2 (636), 34S16O2 (646), 36S16O2 (666), and 32S18O2 (828). The line lists are based on J=0-80 rovibrational variational calculations with E’ ≤ 8000 cm-1. The 34S16O2 and 33S16O2 line lists are compared to the experiment-based models in the HIgh-resolution TRANsmission molecular absorption database (HITRAN2012, http://www.cfa.harvard.edu/hitran/) and the Cologne Database for Molecular Spectroscopy, CDMS (http://www.astro.uni-koeln.de/cdms/). The accuracy for computed 646 band origins is similar to what has been reported for the main isotopologue, i.e. 0.01 – 0.03 cm-1 for bands up to 5500 cm-1. For rovibrational transitions, the 646 line position and intensity deviation patterns are much simpler and more self-consistent than those of the main isotopologue 626. The discrepancies are mainly found for higher Ka/J transitions. 626 and 646 exhibit comparable line position and intensity agreement for lower Ka/J transitions. The line position deviations for the 636 purely rotational band are parallel to those of 626 and 646, while its line intensity deviations do not show branching patterns as we found in the 626 and 646 cases. Predictions for the other minor isotopologues are expected to exhibit similar accuracy. These line lists are accurate enough to provide alternatives for missing bands of 626 and the minor isotopologues. It may significantly facilitate the laboratory spectroscopic measurement and analysis, as well as to identify these isotopologues in various astrophysical environments.

Sulfur Dioxide↗

Laboratory Astrophysics Using a Spare XRS Microcalorimeter

The XRS instrument on Astro-E is a fully self-contained microcalorimeter x-ray instrument capable of acquiring optimally filtering, and characterizing events for 32 independent pixels. With the launch of the Astro-E spacecraft, a full flight spare detector system has been integrated into a laboratory cryostat for use on the electron beam ion trap (EBIT) at Lawrence Livermore National Laboratory. The detector system contains a microcalorimeter array with 32 instrumented pixels heat sunk to 60 mK using an adiabatic demagnetization refrio,erator. The instrument has a composite resolution of 8eV at 1 keV and 12eV at 6 keV with a minimum of 95% quantum efficiency. This will allow high spectral resolution, broadband observations of collisionally excited plasmas which are produced in the EBIT experiment. Unique to our instrument are exceptionally well characterized 1000 Angstrom thick aluminum on polyimide infrared blocking filters. The detailed transmission function including the edc,e fine structure of these filters has been measured in our laboratory using an erect field grating spectrometer. This will allow the instrument to perform the first broadband absolute flux measurements with the EBIT instrument. The instrument performance as well as the results of preliminary measurements will be discussed. Work performed under the auspices of the U.S. D.o.E. by Lawrence Livermore National Laboratory under contract W-7405-ENG-48 and was supported by the NASA High Energy Astrophysics Supporting Research and Technology Program.

Audley, M. Damian↗

Advanced X-ray Astrophysics Facility (AXAF) science instruments

The overall AXAF program is summarized, with particular emphasis given to its science instruments. The science objectives established for AXAF are to determine the nature of celestial objects, from normal stars to quasars, to elucidate the nature of the physical processes which take place in and between astronomical objects, and to shed light on the history and evolution of the universe. Attention is given to the AXAF CCD imaging spectrometer, which is to provide spectrally and temporally resolved imaging, or, in conjunction with transmission grating, high-resolution dispersed spectral images of celestial sources. A high-resolution camera, an X-ray spectrometer, and the Bragg Crystal Spectrometer are also discussed.

Winkler, Carl E.↗

Advanced X-ray Astrophysics Facility (AXAF) science instrumentation

AXAF is to be equipped with a high performance X-ray telescope for the conduction of detailed astrophysics research. The observatory is to be serviced by the Space Station or the Shuttle, depending on capabilities during the AXAF operational period. The AXAF is to utilize the wavelength band from 1.2 A to 120 A. Attention is given to the AXAF science team, the AXAF observatory characteristics, the AXAF science instrument definition program, the Advanced Charge Coupled Device (CCD) Imaging Spectrometer (ACIS), the High Resolution Camera (HRC), the Bragg Crystal Spectrometer (BCS), the X-ray Spectrometer (XRS), the transmission gratings, and the program schedule.

