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At least 19 records

Unrealized Critical Lanthanide Extraction from Sea Algae Mining (UNCLE SAM): Domestic production of critical minerals from seawater

The UNCLE-SAM project, under the Biotechnologies to Ensure a Robust Supply of Critical Materials for Clean Energy program, examined the biomining applications of seaweeds for sustainable, domestic production of critical mineral feedstocks. The ocean is a vast reserve of mineralogical wealth including rare earth elements (REEs) and platinum group metal (PGMs). These elements, categorized as “critical minerals”, are used in telecommunication devices, lasers, LED lighting, turbine generators, electric car motors, jet engine alloys, and many other applications. These critical elements are increasingly vital to a thriving, efficient and sustainable society. However, only a few countries in the global market currently produce and export REEs, leading to potential geopolitical supply disruptions. Marine macroalgae, often referred to as seaweeds, bioconcentrate critical minerals from seawater, including REEs and PGMs. Marine algae cultivation can generate a significant amount of biomass with minimal freshwater, fertilizer, and land requirements. In summary, the UNCLE-SAM project successfully evaluated the technological feasibility for marine macroalgal cultivation as a feedstock for critical minerals, explored the biological capacity of different seaweeds to provide economically relevant domestic mineral production, assessed processing techniques for thermal co-conversion of seaweeds into renewable fuel and mineral feedstocks, and executed techno-economic and lifecycle assessments for identifying the most critical gaps in our current understanding to move the technology into commercially relevant deployment. Further development of this technology could transform the bioproduct and REE mining industries and catalyze the development of a more sustainable future.

58 GEOSCIENCES↗

UNrealized Critical Lanthanide Extraction from Sea Algae Mining (UNCLE SAM)

The UNCLE-SAM project, under the Biotechnologies to Ensure a Robust Supply of Critical Materials for Clean Energy program, examined the biomining applications of seaweeds for sustainable, domestic production of critical mineral feedstocks. The ocean is a vast reserve of mineralogical wealth including rare earth elements (REEs) and platinum group metal (PGMs). These elements, categorized as “critical minerals”, are used in telecommunication devices, lasers, LED lighting, turbine generators, electric car motors, jet engine alloys, and many other applications. These critical elements are increasingly vital to a thriving, efficient and sustainable society. However, only a few countries in the global market currently produce and export REEs, leading to potential geopolitical supply disruptions. Marine macroalgae, often referred to as seaweeds, bioconcentrate critical minerals from seawater, including REEs and PGMs. Marine algae cultivation can generate a significant amount of biomass with minimal freshwater, fertilizer, and land requirements. In summary, the UNCLE-SAM project successfully evaluated the technological feasibility for marine macroalgal cultivation as a feedstock for critical minerals, explored the biological capacity of different seaweeds to provide economically relevant domestic mineral production, assessed processing techniques for thermal co-conversion of seaweeds into renewable fuel and mineral feedstocks, and executed techno-economic and lifecycle assessments for identifying the most critical gaps in our current understanding to move the technology into commercially relevant deployment. Further development of this technology could transform the bioproduct and REE mining industries and catalyze the development of a more sustainable future.

09 BIOMASS FUELS↗

Materials Data on UNCl by Materials Project

UNCl is Matlockite structured and crystallizes in the tetragonal P4/nmm space group. The structure is three-dimensional. U4+ is bonded in a 4-coordinate geometry to four equivalent N3- and five equivalent Cl1- atoms. All U–N bond lengths are 2.25 Å. There are four shorter (3.12 Å) and one longer (3.33 Å) U–Cl bond lengths. N3- is bonded to four equivalent U4+ atoms to form a mixture of edge and corner-sharing NU4 tetrahedra. Cl1- is bonded in a 5-coordinate geometry to five equivalent U4+ atoms.

