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The Challenges of Measuring Methane from Space with a Lidar

The global and regional quantification of methane fluxes and identification of its sources and sinks has been highlighted as one of the goals of the NASA 2017 Earth Science Decadal Survey. Detecting methane from space and airborne platforms with an active (laser) remote sensing instrument presents several unique technology and measurement challenges. The instrument must have a single frequency, narrow-linewidth light source, and photon-sensitive detector at the right spectral region to make continuous measurements from orbit, day and night, all seasons and at all latitudes. It must have a high signal to noise ratio and must be relatively immune to biases from aerosol/cloud scattering, spectroscopic and meteorological data uncertainties, and instrument systematic errors. At Goddard Space Flight Center (GSFC), in collaboration with industry, we have developed an airborne instrument to measure methane. Our instrument is a nadir-viewing lidar that uses Integrated Path Differential Absorption (IPDA), to measure methane near 1.65 µm. We sample the absorption line using multiple wavelengths from a narrow linewidth laser source and a sensitive photodetector. This measurement approach provides maximum information content about the CH4 column, and minimizes biases in the XCH4 retrieval. In this paper, we will review our progress to date and discuss the technology challenges, options and tradeoffs to measure methane from space and airborne platforms.

airborne instruments↗

Development of a Batch Fabrication Process for Chemical Nanosensors: Recent Advancements at NASA Glenn Research Center

A major objective in aerospace sensor development is to produce sensors that are small in size, easy to batch fabricate and low in cost, and have low power consumption. Chemical sensors involving nanostructured materials can provide these characteristics as well as the potential for the development of sensor systems with unique properties and improved performance. However, the fabrication and processing of nanostructures for sensor applications currently is limited by the ability to control their location on the sensor platform, which in turn hinders the progress for batch fabrication. This presentation will discuss the following: the development of a novel room temperature methane (CH4) sensor fabricated using porous tin oxide (SnO2) nanorods as the sensing material, the advantages of using nanomaterials in sensor designs, the challenges encountered with the integration of nanostructures into microsensordevices, and the different methods that have been attempted to address these challenges. An approach for the mass production of sensors with nanostructures using a method developed by our group at the NASA Glenn Research Center to control the alignment of nanostructures onto a sensor platform will also be described.

Nanotechnology↗

Gulf of Mexico Health & Air Quality: Mapping Methane Emission Plumes Using Sunglint-configured Imagery for Monitoring Offshore Oil and Gas Activity

We had three project objectives that we set out to accomplish. The first objective is to demonstrate how remote sensing can complement the current bottom-up methane emission assessments. Currently, quantities of disposed gas vented and flared are self-reported by operators to BOEM and BSEE. Meanwhile, inspections are uncommon, and ground sensors are non-existent. Therefore, remote sensing may be the agencies' best bet in verifying these operator accounts. The second objective is to identify methane plumes in the Gulf of Mexico, Asia, and elsewhere using Sentinel-2, LandSat, and PRISMA images, and then present an estimate of their emission rate. While methane retrievals from oil and gas infrastructure on-shore has been relatively well-documented, doing so on the offshore oil and gas platforms is more difficult, less prevalent, and contingent on the presence of specific conditions. The final objective is to give our partners, BOEM and BSEE, a more robust understanding of methane emissions from oil and gas production in the Gulf of Mexico. This increased knowledge, paired with a demonstration of methane monitoring, is intended to help our partners think about how they can incorporate remote sensing into their monitoring, regulatory and enforcement framework.

Ben Dahan↗

A New Remote Sensing Filter Radiometer Employing a Fabry-Perot Etalon and a CCD Camera for Column Measurements of Methane in the Earth Atmosphere

A portable remote sensing system for precision column measurements of methane has been developed, built and tested at NASA GSFC. The sensor covers the spectral range from 1.636 micrometers to 1.646 micrometers, employs an air-gapped Fabry-Perot filter and a CCD camera and has a potential to operate from a variety of platforms. The detector is an XS-1.7-320 camera unit from Xenics Infrared solutions which combines an uncooled InGaAs detector array working up to 1.7 micrometers. Custom software was developed in addition to the graphical user basic interface X-Control provided by the company to help save and process the data. The technique and setup can be used to measure other trace gases in the atmosphere with minimal changes of the etalon and the prefilter. In this paper we describe the calibration of the system using several different approaches.

