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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Influence of electrical fields and asymmetric application of mucilage on curvature of primary roots of Zea mays

Primary roots of Zea mays cv. Yellow Dent growing in an electric field curve towards the anode. Roots treated with EDTA and growing in electric field do not curve. When root cap mucilage is applied asymmetrically to tips of vertically-oriented roots, the roots curve toward the mucilage. Roots treated with EDTA curve toward the side receiving mucilage and toward blocks containing 10 mM CaCl2, but not toward "empty" agar blocks or the cut surfaces of severed root tips. These results suggest that 1) free calcium (Ca) is necessary for root electrotropism, 2) mucilage contains effector(s) that induce gravitropiclike curvature, and 3) mucilage can replace gravitropic effectors chelated by EDTA. These results are consistent with the hypothesis that the downward movement of gravitropic effectors to the lower sides of tips of horizontally-oriented roots occurs at least partially in the apoplast.

NASA Discipline Number 29-20↗

Ab initio electron dynamics in high electric fields: Accurate prediction of velocity-field curves

Electron dynamics in external electric fields governs the behavior of solid-state electronic devices. First-principles calculations enable precise predictions of charge transport in low electric fields. However, studies of high-field electron dynamics remain elusive due to a lack of accurate and broadly applicable methods. In this work, we develop an efficient approach to solve the real-time Boltzmann transport equation with both the electric field term and ab initio electron-phonon collisions. These simulations provide field-dependent electronic distributions in the time domain, allowing us to investigate both transient and steady-state transport in electric fields ranging from low to high (> 10 kV/cm). The broad capabilities of our approach are shown by computing nonequilibrium electron occupations and velocity-field curves in Si, GaAs, and graphene, obtaining results in quantitative agreement with experiment. Our approach sheds light on microscopic details of transport in high electric fields, including the dominant scattering mechanisms and valley occupation dynamics. Our results demonstrate quantitatively accurate calculations of electron dynamics in low to high electric fields, with broad application to power and micro-electronics, optoelectronics, and sensing.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Ion composition experiment

An investigation using a novel ion mass spectrometer for measuring the ionic composition of the solar wind from the ISEE-C spacecraft is described. The resolution and dynamic range of the instrument are sufficient to be able to resolve up to twelve individual ions or groups of ions. This will permit the solution of a number of fundamental problems related to solar abundances and the formation of the solar wind. The spectrometer is composed of a stigmatic Wien filter and hemispherical electrostatic energy analyzer. The use of curved electric field plates in the filter results in a substantial saving of weight with respect to a conventional filter of the same resolution and angular acceptance. The spectrometer is controlled by a microprocessor based on a special purpose computer which has three modes of operations: full and partial survey modes and a search mode. In the search mode, the instrument locks on to the solar wind. This allows four times the time resolution of the full survey mode and yields a full mass spectrum every 12.6 min.

Coplan, M. A.↗

Focusing ions at atmospheric pressure using nonlinear DC voltage sequences applied to a stacked ring ion guide

Many modern ion mobility (IM) and mass spectrometers (MS) operate under low pressure (= 10 Torr) and employ high voltage radiofrequencies (RF) to provide ion confinement. Unfortunately, RF effectiveness drastically decreases as pressure increases, and few techniques for focusing ions at elevated pressures exist. Here we demonstrate a new approach for focusing ions at atmospheric pressure (AP) by applying nonlinear DC voltage sequences following quadratic and power (exponential) functions to a stacked ring ion guide. In this work, we used ion trajectory simulations to rigorously explore how ions react to nonlinear electric fields and validate the simulations with a set of ion current measurements performed at AP. Ion trajectory simulations show that ions initially defocus near the entrance of the device but then become intensely focused as they travel through the device. Contour plots for both nonlinear voltage sequences show electric field lines that increasingly curve inwards as a function of distance, resulting in spatial ion focusing. Experimental ion current and spot size measurements were performed at AP using a 10-cm stacked ring ion guide and a segmented Faraday cup detector. Quadratic sequences produced ~5% smaller spot sizes (~22.8 mm) and ~25% higher ion current compared to a linear voltage sequence (~24.0 mm). Alternatively, power sequences produced ~64% smaller spot sizes (~8.7 mm), albeit with ~10x lower ion current. However, both nonlinear voltage sequences produced similar ion currents at the center of the Faraday cup detector, indicating that higher ion densities are achieved when using nonlinear voltage gradients. These results demonstrate a new way to focus ions at AP, and the capabilities demonstrated here provide fundamental insights on how to keep ions inside analytical devices at elevated pressures without RF.