36 MATERIALS SCIENCE↗

Neutron Rodeo Phase II Final Report

The ability to perform nondestructive assay (NDA) of fresh fuel assemblies with high precision in reasonable measurement times is significant for nuclear nonproliferation and safeguards. The current methodology used by the International Atomic Energy Agency (IAEA) for NDA of fresh fuel assemblies involves a He-3 based Uranium Neutron Collar (UNCL) system, which is an active coincidence counting system designed to measure time-correlated neutron doubles from induced fissions within the assembly. The UNCL system provides an easily implementable process of quantifying the 235 U linear density of the fresh fuel assemblies; however, operational limitations of the UNCL include long assay times and adverse sensitivity to poisoned assemblies. This has engendered investigation in alternative detector materials for fast-neutron counting to rectify some of these current limitations in the UNCL. The potential improvements of using fast-neutron organic scintillators (e.g. liquid scintillators, stilbene, PSDcapable plastics, etc.) was compared directly to the original Uranium Neutron Collar (UNCL) in-detail during the initial Advanced Neutron Detection Technology Rodeo. The simulation results showed that these alternative detector materials can provide an improvement in the assay time required to reach a suitable precision due to both their lower sensitivity to the interrogation source neutrons (i.e. AmLi neutrons) and their inherently shorter coincidence gate widths. The IAEA has developed a liquid scintillator-based Fast-Neutron Collar (FNCL) as a potential replacement system for the UNCL.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Evaluation of B10Plus+* proportional detectors for neutron coincidence counting

GE-Reuter-Stokes (GERS) has developed a new line of neutron proportional counters, the B10Plus+* proportional counter. The detector design is intended to serve as a cost-effective alternative to traditional {sup 3}He proportional counters in a variety of applications. The detector is a hybrid design 10B-lined tube optimized with the addition of a small quantity of 3He gas to improve the detector performance and efficiency. As a demonstration of the B10Plus+* detector, GERS has constructed a Uranium Neutron Collar (UNCL) system consisting of B-10Plus+* proportional counters. GERS has designed and built a demonstration UNCL system intended to match the performance of a Type-I UNCL design in Pressurized Water Reactor (PWR) geometry operating in thermal mode. GERS offered their system on loan to the International Atomic Energy Agency (IAEA) Safeguards Division of Technical and Scientific Services for an assessment of the detector technology and the demonstration system. We have characterized the demonstration UNCL system and compared its performance with a traditional Type-I UNCL design in regular use by the IAEA. This paper summarizes our findings and observations during the characterization and testing activity. (authors)

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Simulations of a PSD Plastic Neutron Collar for Assaying Fresh Fuel

The potential performance of a notional active coincidence collar for assaying uranium fuel based on segmented detectors constructed from the new PSD plastic fast organic scintillator with pulse shape discrimination capability was investigated in simulation. Like the International Atomic Energy Agency's present Uranium Neutron Collar for LEU (UNCL), the PSD plastic collar would also function by stimulating fission in the 235 U content of the fuel with a moderated 241 Am/Li neutron source and detecting instances of induced fission via neutron coincidence counting. In contrast to the moderated detectors of the UNCL, the fast time scale of detection in the scintillator eliminates statistical errors due to accidental coincidences that limit the performance of the UNCL. However, the potential to detect a single neutron multiple times historically has been one of the properties of organic scintillator detectors that has prevented their adoption for international safeguards applications. Consequently, as part of the analysis of simulated data, a method was developed by which true neutron-neutron coincidences can be distinguished from inter-detector scatter that takes advantage of the position and timing resolution of segmented detectors. Then, the performance of the notional simulated coincidence collar was evaluated for assaying a variety of fresh fuels, including some containing burnable poisons and partial defects. In these simulations, particular attention was paid to the analysis of fast mode measurements. In fast mode, a Cd liner is placed inside the collar to shield the fuel from the interrogating source and detector moderators, thereby eliminating the thermal neutron flux that is most sensitive to the presence of burnable poisons that are ubiquitous in modern nuclear fuels. The simulations indicate that the predicted precision of fast mode measurements is similar to what can be achieved by the present UNCL in thermal mode. For example, the statistical accuracy of a ten-minute measurement of fission coincidences collected in fast mode will be approximately 1% for most fuels of interest, yielding a ~1.4% error after subtraction of a five minute measurement of the spontaneous fissions from 238 U in the fuel, a ~2% error in analyzed linear density after accounting for the slope of the calibration curve, and a ~2.9% total error after addition of an assumed systematic error of 2%.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

