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Impacts of Electric Space Heating in Multifamily Apartments in Juneau, Alaska [Slides]

The study objective was to understand the change in electrical consumption and cost after the addition of a ductless mini-split air-source heat pump (ASHP) across rental apartments heated by electrical resistance heating systems in multifamily buildings in Juneau, Alaska. Alaska Electric Light and Power Company (AELP), the utility in Juneau, Alaska, funded installation of 19 heat pumps across four buildings. Using electrical meter interval data, including the total apartment consumption and submeter data for each heating appliance (electric resistance baseboard and heat pump), the National Laboratory of the Rockies (NLR) calculated energy use metrics before and after heat pump installation and visualized results. Through this research, NLR compares electrical use (total and specific to heating appliances), adjusted for weather and apartment size, and electrical demand in the year before and after installation of an ASHP across study units. The results will inform the utility and residents of documented energy and cost savings from transitioning building heating systems to a higher-efficiency electricity-based appliance, deliver a basis for building energy modeling across other multifamily housing dwellings, and enable estimates of potential electricity savings to AELP grid under widespread adoption scenarios.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Itinerant G-type antiferromagnet SrCr 2 As 2 studied by magnetization, heat capacity, electrical resistivity, and NMR measurements

Here, the physical properties of itinerant antiferromagnetic (AFM) SrCr 2 As 2 with body-centered tetragonal ThCr 2 Si 2 structure were investigated in single crystalline and polycrystalline forms by electrical resistivity ρ, heat capacity C p , magnetic susceptibility χ versus temperature T, and magnetization M versus applied magnetic field H isotherm measurements as well as 75 As and 53 Cr nuclear magnetic resonance (NMR) measurements in the wide temperature range T = 1.6–900 K. From the χ(T) and 75 As NMR measurements, the G-type AFM state below T N = 615(15) K has been determined, consistent with the previous neutron-diffraction measurements. Direct evidence of magnetic ordering of the Cr spins was shown by the observation of the 53 Cr NMR spectrum under H = 0. From the χ( T) measurements on single-crystal SrCr 2 As 2 under the two different magnetic field directions H|| ab and H || c in the AFM state, the Cr ordered moments are shown to align along the c axis in the G-type AFM state. The metallic state is directly evidenced by the ρ, C p , and NMR measurements, and the density of states at the Fermi energy $\mathscr{D}$(E F ) in the AFM state is estimated to be 7.53 states/eV f.u. for both spin directions which is almost twice the bare $\mathscr{D}$(E F ) estimated from first-principles calculations, suggesting an enhancement of the conduction-carrier mass by a factor of two in the AFM state. The $\mathscr{D}$(E F ) is found to be nearly constant below at least 100 K and is independent of H. The ρ(T) is found to show T-linear behavior above T N and exhibits positive curvature below T N where significant loss of spin-disorder scattering upon magnetic ordering is observed. The resistivity anisotropy of the compound remains moderate ρ c /ρ a ~ 9 through most of the magnetically ordered phase but shows a rapid increase below 50 K.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Bench-Scale Development of a Novel Direct Air Capture Technology Using High-Capacity Structured Sorbents

The work performed under this project has resulted into development of a DAC technology utilizing a structured sorbent to capture CO 2 from ambient air with a key innovation of direct Joule heating of the sorbent for CO 2 desorption. A working SMA, fully integrated with an electrically resistive heating layer, high surface area support, and high CO 2 capacity sorbent coated onto a commercial ceramic monolithic substrate, was successfully developed and demonstrated over >200 adsorption-desorption cycles in a high-fidelity bench test unit directly using ambient air. A cordierite-based monolith was selected as a substrate owing to its high surface area, low bulk density, low heat capacity, and commercial availability. Reaction kinetics study conducted during this project led to development of a promoter for the base Na 2 CO 3 sorbent that could be incorporated into the sorbent to enhance to achieve higher CO 2 adsorption/desorption rates, greater working capacity, and reduced regeneration temperature. An accelerated aging study was conducted in a TGA to determine sorbent stability and no degradation in the sorbent performance was observed even after 250 adsorption-desorption cycles. An electrically resistive heating layer was developed with tunable electrical properties. The heating layer was coated onto the selected cordierite substrate. Aging studies performed showed the electrical properties and heating performance was stable after 500 heating and cooling cycles. The collective findings on the selected cordierite substrate, robust heating layer, promoter and sorbent selection were used to synthesize a full, 6”x6” SMA for bench-scale testing. The bench-scale DAC system was constructed to test full size SMAs using real ambient air for adsorption and joule heating for regeneration. After completing shakedown and commissioning of the 1 kg/day of CO 2 capacity DAC bench unit, an extended operation was performed to complete over 230 cycles with the full size SMA. This testing showed no observable degradation in sorbent performance. A detailed process model, TEA and LCA were developed for a conceptual 100,000 TPY CO 2 removal DAC facility. The LCA results show the net CO 2 e emissions from the DAC system are highly dependent on the electricity source. All other factors, including SMA manufacturing, materials for facility enclosure, etc., are minor cost contributors compared to the energy consumption required for CO 2 removal. With the successful development and validation of the SMA for the sustained performance for CO 2 removal from ambient air with joule heated regeneration in this project, a fully integrated 1 TPY bench-scale DAC system is currently in development with the support of DOE/FECM (DE-FE0032243). The project objective is to demonstrate the engineering design of the DAC system to produce a continuous, high purity CO 2 stream from ambient air. This project will address and validate key engineering features of the DAC system including the gas sealing mechanism and panels, enclosure and air contactor design, and automation sequence to achieve continuous CO 2 production.