Georgieva, E. M.↗

Detecting Methane From Leaking Pipelines and as Greenhouse Gas in the Atmosphere

Laser remote sensing measurements of trace gases from orbit can provide unprecedented information about important planetary science and answer critical questions about planetary atmospheres. Methane (CH4) is the second most important anthropogenically produced greenhouse gas. Though its atmospheric abundance is much less than that of CO2 (1.78 ppm vs. 380 ppm), it has much larger greenhouse heating potential. CH4 also contributes to pollution in the lower atmosphere through chemical reactions, leading to ozone production. Atmospheric CH4 concentrations have been increasing as a result of increased fossil fuel production, rice farming, livestock, and landfills. Natural sources of CH4 include wetlands, wild fires, and termites, and perhaps other unknown sources. Important sinks for CH4 include non-saturated soils and oxidation by hydroxyl radicals in the atmosphere. Remotely measuring CH4 and other biogenic molecules (such as ethane and formaldehyde) on Mars also has important implications on the existence of life on Mars. Measuring CH4 at very low (ppb) concentrations from orbit will dramatically improve the sensitivity and spatial resolution in the search for CH4 vents and sub-surface life on other planets. A capability has been developed using lasers and spectroscopic detection techniques for the remote measurements of trace gases in open paths. Detection of CH4, CO2, H2O, and CO in absorption cells and in open paths, both in the mid- IR and near-IR region, has been demonstrated using an Optical Parametric Amplifier laser transmitter developed at GSFC. With this transmitter, it would be possible to develop a remote sensing methane instrument. CH4 detection also has very important commercial applications. Pipeline leak detection from an aircraft or a helicopter can significantly reduce cost, response time, and pinpoint the location. The main advantage is the ability to rapidly detect CH4 leaks remotely. This is extremely important for the petrochemical industry. This capability can be used in manned or unmanned airborne platforms for the detection of leaks in pipelines and other areas of interest where a CH4 leak is suspected.

Riris, Haris↗

Performance Simulations for a Spaceborne Methane Lidar Mission

Future spaceborne lidar measurements of key anthropogenic greenhouse gases are expected to close current observational gaps particularly over remote, polar, and aerosol-contaminated regions, where actual in situ and passive remote sensing observation techniques have difficulties. For methane, a "Methane Remote Lidar Mission" was proposed by Deutsches Zentrum fuer Luft- und Raumfahrt and Centre National d'Etudes Spatiales in the frame of a German-French climate monitoring initiative. Simulations assess the performance of this mission with the help of Moderate Resolution Imaging Spectroradiometer and Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations of the earth's surface albedo and atmospheric optical depth. These are key environmental parameters for integrated path differential absorption lidar which uses the surface backscatter to measure the total atmospheric methane column. Results showthat a lidar with an average optical power of 0.45W at 1.6 μm wavelength and a telescope diameter of 0.55 m, installed on a low Earth orbit platform(506 km), will measure methane columns at precisions of 1.2%, 1.7%, and 2.1% over land, water, and snow or ice surfaces, respectively, for monthly aggregated measurement samples within areas of 50 × 50 km2. Globally, the mean precision for the simulated year 2007 is 1.6%, with a standard deviation of 0.7%. At high latitudes, a lower reflectance due to snow and ice is compensated by denser measurements, owing to the orbital pattern. Over key methane source regions such as densely populated areas, boreal and tropical wetlands, or permafrost, our simulations show that the measurement precision will be between 1 and 2%.

methane↗

Atmospheric Instrument Systems and Technology in the Goddard Earth Sciences Division