47 OTHER INSTRUMENTATION↗

A self-consistent electrostatic electrified shallow water model for charged liquid surface dynamics

The dynamics of an electrified liquid surface are investigated using a shallow water model that is self-consistently coupled with an electrostatic solver. To account for the spatiotemporal variation of a curved liquid surface, the electric field on curved surfaces is calculated by solving a two-dimensional electrostatic equation using the weighted least squares (WLSQ) interpolation method. First, the WLSQ implementation is verified with analytical theory obtained from a Laplace solution assuming a half-cylinder liquid surface profile. Then, the coupled electrified shallow water model is used to study the instability of liquid surface perturbation as a function of the potential drop between an electrode and conducting liquid, surface tension, and gravity. We present a linear dispersion theory of liquid surface instability for long-wavelength perturbations, including the effects of liquid viscosity. Furthermore, the effects of multiple sinusoidal surface perturbations on the electrified liquid surface instability are investigated.

Capillary waves↗

Microgap breakdown with floating metal rod perturbations

Here, we report the characterization of microgap breakdown with perturbations from a metal rod floating between anode and cathode electrodes. The effects of the metal rod on the electric field distribution and the field enhancement factor are evaluated by numerical simulation and the conformal mapping method, and they indicate that the field emission regime is not reached. The breakdown voltages in the Townsend discharge regime are determined based on the voltage–current characteristics, which are obtained from two-dimensional fluid simulations. It is found that the breakdown characteristics can be significantly modulated by the floating metal rod, and the breakdown curve (breakdown voltage vs the net gap distance) is no longer U-shaped, which deviates from the conventional Paschen's law. The underlying physical mechanisms are related to the electric field enhancement, curved breakdown path, and nonuniform ion flux caused by the electric shielding effect. The results provide insights into breakdown characteristics in microscale discharges, which may promote conventional investigation of simplified clean gaps toward more complex conditions (e.g., with floating microparticles) in miniaturized plasma devices.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Tropical convection, ionospheric potentials and global circuit variation

The ionospheric potential (VI), a measure of the earth's overall electric field intensity, correlates with the classic 'Carnegie curve' diurnal variation in electric field caused by the global distribution of thunderstorms. A comparison of VI variation with satellite images of high tropical cloud fields indicates that equatorial thunderstorms over the continents are dominant in maintaining the earth's electric field. VI time series obtained at just one location may provide a high-resolution measure of intense tropical convection.

Markson, R.↗

Chemical Compensation Challenges in Processing Antiferroelectric PbZrO 3 Thin Films