The DD Neutron Generator as an Alternative to Am(Li) Isotopic Neutron Source in the Uranium Neutron Coincidence Collar

The 235 U mass assay of bulk uranium items, such as oxide canisters, fuel pellets, and fuel assemblies, is not achievable by traditional gamma-ray assay techniques because of the limited penetration of the item by the characteristic 235 U gamma rays. Instead, fast neutron interrogation methods such as active neutron coincidence counting must be used. For international safeguards applications, the most commonly used active neutron systems, the Active Well Coincidence Counter (AWCC), Uranium Neutron Coincidence Collar (UNCL), and 252 Cf Shuffler, rely on fast neutron interrogation using an isotopic neutron source [i.e., 252 Cf or Am(Li)] to achieve better measurement accuracies than are possible using gamma-ray techniques for high-mass, high-density items. However, the Am(Li) sources required for the AWCC and UNCL systems are no longer manufactured, and newly produced systems rely on limited supplies of sources salvaged from disused instruments. The 252 Cf shuffler systems rely on the use of high-output 252 Cf sources, which while still available have become extremely costly for use in routine operations and require replacement every 5–7 years. Lack of a suitable alternative neutron interrogation source would leave a potentially significant gap in the safeguarding of uranium processing facilities. Previously we examined the performance of Oak Ridge National Laboratory’s Large Volume Active Well Coincidence Counter modified to accept a commercially available deuterium-deuterium (DD) neutron generator to examine the potential of the DD neutron generator as an alternative to the isotopic sources [1]. That work indicated that the DD generator was a viable replacement for the AWCC applications, but because of the large dimensions of that generator, the DD/AWCC would have to be run as a delayed neutron counting system to provide equivalent measurement precision. In this work we examine the performance of a standard UNCL modified to accept the DD neutron generator for the assay of 235 U based on the results of Monte Carlo N-Particle (MCNP) simulations and measurements of depleted uranium and highly enriched uranium items. The projected performance of the modified UNCL for fresh pressurized water reactor fuel assemblies operated in both traditional coincidence counting and delayed neutron counting modes is presented.

07 ISOTOPE AND RADIATION SOURCES↗

Sensitivity of the active neutron coincidence collar response during simulated and experimental fresh fuel assay

Verification of the fissile (and fertile) content in fresh nuclear fuel assemblies is conducted by the IAEA to enforce the Nuclear Non-Proliferation Treaty using the UNCL (Uranium Neutron Collar — Light Water Reactor Fuel). The UNCL uses an uncorrelated AmLi neutron source to interrogate the fuel, producing a signal of coincident fission neutrons (Doubles rate) used to assay 235 U content of the fuel. The cost of producing calibration assemblies and limited availability of diverse commercial assemblies at any one time historically restricted the ability to explore the full parameter space experimentally. Monte Carlo simulations can overcome this, but introduce additional sources of uncertainty. In this work, the sensitivity of simulations and measurements to various parameters is assessed for a reference 1616 PWR assembly of uniform 3.2% enrichment. Uncertainty contributions in this evaluation include: simulated AmLi neutron source spectrum, AmLi neutron emission rate, AmLi anisotropicity, high density polyethylene (HDPE) density, the precise position of the fuel assembly within the detector, and experimentally the statistical uncertainty. The overall total systematic uncertainty estimate for the simulation of the absolute/relative Doubles rates responses are estimated to be approximately 2.0%/1.5%, and for experimental measurements systematic uncertainty reduces to 1.1%. This analysis supports further work using the relative Doubles rates in place of measurements for updating and extending the UNCL analysis methodology as systematic uncertainty is reasonably small.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Validation of gamma-ray detection techniques for safeguards monitoring at natural uranium conversion facilities