Studies of the Earth’s atmosphere require a comprehensive set of observations that rely on instruments flown on spacecraft, aircraft, and balloons as well as those deployed on the surface. Within NASA’s Goddard Space Flight Center (GSFC) Earth Sciences Division-Atmospheres, laboratories and offices maintain an active program of instrument system development and observational studies that provide: 1) information leading to a basic understanding of atmospheric processes and their relationships with the Earth’s climate system, 2) prototypes for future flight instruments, 3) instruments to serve as calibration references for satellite missions, and 4) instruments for future field validation campaigns that support ongoing space missions. Our scientists participate in all aspects of instrument activity, including component and system design, calibration techniques, retrieval algorithm development, and data processing systems. The Atmospheres Program has well-equipped labs and test equipment to support the development and testing of instrument systems, such as a radiometric calibration and development facility to support the calibration of ultraviolet and visible (UV/VIS), space-borne solar backscatter instruments. This document summarizes the features and characteristics of 46 instrument systems that currently exist or are under development. The report is organized according to active, passive, or in situ remote sensing across the electromagnetic spectrum. Most of the systems are considered operational in that they have demonstrated performance in the field and are capable of being deployed on relatively short notice. Other systems are under study or of low technical readiness level (TRL). The systems described herein are designed mainly for surface or airborne platforms. However, two Cubesat systems also have been developed through collaborative efforts. The Solar Disk Sextant (SDS) is the single balloon-borne instrument. The lidar systems described herein are designed to retrieve clouds, aerosols, methane, water vapor pressure, temperature, and winds. Most of the lasers operate at some wavelength combination of 355, 532, and 1064 nm. The various systems provide high sensitivity measurements based on returns from backscatter or Raman scattering including intensity and polarization. Measurements of the frequency (Doppler) shift of light scattered from various atmospheric constitutes can also be made. Microwave sensors consist of both active (radar) and passive (radiometer) systems. These systems are important for studying processes involving water in various forms. The dielectric properties of water affect microwave brightness temperatures, which are used to retrieve atmospheric parameters such as rainfall rate and other key elements of the hydrological cycle. Atmosphere radar systems operate in the range from 9.6 GHz to 94 GHz and have measurement accuracies from -5 to 1 dBZ; radiometers operate in the 50 GHz to 874 GHz range with accuracies from 0.5 to 1 degree K; conical and cross-track scan modes are used. Our passive optical sensors, consisting of radiometers and spectrometers, collectively operate from the UV into the infrared. These systems measure energy fluxes and atmospheric parameters such as trace gases, aerosols, cloud properties, or altitude profiles of various species. Imager spatial resolution varies from 37 m to 400 m depending on altitude; spectral resolution is as small as 0.5 nm. Many of the airborne systems have been developed to fly on multiple aircraft.

Platnick, Steven E.↗

NASA Tech Briefs, April 2012

Topics include: Computational Ghost Imaging for Remote Sensing; Digital Architecture for a Trace Gas Sensor Platform; Dispersed Fringe Sensing Analysis - DFSA; Indium Tin Oxide Resistor-Based Nitric Oxide Microsensors; Gas Composition Sensing Using Carbon Nanotube Arrays; Sensor for Boundary Shear Stress in Fluid Flow; Model-Based Method for Sensor Validation; Qualification of Engineering Camera for Long-Duration Deep Space Missions; Remotely Powered Reconfigurable Receiver for Extreme Environment Sensing Platforms; Bump Bonding Using Metal-Coated Carbon Nanotubes; In Situ Mosaic Brightness Correction; Simplex GPS and InSAR Inversion Software; Virtual Machine Language 2.1; Multi-Scale Three-Dimensional Variational Data Assimilation System for Coastal Ocean Prediction; Pandora Operation and Analysis Software; Fabrication of a Cryogenic Bias Filter for Ultrasensitive Focal Plane; Processing of Nanosensors Using a Sacrificial Template Approach; High-Temperature Shape Memory Polymers; Modular Flooring System; Non-Toxic, Low-Freezing, Drop-In Replacement Heat Transfer Fluids; Materials That Enhance Efficiency and Radiation Resistance of Solar Cells; Low-Cost, Rugged High-Vacuum System; Static Gas-Charging Plug; Floating Oil-Spill Containment Device; Stemless Ball Valve; Improving Balance Function Using Low Levels of Electrical Stimulation of the Balance Organs; Oxygen-Methane Thruster; Lunar Navigation Determination System - LaNDS; Launch Method for Kites in Low-Wind or No-Wind Conditions; Supercritical CO2 Cleaning System for Planetary Protection and Contamination Control Applications; Design and Performance of a Wideband Radio Telescope; Finite Element Models for Electron Beam Freeform Fabrication Process Autonomous Information Unit for Fine-Grain Data Access Control and Information Protection in a Net-Centric System; Vehicle Detection for RCTA/ANS (Autonomous Navigation System); Image Mapping and Visual Attention on the Sensory Ego-Sphere; HyDE Framework for Stochastic and Hybrid Model-Based Diagnosis; and IMAGESEER - IMAGEs for Education and Research.