The electric field-induced antipolar-to-polar phase transition in antiferroelectric materials is accompanied by large changes in the structural and functional response, making them attractive for many applications ranging from pulsed energy capacitors to high-strain-high (blocking-)force actuators, solid-state heating and cooling systems, and optoelectronic devices. PbZrO 3 , as an end member of the PZT, (x)PbZr 1–x Ti x O 3 , solid solution, has been the subject of many studies. However, processing of perovskite PbZrO 3 is extremely challenging due to phase instabilities induced by Pb loss at the temperatures necessary for perovskite crystallization. Here, we discuss the challenges associated with Pb loss, as well as its compensation through bulk Pb overstoichiometry and interfacial PbO additions, in chemical solution processed, highly oriented PbZrO 3 thin films. For both 042 o - and 001 o -oriented (o-orthorhombic distortion) PbZrO 3 thin films, the crystallization interfaces are the most important contributors to Pb loss and off-stoichiometric outcomes, and no single approach was sufficient to address these challenges. Pb-rich and Pb-deficient nonperovskite phases including ZrO x were only observable through microscopic characterization, and X-ray diffraction alone could not rule out the presence of such secondary phases. “Ideal” macroscopic antiferroelectric polarization-electric field double hysteresis curves were observed despite (at times) the large presence of secondary phases. However, reduced saturation polarization and increased phase transition electric fields were observed concomitantly with the presence of secondary phase(s) and tentatively assigned to the voltage drop across the ZrO x nanocrystals. Based on these results, it is imperative that the presence of secondary phases always be addressed (beyond X-ray diffraction spectra) in order to correctly evaluate the properties of antiferroelectric films.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Pressure-induced metallization and loss of surface magnetism in FeSi

Single-crystalline FeSi samples with a conducting surface state were studied under high pressure and magnetic field by means of electrical resistance measurements to explore how the bulk semiconducting state and the surface state are tuned by the application of pressure. Here, we found that the energy gap associated with the semiconducting bulk phase begins to close abruptly at a critical pressure of ~10 GPa and the bulk material becomes metallic with no obvious sign of any emergent phases or non-Fermi liquid behavior in temperature dependent electrical resistance in the neighborhood of the critical pressure above 3 K. Moreover, the metallic phase appears to remain at near-ambient pressure upon release of the pressure. Interestingly, the hysteresis in the electrical resistance vs magnetic field curve associated with the magnetically ordered conducting surface state decreases with pressure and vanishes at the critical pressure, while the slope of the electrical resistance vs magnetic field curve, which has a negative value for pressure below the critical pressure, decreases in magnitude with pressure and changes sign at the critical pressure. Thus the conducting surface state and the corresponding two-dimensional magnetic order collapse at the critical pressure where the energy gap of the bulk material starts to close abruptly, revealing the connection between the conducting surface state and the semiconducting bulk state in FeSi.

36 MATERIALS SCIENCE↗

Enhancement of Pool Boiling Heat Transfer and Control of Bubble Motion in Microgravity Using Electric Fields (BCOEL)

The BCOEL project focuses on improving pool boiling heat transfer and bubble control in microgravity by exposing the fluid to electric fields. The electric fields induce a body force that can replace gravity in the low gravity environment, and enhance bubble removal from the heated surface. A better understanding of microgravity effects on boiling with and without electric fields is critical to the proper design of the phase-change-heat-removal equipment for use in spacebased applications. The microgravity experiments will focus on the visualization of bubble formation and shape during boiling. Heat fluxes on the boiling surface will be measured, and, together with the measured driving temperature differences, used to plot boiling curves for different electric field magnitudes. Bubble formation and boiling processes were found to be extremely sensitive to g-jitter. The duration of the experimental run is critical in order to achieve steady state in microgravity experiments. The International Space Station provides conditions suitable for such experiments. The experimental apparatus to be used in the study is described in the paper. The apparatus will be tested in the KC-135 first, and microgravity experiments will be conducted on board of the International Space Station using the Microgravity Science Glovebox as the experimental platform.