Recent IAEA circulars and policy papers have sought to implement safeguards when any purified aqueous uranium solution or uranium oxides suitable for isotopic enrichment or fuel fabrication exists. Under the revised policy, IAEA Policy Paper 18, the starting point for nuclear material under safeguards was reinterpreted, suggesting that purified uranium compounds should be subject to safeguards procedures no later than the first point in the conversion process. In response to this technical need, a combination of simulation models and experimental measurements were employed to develop and validate concepts of nondestructive assay monitoring systems in a natural uranium conversion plant (NUCP). In particular, uranyl nitrate (UO 2 (NO 3 ) 2 ) solution exiting solvent extraction was identified as a key measurement point (KMP), where gamma-ray spectroscopy was selected as the process monitoring tool. The Uranyl Nitrate Calibration Loop Equipment (UNCLE) facility at Oak Ridge National Laboratory was employed to simulate the full-scale operating conditions of a purified uranium-bearing aqueous stream exiting the solvent extraction process in an NUCP. Nondestructive assay techniques using gamma-ray spectroscopy were evaluated to determine their viability as a technical means for drawing safeguards conclusions at NUCPs, and if the IAEA detection requirements of 1 significant quantity (SQ) can be met in a timely way. This work investigated gamma-ray signatures of uranyl nitrate circulating in the UNCLE facility and evaluated various gamma-ray detector sensitivities to uranyl nitrate. These detector validation activities include assessing detector responses to the uranyl nitrate gamma-ray signatures for spectrometers based on sodium iodide, lanthanum bromide, and high-purity germanium detectors. The results of measurements under static and dynamic operating conditions at concentrations ranging from 10–90 g U/L of natural uranyl nitrate are presented. A range of gamma-ray lines is examined, including attenuation for transmission measurement of density and concentration. It was determined that transmission-corrected gamma-ray spectra provide a reliable way to monitor the 235 U concentration of uranyl nitrate solution in transfer pipes in NUCPs. Furthermore, existing predictive and analysis methods are adequate to design and realize practical designs. The 137 Cs transmission source employed in this work is viable but not optimal for 235 U densitometry determination. Validated simulations assessed the viability of 133 Ba and 57Co as alternative densitometry sources. All three gamma-ray detectors are viable for monitoring natural uranium feed; although high-purity germanium is easiest to interpret, it is, however, the least attractive as an installation instrument. Overall, for monitoring throughput in a facility such as UNCLE, emulating the uranium concentration and pump speeds of the Springfields conversion facility in the United Kingdom, an uncertainty of less than 0.17% is required in order to detect the diversion of 1 SQ of uranyl nitrate through changes in uranium concentration over an accountancy period of one year with a detection probability of 50%. As a result, calibrated gamma-ray detection systems are capable of determining the concentration of uranium content in NUCPs, it is only in combination with verifiable operator declarations and supporting data, such as flow rate and enrichment, that safeguards conclusions can be drawn.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Technical basis for the use of a correlated neutron source in the uranium neutron coincidence collar

Active neutron coincidence systems are commonly used by international inspectorates to verify a material balance across the various stages of the nuclear fuel cycle. The Uranium Neutron Coincidence Collar (UNCL) is one such instrument; it is used to measure the linear density of 235 U (g 235 U/cm of active length in assembly) in fresh light water reactor fuel in nuclear fuel fabrication facilities. The UNCL and other active neutron interrogation detectors have historically relied on americium lithium ( 241 AmLi) sources to induce fission within the sample in question. Californium-252 is under consideration as a possible alternative to the traditional 241 AmLi source. Finally, this work relied upon a combination of experiments and Monte Carlo simulations to demonstrate the technical basis for the replacement of 241 AmLi sources with 252 Cf sources by evaluating the statistical uncertainty in the measurements incurred by each source and assessing the penetrability of neutrons from each source for the UNCL.

