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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Broadband photoexcitation of lasers

Existing techniques are reviewed and novel approaches for broadband photoexcitation of lasers are discussed. This subject is of interest because of the emergence of future intense near equilibrium and blackbody sources, such as the gas core reactor, and electric discharge plasma devices, which are the key to the development of intense broadband radiation sources. The possible use of radiation from solar concentrators in space also fits into this general area. The varied use of photoexcitation of lasers are discussed ranging over direct optical pumping, photodissociation, and photoreionization. In addition, the new uses of laser transitions and chemical reactions is shown. This is accomplished through multiline operation of high pressure tunable lasers which can use the broadband radiation for multiphoton excitation.

Hess, R. V.↗

Electron collisional excitation and resonant photoexcitation of solar S XI

The line emission of carbon-like S XI is predicted using a comprehensive 46-level model including the configurations 2p2, 2s2p3, 2p3s, 2p4, 2p3p, 2p3d. Relative intensities of allowed, intercombination, and forbidden lines are computed for quiet and active solar conditions. The process of photoexcitation by the Fe XIII 191.26 A line is included to study its effect on EUV lines and the infrared forbidden lines at 1.92 and 1.39 microns. It is concluded that an observation of the 1.92-micron line by Olsen, Anderson, and Stewart (1971) is consistent with quiet solar conditions in the absence of photoexcitation.

Kastner, S. O.↗

Testing integrated circuits by photoexcitation

System for testing integrated circuits uses photoexcitation to determine quality of internal elements inaccessible to electrical tests. Approach prevents direct monitoring of internal operation of circuit by measurements at external terminals and is superior to electron beam scanning due to nondestructiveness.

Erickson, J. J.↗

Photoexcitation and ionization in carbon dioxide - Theoretical studies in the separated-channel static-exchange approximation

Vertical-electronic static-exchange photoexcitation and ionization cross sections are reported which provide a first approximation to the complete dipole spectrum of CO2. Separated-channel static-exchange calculations of vertical-electronic transition energies and oscillator strengths, and Stieltjes-Chebyshev moment methods were used in the development. Detailed comparisons were made of the static-exchange excitation and ionization spectra with photoabsorption, electron-impact excitation, and quantum-defect estimates of discrete transition energies and intensities, and with partial-channel photoionization cross sections obtained from fluorescence measurements and from tunable-source and (e, 2e) photoelectron spectroscopy. Results show that the separate-channel static-exchange approximation is generally satisfactory in CO2.

Padial, N.↗

The solar spectrum of O IV, including photoexcitation by Fe IX 171.07 A

The extreme and far ultraviolet doublet spectrum of O IV, emitted from the solar transition region, is calculated taking account of expected photo-excitation by Fe IX at the wavelength 171.07 A. Four multiplets are shown to be sensitive to such photoexcitation, of which two in particular are potentially observable and could provide an estimate of the local Fe IX radiation field.

Kastner, S. O.↗

Indirect IUE observation of O VI from photoexcited fluorescence lines of Fe II, present in the spectrum of RR Telescopii

A new, highly excited level of Fe II at 13.7 eV has been established by means of six lines in the laboratory spectrum below 2000 A. Confirming transitions appear in the infrared region. Four of the ultraviolet lines coincide with previously unidentified lines in the IUE spectrum of RR Tel reported by Penston et al. in 1983. One of the remaining UV lines coincides with the resonance line of O VI at 1032 A, outside the range of the IUE. This suggests that the new FE II level is selectively photoexcited by O VI in RR Tel, resulting in the strong fluorescence lines observed. This case of a Bowen mechanism provides an indirect observation of O VI, important for diagnostics of, e.g., symbiotic stars.

Johansson, Sveneric↗

Photoexcited escape probability, optical gain, and noise in quantum well infrared photodetectors

We present a detailed and thorough study of a wide variety of quantum well infrared photodetectors (QWIPs), which were chosen to have large differences in their optical and transport properties. Both n- and p-doped QWIPs, as well as intersubband transitions based on photoexcitation from bound-to-bound, bound-to-quasi-continuum, and bound-to-continuum quantum well states were investigated. The measurements and theoretical analysis included optical absorption, responsivity, dark current, current noise, optical gain, hot carrier mean free path; net quantum efficiency, quantum well escape probability, quantum well escape time, as well as detectivity. These results allow a better understanding of the optical and transport physics and thus a better optimization of the QWIP performance.

Levine, B. F.↗

Photoexcitation of lasers and chemical reactions for NASA missions: A theoretical study

The possibility of obtaining CW laser oscillation by optical pumping in the infrared at an elevated gas pressure is reviewed. A specific example utilizing a mixture of CO and NO gases is included. The gas pressures considered are in excess of several atmospheres. Laser frequency tuning over a broad region becomes possible at such elevated gas pressures due to collisional broadening of the amplifying transitions. The prior-rate and surprisal analysis are applied to obtain detailed VV and VT rates for CO and NO molecules and the transfer rates in a CO-NO gas mixture. The analysis is capable of giving temperature dependence of the rate constants. Computer estimates of the rates are presented for vibrational levels up to v = 50. The results show that in the high-lying vibrational states the VV transfer rates with Delta nu = 2 become appreciable.

Javan, A.↗

Theoretical studies of photoexcitation and ionization in H2O

Theoretical studies using Franck-Condon and static-exchange approximations are reported for the complete dipole excitation and ionization spectrum in H2O, where (1) large Cartesian Gaussian basis sets are used to represent the required discrete and continuum electronic eigenfunctions at the ground state equilibrium geometry, and (2) previously devised moment-theory techniques are employed in constructing the continuum oscillator-strength densities from the calculated spectra. Comparisons are made of the calculated excitation and ionization profiles with recent experimental photoabsorption studies and corresponding spectral assignments, electron impact-excitation cross sections, and dipole and synchrotron-radiation studies of partial-channel photoionization cross sections. The calculated partial-channel cross sections are found to be atomic-like, and dominated by 2p-kd components. It is suggested that the latter transition couples with the underlying 1b(1)-kb(1) channel, accounting for a prominent feature in recent synchrotron-radiation measurements.

Diercksen, G. H. F.↗

Study of sulfur-containing molecules in the EUV region. III Photoexcitation of CS2

Using synchrotron radiation as a continuum background, the absorption cross section of CS2 has been measured using a double ionization chamber. The cross sections range from four to a maximum value of 65 Mb in the 175-760 A region. Two new Rydberg series X and XI have been identified and apparently converge to the D2Pi state of CS2(+) at 16.943 eV.

Wu, C. Y. R.↗

Quantitative photoexcitation and fluorescence studies of C2H2 in vacuum ultraviolet

Synchrotron radiation light source measurements were conducted in the 105-155 nm region to obtain the photoabsorption and fluorescence cross sections of C2H2, and the quantum yield for producing the C2H-asterisk fluorescence from C2H2's photodissociation was measured in the 106-136.5 nm region. The products of the radiative lifetime quenching rate constant increase with excitation wavelengths. The data obtained on lifetimes, quenchings, and fluorescence spectra point to an upper state of the C2H-asterisk fluorescence that is well bound, while the lower state is a repulsive or weak-bound state.

Suto, M.↗