Herman, Cila↗

Ferroelectric Switching in Hybrid Molecular-Beam-Epitaxy-Grown BaTiO 3 Films

Molecular beam epitaxy (MBE) is a promising synthesis technique for both heterostructure growth and epitaxial integration of ferroelectric BaTiO 3 . However, direct measurement of the remnant polarization (P r ) has not been previously reported in MBE-grown BaTiO 3 films. We report the in situ growth of an all-epitaxial SrRuO 3 /BaTiO 3 /SrRuO 3 heterostructure on Nb-doped SrTiO 3 (001) substrates by hybrid MBE using metal–organic precursors. This capacitor structure consisting of 16 nm SrRuO 3 /40 nm BaTiO 3 /16 nm SrRuO 3 shows hysteretic polarization–electric field (P–E) curves with P r ∼ 15 μC cm –2 at frequencies ranging from 500 Hz to 20 kHz, after isolating the intrinsic ferroelectric response from non-ferroelectric contributions using the Positive-Up-Negative-Down (PUND) method. We hypothesize that the asymmetry in switching behavior and current leakage has origins in structural defects. Furthermore, this work opens the door to defect-engineered ferroelectric BaTiO 3 -based heterostructures grown by hybrid MBE for future electronic, photonic and spintronic applications.

SrRuO3 electrode↗

Electrostatic field changes and recovery curves produced by Florida lightning

Preliminary data on electric field changes produced by cloud-to-ground lightning and the subsequent field recoveries are presented. Both single-station and multiple-station observations were made. There is large variation in the data: total charge transfers range from 10 to 30 C and beyond, electric-field recovery times vary by a factor of 2 or more, and initial charge heights occur over a large interval. Only distance and angle dependencies are somewhat predictable, and then only in a few cases. Thus the field recovery mechanism is not a simple one.

Jacobson, E. A.↗

Gamma-Ray Light Curves from Pulsar Magnetospheres with Finite Conductivity

The Fermi Large Area Telescope has provided an unprecedented database for pulsar emission studies that includes gamma-ray light curves for over 100 pulsars. Modeling these light curves can reveal and constrain the geometry of the particle accelerator, as well as the pulsar magnetic field structure. We have constructed 3D magnetosphere models with finite conductivity, that bridge the extreme vacuum and force-free solutions used in previous light curves modeling. We are investigating the shapes of pulsar gamma-ray light curves using these dissipative solutions with two different approaches: (l) assuming geometric emission patterns of the slot gap and outer gap, and (2) using the parallel electric field provided by the resistive models to compute the trajectories and . emission of the radiating particles. The light curves using geometric emission patterns show a systematic increase in gamma-ray peak phase with increasing conductivity, introducing a new diagnostic of these solutions. The light curves using the model electric fields are very sensitive to the conductivity but do not resemble the observed Fermi light curves, suggesting that some screening of the parallel electric field, by pair cascades not included in the models, is necessary

Harding, A. K.↗

A study of the electric field in an open magnetospheric model

The qualitative properties of an open magnetosphere and its electric field are examined and compared to a simple model of a dipole in a constant field and to actual observations. Many of these properties are found to depend on the separatrix, a curve connecting neutral points and separating different field-line regimes. In the simple model, the electric field in the central polar cap tends to point from dawn to dusk for a wide choice of external fields. Near the boundary of the polar cap electric equipotentials curve and become crescent-shaped, which may explain the correlation of polar magnetic variations with the azimuthal component of the interplanetary magnetic field, reported by Svalgaard. Modifications expected to occur in the actual magnetosphere are also investigated: in particular, it appears that bending of equipotentials may be reduced by cross-field flow during the merging of field lines and that open field lines connected to the polar caps emerge from a long and narrow slot extending along the tail.

Stern, D. P.↗

Focusing Ions at Atmospheric Pressure using Nonlinear DC Voltage Sequences Applied to a Stacked Ring Ion Guide