Dailey, C. C.↗

The Astro-E/XRS Blocking Filter Calibration

We describe the transmission calibration of the Astro-E XRS blocking filters. The XRS instrument has five aluminized polyimide blocking filters. These filters are located at thermal stages ranging from 200 K to 60 mK. They are each about 1000 A thick. XRS will have high energy resolution which will enable it to see some of the extended fine structure around the oxygen and aluminum K edges of these filters. Thus, we are conducting a high spectral resolution calibration of the filters near these energies to resolve out extended flue structure and absorption lines.

Audley, Michael D.↗

Shuttle Spacesuit: Fabric/LCVG Model Validation

A detailed spacesuit computational model is being developed at the Langley Research Center for radiation exposure evaluation studies. The details of the construction of the spacesuit are critical to estimation of exposures and assessing the risk to the astronaut on EVA. Past evaluations of spacesuit shielding properties assumed the basic fabric lay-up (Thermal Micrometeroid Garment, fabric restraints, and pressure envelope) and Liquid Cooling and Ventilation Garment (LCVG) could be homogenized as a single layer overestimating the protective properties over 60 percent of the fabric area. The present spacesuit model represents the inhomogeneous distributions of LCVG materials (mainly the water filled cooling tubes). An experimental test is performed using a 34-MeV proton beam and high- resolution detectors to compare with model-predicted transmission factors. Some suggestions are made on possible improved construction methods to improve the spacesuit's protection properties.

Wilson, J. W.↗

Imaging of Mercury and Venus from a flyby.

Study of an imaging experiment planned for the 1973 Mariner Venus/Mercury flyby mission. Scientific objectives are presented together with mission constraints, analysis of alternative systems, and the rationale for the final choice. The final selection was a vidicon camera quite similar to that used for Mariner Mars 1971, but with the capability of real time transmission during the Venus and Mercury flybys. Systematic high resolution UV photography of Venus is planned after encounter in an attempt to understand the nature of the mysterious UV markings and their apparent 4- to 5-day rotation period.

Murray, B. C.↗

The Complex Circumnuclear Environment of the Broad-Line Radio Galaxy 3C 390.3 Revealed by Chandra HETG

We present the first high spectral resolution X-ray observation of the broad-line radio galaxy 3C 390.3 obtained with the high-energy transmission grating spectrometer on board the Chandra X-ray Observatory. The spectrum shows complex emission and absorption features in both the soft X-rays and Fe K band. We detect emission and absorption lines in the energy range E = 700-1000 eV associated with ionized Fe L transitions (Fe XVIIXX). An emission line at the energy of E approximately equal to 6.4 keV consistent with the Fe K alpha is also observed. Our best-fit model requires at least three different components: (i) a hot emission component likely associated with the hot interstellar medium in this elliptical galaxy with temperature kT = 0.5 +/- 0.1 keV; (ii) a warm absorber with ionization parameter log Epislon = 2.3 +/- 0.5 erg s(exp 1) cm, column density logN(sub H) = 20.7 +/- 0.1 cm(exp -2), and outflow velocity v(sub out) less than 150 km s(exp -1); and (iii) a lowly ionized reflection component in the Fe K band likely associated with the optical broad-line region or the outer accretion disk. These evidences suggest the possibility that we are looking directly down the ionization cone of this active galaxy and that the central X-ray source only photoionizes along the unobscured cone. This is overall consistent with the angle-dependent unified picture of active galactic nuclei.

black hole physics↗

Shuttle Space Suit: Fabric/LCVG Model Validation

A detailed space suit computational model is being developed at the Langley Research Center for radiation exposure evaluation studies. The details of the construction of the space suit are critical to estimation of exposures and assessing the risk to the astronaut on EVA. Past evaluations of space suit shielding properties assumed the basic fabric layup (Thermal Micrometeoroid Garment, fabric restraints, and pressure envelope) and LCVG could be homogenized as a single layer overestimating the protective properties over 60 percent of the fabric area. The present space suit model represents the inhomogeneous distributions of LCVG materials (mainly the water filled cooling tubes). An experimental test is performed using a 34-MeV proton beam and high-resolution detectors to compare with model-predicted transmission factors. Some suggestions are made on possible improved construction methods to improve the space suit s protection properties.