Source record↗

Titan Airship Surveyor

Saturn's moon Titan is considered to be one of the prime candidates for studying prebiotic materials - the substances that precede the formation of life but have disappeared from the Earth as a result of the evolution of life. A unique combination of a dense, predominantly nitrogen, atmosphere (more than four times that of the Earth), low gravity (six times less than on the Earth) and small temperature variations makes Titan the almost ideal planet for studies with lighter-than-air aerial platforms (aerobots). Moreover, since methane clouds and photochemical haze obscure the surface, low-altitude aerial platforms are the only practical means that can provide global mapping of the Titan surface at visible and infrared wavelengths. One major challenge in Titan exploration is the extremely cold atmosphere (approx. 90 K). However, current material technology the capability to operate aerobots at these very low temperatures. A second challenge is the remoteness from the Sun (10 AU) that makes the nuclear (radioisotopic) energy the only practical source of power. A third challenge is remoteness from the Earth (approx. 10 AU, two-way light-time approx. 160 min) which imposes restrictions on data rates and makes impractical any meaningful real-time control. A small-size airship (approx. 25 cu m) can carry a payload approximately 100 kg. A Stirling engine coupled to a radioisotope heat source would be the prime choice for producing both mechanical and electrical power for sensing, control, and communications. The cold atmospheric temperature makes Stirling machines especially effective. With the radioisotope power source the airship may fly with speed approximately 5 m/s for a year or more providing an excellent platform for in situ atmosphere measurements and a high-resolution remote sensing with unlimited access on a global scale. In a station-keeping mode the airship can be used for in situ studies on the surface by winching down an instrument package. Floating above the surface allows relatively simple means for flight control. Mission requirements and possible methods of navigation, control, data acquisition, and communications are discussed. The presentation describes also the state-of-the art and current progress in aerial deployed aerobots.

Kerzhanovich, V.↗

Capturing Complete Spatial Context in Satellite Observations of Greenhouse Gases

Scientific consensus from a 2015 pre-Decadal Survey workshop highlighted the essential need for a wide-swath (mapping) low earth orbit (LEO) instrument delivering carbon dioxide (CO2), methane (CH4), and carbon monoxide (CO) measurements with global coverage. OCO-2 pioneered space-based CO2 remote sensing, but lacks the CH4, CO and mapping capabilities required for an improved understanding of the global carbon cycle. The Carbon Balance Observatory (CARBO) advances key technologies to enable high-performance, cost-effective solutions for a space-based carbon-climate observing system. CARBO is a compact, modular, 15-30° field of view spectrometer that delivers high-precision CO2, CH4, CO and solar induced chlorophyll fluorescence (SIF) data with weekly global coverage from LEO. CARBO employs innovative immersion grating technologies to achieve diffraction-limited performance with OCO-like spatial (2 x 2 sq.km) and spectral (λ/Δλ≈ 20,000) resolution in a package that is >50% smaller, lighter and more cost-effective. CARBO delivers a 25- to 50-fold increase in spatial coverage compared to OCO-2 with no loss of detection sensitivity. Individual CARBO modules weigh < 20 kg, opening diverse new space-based platform opportunities.

Miller, Charles E.↗

Differential absorption lidar (DIAL) for water vapor and aerosol profiling from airborne and space-based platforms

Many current challenges in weather and climate prediction involve cloud and aerosol processes, which are intimately linked to processes that initiate or take place within the planetary boundary layer (PBL). The current space-based observing system provides a wealth of information on the spatial distribution of key atmospheric variables such as profiles of water vapor (WV) and temperature, but lacks the sensitivity, accuracy, and vertical resolution in the PBL to overcome the observational gaps that inhibit the parametrization and advancement of current climate and weather models. To overcome some of these observational gaps and improve understanding and monitoring of these key processes, mature remote sensing techniques like Differential Absorption Lidar (DIAL) can be employed from various platforms to capture processes on a wide range of spatial scales. This presentation will provide an overview of NASA’s water vapor DIAL capabilities, present the strengths, weaknesses, and synergies of the DIAL technique relative to traditional methods, and provide representative data examples from the HALO airborne water vapor DIAL which was designed as a technology testbed for future space-based DIAL missions as well as a workhorse instrument in support of suborbital process studies. HALO is an airborne multifunction lidar system, simultaneously profiling WV with the DIAL technique and aerosol and cloud optical properties and PBL heights via the high spectral resolution lidar (HSRL) technique. HALO has a compact design that allows it to fly on most research aircraft, enabling nadir profiling from the lower stratosphere down through the PBL, which is critical for studying processes such as convection and cloud formation that can link the PBL and free troposphere. We will end with an outlook on the benefits and challenges of transitioning the mature DIAL technique to space to compliment other active and passive sounders and enable new PBL observations for the future Earth Observing System. The Atmospheric Boundary layer Lidar pathfindEr (ABLE), a program aimed at advancing technologies to enable the first demonstration of DIAL from space with cross-cutting observables of PBL heights, aerosol and cloud profiling, and methane columns from space will also be presented.