Many modern ion mobility (IM) and mass spectrometers (MS) operate under low pressure (= 10 Torr) and employ high voltage radiofrequencies (RF) to provide ion confinement. Unfortunately, RF effectiveness drastically decreases as pressure increases, and few techniques for focusing ions at elevated pressures exist. Here we demonstrate a new approach for focusing ions at atmospheric pressure (AP) by applying nonlinear DC voltage sequences following quadratic and power (exponential) functions to a stacked ring ion guide. We used ion trajectory simulations to rigorously explore how ions react to nonlinear electric fields and validate the simulations with a set of ion current measurements performed at AP. Ion trajectory simulations show that ions initially defocus near the entrance of the device but then become intensely focused as they travel through the device. Contour plots for both nonlinear voltage sequences show electric field lines that increasingly curve inwards as a function of distance, resulting in spatial ion focusing. Experimental ion current and spot size measurements were performed at AP using a 10-cm stacked ring ion guide and a segmented Faraday cup detector. Quadratic sequences produced ~5% smaller spot sizes (~22.8 mm) and ~25% higher ion current compared to a linear voltage sequence (~24.0 mm). Alternatively, power sequences produced ~64% smaller spot sizes (~8.7 mm), albeit with ~10x lower ion current. However, both nonlinear voltage sequences produced similar ion currents at the center of the Faraday cup detector, indicating that higher ion densities are achieved when using nonlinear voltage gradients. These results demonstrate a new way to focus ions at AP, and the capabilities demonstrated here provide fundamental insights on how to keep ions inside analytical devices at elevated pressures without RF.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Integral image tube-optical systems for the far UV.

Description of proposed image tube optical systems for narrow-band direct photography and broad bandpass photography from spacecraft outside the atmosphere. For narrow-band photography an f/1.5 Schmidt camera with a photocathode located on the focal surface is recommended. The photoelectrons are accelerated and magnetically focused onto a phosphor/fiber optics surface, the curvature of which partially corrects for distortions of the electric field introduced by the curved photocathode. The second stage can be any other tube, electrostatically or magnetically focused, having a fiber optics faceplate butted to the first stage. For broad bandpass a spectrograph with an f/3 all-reflecting Schmidt image tube camera is recommended.

Chincarini, G.↗

Semi-Annual Report: October 15, 1961

Investigations are proposed involving an experimental and theoretical program designed to investigate various properties of the structure of helium both in its atomic form and in the aggregates of the liquid and solid states. The key to the possibilities of performing the experiments lies in the relatively weak electric fields existing in liquid and solid helium and the possibility of producing external fields almost comparable with the internal fields. It is proposed to examine a) the melting pressure curve for helium as a function of electric field b) the dielectric constant of helium as a function of pressure and electric field c) in future, the effect of electric fields on the lambda transition. From the results of these experiments one would expect to be able to gather at least corroborative evidence on a) the crystal structure of solid helium on b) the effect of the Van der Waal interaction of the electric polarizability of helium, c) the possibility of producing helium molecules d) the effective volume available to helium atoms in the liquid and possibly e) the effect of particle interactions on the Bose-Einstein condensation.

HELIUM↗

Electrotropism of maize roots. Role of the root cap and relationship to gravitropism

We examined the kinetics of electrotropic curvature in solutions of low electrolyte concentration using primary roots of maize (Zea mays L., variety Merit). When submerged in oxygenated solution across which an electric field was applied, the roots curved rapidly and strongly toward the positive electrode (anode). The strength of the electrotropic response increased and the latent period decreased with increasing field strength. At a field strength of 7.5 volts per centimeter the latent period was 6.6 minutes and curvature reached 60 degrees in about 1 hour. For electric fields greater than 10 volts per centimeter the latent period was less than 1 minute. There was no response to electric fields less than 2.8 volts per centimeter. Both electrotropism and growth were inhibited when indoleacetic acid (10 micromolar) was included in the medium. The auxin transport inhibitor pyrenoylbenzoic acid strongly inhibited electrotropism without inhibiting growth. Electrotropism was enhanced by treatments that interfere with gravitropism, e.g. decapping the roots or pretreating them with ethyleneglycol-bis-[beta-ethylether]-N,N,N',N' -tetraacetic acid. Similarly, roots of agravitropic pea (Pisum sativum, variety Ageotropum) seedlings were more responsive to electrotropic stimulation than roots of normal (variety Alaska) seedlings. The data indicate that the early steps of gravitropism and electrotropism occur by independent mechanisms. However, the motor mechanisms of the two responses may have features in common since auxin and auxin transport inhibitors reduced both gravitropism and electrotropism.

NASA Discipline Plant Biology↗