Wilson, J. W.↗

Ground Calibration of the Astro-H (Hitomi) Soft X-Ray Spectrometer

The Astro-H (Hitomi) Soft X-ray Spectrometer (SXS) was a pioneering imaging x-ray spectrometer with 5 eV energy resolution at 6 keV. The instrument used a microcalorimeter array at the focus of a high-throughput soft x-ray telescope to enable high-resolution non-dispersive spectroscopy in the soft x-ray waveband (0.3-12 keV). We present the suite of ground calibration measurements acquired from 2012-2015, including characterization of the detector system, anti-coincidence detector, optical blocking filters, and filter-wheel filters. The calibration of the 36-pixel silicon thermistor microcalorimeter array includes parameterizations of the energy gain scale and line spread function for each event grade over a range of instrument operating conditions, as well as quantum efficiency measurements. The x-ray transmission of the set of five Al/polyimide thin-film optical blocking filters mounted inside the SXS dewar has been modeled based on measurements at synchrotron beamlines, including with high spectral resolution at the C, N, O, and Al K-edges. In addition, we present the x-ray transmission of the dewar gate valve and of the filters mounted on the SXS filter wheel (external to the dewar), including beryllium, polyimide, and neutral density filters.

detectors↗

Clay minerals in primitive meteorites and interplanetary dust 2. Smectites and micas

The classification is briefly summarized of stony meteorites and cosmic dust, and the mineralogy and chemistry is described of serpentine group minerals. The occurrence of smectites and micas in extraterrestrial materials is examined. The characterization of fine grained minerals in meteorites and IDPs relies heavily on electron beam instruments, especially the transmission electron microscope (TEM). Typically, phyllosilicates are identified by a combination of high resolution imaging of basal spacings, electron diffraction, and chemical analysis. Smectites can be difficult to differentiate from micas because the smectites lose their interlayer water and the interlayer partly collapse in the high vacuum of the TEM.

Keller, L. P.↗

Active-Pixel Image Sensors With Programmable Resolution

Active-pixel image sensors with programmable resolution proposed for use in applications in which speed and efficiency of processing of image data enhanced by providing those data at varying resolutions. Such applications include modeling of biological vision, stereoscopic range-finding, recognition of patterns, tracking targets, and progressive transmission of compressed images. In target-tracking application, sensor initially forms low-resolution image from which area of interest identified, then sensor set at high resolution for examination of identified area. Outputs of contiguous pixels combined. Sensor of this type made to act as though it comprised fewer and larger pixels.

Kemeny, Sabrina E.↗

Appropriateness in using LANDSAT in development energy related data bases

The use of automated classification systems in the field of resource management and resource inventory is discussed. Applications of LANDSAT classification are outlined and include: energy load forecasting based upon land use inventories and change analysis, impact analysis of activities related to energy extraction, capability/suitability mapping in support of generation and substation location and transmission line routing, and assessment of solar energy potential in a highly urbanized setting where land values are high. It is found that the use of LANDSAT data is adequate for general inventories where few data categories are required, where resolution of data to around 150 acres minimum is required, and where no other complete imagery set can be obtained.

Harnden, E.↗

The Large Angle Spectroscopic Coronagraph (LASCO): Visible light coronal imaging and spectroscopy

The Large Angle Spectroscopic Coronagraph (LASCO) is a triple coronagraph being jointly developed for the Solar and Heliospheric Observatory (SOHO) mission. LASCO comprises three nested coronagraphs (C1, C2, and C3) that image the solar corona for 1.1 to 30 solar radii (C1: 1.1 to 3 solar radii, C2: 1.5 to 6 solar radii, and C3: 3 to 30.0 solar radii). The inner coronagraph (C1) is a newly developed mirror version of the classic Lyot coronagraph without an external occultor, while the middle coronagraph (C2) and the outer coronagraph (C3) are externally occulted instruments. High resolution coronal spectroscopy from 1.1 to 3 R solar radii can be performed by using a Fabry-Perot interferometer, which is part of C1. High volume memories and a high speed microprocessor enable extensive onboard image processing. Image compression by factors of 10 to 20 will result in the transmission of 10 to 20 full images per hour.

Brueckner, Guenter E.↗