98 NUCLEAR DISARMAMENT, SAFEGUARDS, AND PHYSICAL P↗

Fast Neutron Passive Collar Optimization Report

The UNCL has been used for over thirty years for the verification of the 235 U content of LWR nuclear fuel.The most recent version of the detector, the UNCL-II, consists of four HDPE blocks, three containing 3He proportional counters and a fourth containing a slot for an AmLi source. [1] The 3He proportional counters have a nominal active length of 33 cm, a diameter of 2.54 cm and a gas pressure of 4 atm. The UNCL-II has cavity dimensions 41.4 x 23.4 x 23.4 cm.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Modernizing the active neutron collar poison rod correction using simulations to enhance PWR fresh fuel verification

The declared inventory of 235 U in fresh, low enriched uranium, nuclear fuel assemblies is routinely verified by nuclear safeguards inspectorates using the UNCL (Uranium Neutron Collar – Light Water Reactor Fuel) nondestructive assay instrument. The trend in modern fuels is towards higher initial enrichment, which in turn requires a larger number of burnable poison pins with higher Gadolinia concentration to hold down the initial reactivity. UNCL assay error for modern fuel assemblies typically exceeds 10%. The traditional algorithm used to correct the response for burnable poison content needs revision to achieve accuracy comparable to the $\sigma_\text{R}$ of 4.5% expected for poison-free assemblies. Here we review the problem and use a large set of 287 Monte Carlo simulations based on an experimentally benchmarked model corresponding to the 16×16 PWR array used in Brazilian Angra type II and III fuel. Simulated relative responses are used to evaluate the functional form of the poison correction and determine parameters optimal for 16×16 PWR assemblies. This update is conducted using between 4–24 Gadolinia pins ranging 2–11 wt% Gd 2 O 3 with assemblies having mean enrichments ranging 2.5%–5%. Experimental validation of the updated coefficients using seven measurements shows bias is reduced by an order of magnitude and $\sigma_\text{R}$R reduced from 10% to less than 2%. Two updated sets of coefficients are provided, the most accurate of which is directly useable in the existing analysis code (INCC) in use by inspectorate at fuel fabrication facilities.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Active Well Counting Using New PSD Plastic Detectors

This report presents results and analysis from a series of proof-of-concept measurements to assess the suitability of segmented detectors constructed from Eljen EJ-299-34 PSD-plastic scintillator with pulse-shape discrimination capability for the purposes of quantifying uranium via active neutron coincidence counting. Present quantification of bulk uranium materials for international safeguards and domestic materials control and accounting relies on active neutron coincidence counting systems, such as the Active Well Coincidence Counter (AWCC) and the Uranium Neutron Coincidence Collar (UNCL), that use moderated He-3 proportional counters along with necessarily low-intensity 241Am(Li) neutron sources. Scintillation-based fast-neutron detectors are a potentially superior technology to the existing AWCC and UNCL designs due to their spectroscopic capability and their inherently short neutron coincidence times that largely eliminate random coincidences and enable interrogation by stronger sources. One of the past impediments to the investigation and adoption of scintillation counters for the purpose of quantifying bulk uranium was the commercial availability of scintillators having the necessary neutron-gamma pulse-shape discrimination properties only as flammable liquids. Recently, Eljen EJ-299-34 PSD-plastic scintillator became commercially available. The present work is the first assessment of an array of PSD-plastic detectors for the purposes of quantifying bulk uranium. The detector panel used in the present work was originally built as the focal plane for a fast-neutron imager, but it was repurposed for the present investigation by construction of a stand to support the inner well of an AWCC immediately in front of the detector panel. The detector panel and data acquisition of this system are particularly well suited for performing active-well fast-neutron counting of LEU and HEU samples because the active detector volume is solid, the 241Am(Li) interrogating neutrons are largely below the detector threshold, and the segmented construction of the detector modules allow for separation of true neutron-neutron coincidences from inter-detector scattering using the kinematics of neutron scattering. The results from a series of measurements of a suite of uranium standards are presented, and compared to measurements of the same standards and source configurations using the AWCC. Using these results, the performance of the segmented detectors reconfigured as a well counter is predicted and outperforms the AWCC.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Improvements in Boron Plate Coating Technology for Higher Efficiency Neutron Detection and Coincidence Counting Error Reduction