Brian J. Carroll↗

Phase 1 Final Report: Titan Submarine

The conceptual design of a submarine for Saturn's moon Titan was a funded NASA Innovative Advanced Concepts (NIAC) Phase 1 for 2014. The proposal stated the desire to investigate what science a submarine for Titan's liquid hydrocarbon seas might accomplish and what that submarine might look like. Focusing on a flagship class science system (100 kg), it was found that a submersible platform can accomplish extensive science both above and below the surface of the Kraken Mare. Submerged science includes mapping using side-looking sonar, imaging and spectroscopy of the lake, as well as sampling of the lake's bottom and shallow shoreline. While surfaced, the submarine will not only sense weather conditions (including the interaction between the liquid and atmosphere) but also image the shoreline, as much as 2 km inland. This imaging requirement pushed the landing date to Titan's next summer period (2047) to allow for lighted conditions, as well as direct-to-Earth communication, avoiding the need for a separate relay orbiter spacecraft. Submerged and surfaced investigation are key to understanding both the hydrological cycle of Titan as well as gather hints to how life may have begun on Earth using liquid, sediment, and chemical interactions. An estimated 25 Mb of data per day would be generated by the various science packages. Most of the science packages (electronics at least) can be safely kept inside the submarine pressure vessel and warmed by the isotope power system.The baseline 90-day mission would be to sail submerged and surfaced around and through Kraken Mare investigating the shoreline and inlets to evaluate the sedimentary interaction both on the surface and then below. Depths of Kraken have yet to be sensed (Ligeia to the north is thought to be 200 m (656 ft) deep), but a maximum depth of 1,000 m (3,281 ft) for Kraken Mare was assumed for the design). The sub would spend 20 d at the interface between Kraken Mare and Ligeia Mare for clues to the drainage of liquid methane into the currently predicted predominantly ethane Kraken Mare. During an extended ninety-day mission, it would transit the throat of Kraken (now Seldon Fretum) and perform similar explorations in other areas of Kraken Mare. Once this half year of exploration is completed the submarine could be tasked to revisit points of interest and perhaps do a complete sonar mapping of the seas. All in all, the submarine could explore over 3,000 km (1,864 mi) in its primary mission at an average speed of 0.3 meters per second.

Titan↗

Validation of Carbon Trace Gas Profile Retrievals from the NOAA-Unique Combined Atmospheric Processing System for the Cross-Track Infrared Sounder

This paper provides an overview of the validation of National Oceanic and Atmospheric Administration (NOAA) operational retrievals of atmospheric carbon trace gas profiles, specifically carbon monoxide (CO), methane (CH4) and carbon dioxide (CO2), from the NOAA-Unique Combined Atmospheric Processing System (NUCAPS), a NOAA enterprise algorithm that retrieves atmospheric profile environmental data records (EDRs) under global non-precipitating (clear to partly cloudy) conditions. Vertical information about atmospheric trace gases is obtained from the Cross-track Infrared Sounder (CrIS), an infrared Fourier transform spectrometer that measures high resolution Earth radiance spectra from NOAA operational low earth orbit (LEO) satellites, including the Suomi National Polar-orbiting Partnership (SNPP) and follow-on Joint Polar Satellite System (JPSS) series beginning with NOAA-20. The NUCAPS CO, CH4, and CO2 profile EDRs are rigorously validated in this paper using well-established independent truth datasets, namely total column data from ground-based Total Carbon Column Observing Network (TCCON) sites, and in situ vertical profile data obtained from aircraft and balloon platforms via the NASA Atmospheric Tomography (ATom) mission and NOAA AirCore sampler, respectively. Statistical analyses using these datasets demonstrate that the NUCAPS carbon gas profile EDRs generally meet JPSS Level 1 global performance requirements, with the absolute accuracy and precision of CO 5% and 15%, respectively, in layers where CrIS has vertical sensitivity; CH4 and CO2 product accuracies are both found to be within ±1%, with precisions of ≈1.5% and ⪅0.5%, respectively, throughout the tropospheric column.

satellite cal/val; error analysis; greenhouse gase↗