This informal report presents the measurement data and information to document the performance of the advanced Precision Data Technology, Inc. (PDT) sealed cell boron-10 plate neutron detector that makes use of the advanced coating materials and procedures. In 2015, PDT changed the boron coating materials and application procedures to significantly increase the efficiency of their basic corrugated plate detector performance. A prototype sealed cell unit was supplied to LANL for testing and comparison with prior detector cells. Also, LANL had reference detector slabs from the original neutron collar (UNCL) and the new Antech UNCL with the removable 3He tubes. The comparison data is presented in this report.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Estimating the AmLi Neutron Spectrum from Measured Ring Ratios

These are a set of slides on estimating the AmLi neutron spectrum from measured ring ratios. The IAEA uses an AmLi source in the Uranium Neutron Coincidence Collar (UNCL) to verify compliance with nonproliferation treaties. The UNCL requires calibration with known uranium samples. The AmLi spectrum isn’t known well enough to allow simulated calibrations. Alphas lose energy traveling through AmO 2 particle of unknown size. Energy reduction below Li threshold enhances O contribution. Unknown Li matrix material affects neutron production and thermalization. There is large variation in spectra from each element. Other topics covered include: applications, physics considerations, current spectra, measurement overview, measurement results - variation between sources, simulations, spectra fitting, other simulations, and conclusions.

07 ISOTOPE AND RADIATION SOURCES↗

Boron-Coated Straw Collar for Uranium Neutron Coincidence Collar Replacement

The objective of this project was to design and optimize, in simulation space, an active neutron coincidence counter (or collar) using boron-coated straws (BCSs) as a non- 3 He replacement to the Uranium Neutron Coincidence Collar (UNCL). UNCL has been used by the International Atomic Energy Agency (IAEA) and European Atomic Energy Community (Euratom) since the 1980s to verify the 235 U content in fresh light water reactor fuel assemblies for safeguards purposes. This report documents the design and optimization of the BCS collar.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

The D-D Neutron Generator as an Alternative to Am(Li) Isotopic Neutron Source in the Active Well Coincidence Counter

The 235 U mass assay of bulk uranium items, such as oxide canisters, fuel pellets, and fuel assemblies, is not achievable by traditional gamma-ray assay techniques due to the limited penetration of the item by the characteristic 235 U gamma rays. Instead, fast neutron interrogation methods such as active neutron coincidence counting must be used. For international safeguards applications, the most commonly used active neutron systems, the Active Well Coincidence Counter (AWCC), Uranium Neutron Collar (UNCL) and 252 Cf Shuffler, rely on fast neutron interrogation using an isotopic neutron source [i.e., 252 Cf or Am(Li)] to achieve better measurement accuracies than are possible using gamma-ray techniques for high-mass, high-density items. However, the Am(Li) sources required for the AWCC and UNCL systems are no longer manufactured, and newly produced systems rely on limited supplies of sources salvaged from disused instruments. The 252 Cf shuffler systems rely on the use of high-output 252 Cf sources, which while still available have become extremely costly for use in routine operations and require replacement every five to seven years. Lack of a suitable alternative neutron interrogation source would leave a potentially significant gap in the safeguarding of uranium processing facilities. In this work, we made use of Oak Ridge National Laboratory’s (ORNL’s) Large Volume Active Well Coincidence Counter (LV-AWCC) and a commercially available deuterium-deuterium (D-D) neutron generator to examine the potential of the D-D neutron generator as an alternative to the isotopic sources. We present the performance of the LV-AWCC with D-D generator for the assay of 235 U based on the results of Monte Carlo N-Particle (MCNP) simulations and measurements of depleted uranium (DU), low enriched uranium (LEU), and highly enriched uranium (HEU) items.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗

Management of Digital Equipment in Preproduction by Means of Uniform Numeric Control Language

The requirements on preproduction and the control software for various digital machining systems (numerically controlled machine tools, robot manipulators, additive manufacturing equipment) in flexible production are considered. By analysis of existing programming languages for digital equipment, UNCL (Uniform Numeric Control Language) has been developed for standard representation of control commands. The use of UNCL in verifying program operation on a machining simulator is considered. Software for the translation of control programs (specified in CLDATA formats and in ISO code) to the invariant format of the universal language is described. The postprocessing of control software from the universal language into programs in commonly used digital control systems is also considered.

42 ENGINEERING↗