42 ENGINEERING↗

End-Use Savings Shapes Measure Documentation: Heat Pump Rooftop Units with Original Fuel Backup

This documentation focuses on a single end-use savings shape measure—heat pump rooftop units with supplemental heat that matches the original fuel type of the replaced system; if the existing system used electric resistance heating, the supplemental heating source is electric resistance. If it was a natural gas furnace, the supplemental system is modeled as natural gas. This is a modification to the heat pump rooftop unit with electric supplemental heat measure from the Commercial EUSS 2023 Release 1 dataset. This document will primarily discuss the supplemental heating change for the heat pump RTU measure. For a comprehensive overview of the fundamental modeling methodology and background of the heat pump RTU measure, including performance curves and other key assumptions, please review the documentation for the original heat pump rooftop unit with electric supplemental heat.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Electrically Conductive Amine Functionalized Reduced Graphite Oxide Foam for CO 2 Removal from the Air

Rapid regeneration of CO 2 adsorbents is critical to improving the productivity of direct air capture (DAC) systems. In this study, we codesigned a material to have appropriate electrical conductivity and CO 2 adsorption properties to enable efficient CO 2 capture from air. Specifically, we present a poly(ethylenimine) (PEI)-impregnated thermally annealed graphite oxide (TAGO900) foam adsorbent tailored for vacuum-assisted electrically driven thermal swing adsorption (V-ETSA). This structured adsorbent leverages the high electrical conductivity of the reduced graphite oxide framework to enable fast and direct heating of the adsorbent material by electrical resistance heating (Joule heating). An optimal sample, 40 wt % PEI (molecular weight 25k) impregnated TAGO900, shows the best balance between adsorption capacity (1.54 mmol g –1 ) and adsorption rates (0.016 mmol g –1 min –1 ) using fixed bed breakthrough experiments at 25 °C and 70% RH using 50 sccm 400 ppm of CO 2 /N 2 flow. Compared to conventional temperature vacuum swing adsorption (TVSA), the V-ETSA approach achieves substantially faster CO 2 desorption, achieving average desorption rates (including cooling time) of 0.09 mmol g –1 min –1 ─approximately 2.5 times faster than TVSA under similar operating conditions. The maximum desorption rate reaches 0.23 mmol/g/min during the desorption stage. These results underscore the importance of the direct heating strategy, such as Joule heating, for fast and highly productive vacuum swing adsorption in DAC systems.

amines↗

ComStock Measure Documentation: Heat Pump Rooftop Units with Standard Performance

This documentation focuses on a single end-use savings shape measure - heat pump rooftop units (HP-RTUs) with standard efficiencies that are prevalent in the current market. Today, these products are claimed as standard efficiency by the manufacturers and are most commonly installed. This document will primarily discuss the additional changes of performance and configuration of the standard efficiency HP-RTUs while a comprehensive overview of the fundamental modeling methodology and background of the HP-RTU measure, including applicability, sizing scheme, and other key assumptions can be found in the original documentation: Heat Pump RTU. The definition of "standard efficiency" can be a bit vague when considering detailed specifics other than efficiency metrics of a heat pump. Thus, we have focused on reflecting products where manufacturers claim as standard efficiency and products that are not top-of-the-line in their model lineup. Based on gathering information from eight products from four major manufacturers, there are some common (or relatively prevalent) characteristics and we have defined standard efficiency product as follows: direct drive outdoor unit fan, two stages of heat pump cooling, single stage heat pump heating (i.e., all compressors running at the same time), heat pump minimum lockout temperature of 0°F (-17.8°C), backup electric resistance heating, backup heating runs at the same time as heat pump heating , heat pump heating locking out below minimum operating temperature, IEER in between 11-13, and HSPF in between 8-8.9. There are cases where some of these products have other variations: a variable frequency drive fan, dual fuel (i.e., gas backup heating) option, three or more cooling stages, two stages of heat pump heating, no backup heating as default , etc. However, this work tried to reflect the most common and prevalent options for a standard efficiency product.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Validated model of a thermoelectric heat pump clothes dryer using secondary pumped loops

The energy associated with clothes drying makes up 4% of the total residential electrical energy consumption in the US. The cost is high since most clothes dryers use electric resistance heating which is inexpensive but also energy inefficient. State-of-the-art vapor-compression heat pump clothes dryers offer significant energy savings but have limited market penetration in the US. Here, a new configuration of clothes dryer was studied that utilizes a solid-state thermoelectric heat pump with pumped secondary water loops and conventional fin-and-tube water-to-air heat exchangers. Experimental results are presented for the thermoelectric dryer prototype with a combined energy factor of 6.89 lb BDW /kWh (specific moisture extraction rate of 1.71 kg w /kWh) and a dry time of 84 min for a standard load size of 8.45 lb (3.83 kg) with 57.5% starting moisture content. This is a 85% energy efficiency improvement over baseline electric resistance dryers. The efficiency and drying time results achieved are similar to vapor compression heat pump dryers. Compared to previous air-based thermoelectric clothes dryers, the energy efficiency has been increased by 6%, but drying time has been reduced by as much as 47% using secondary pumped loops and separate heat exchangers, which represents a significant advancement in the technology. In addition to the experimental prototype, a model was also developed to study the performance. The model was validated against experimental prototype data and used to identify the range of performance (dry time and efficiency) that could be expected of the design.

42 ENGINEERING↗

Cost-Optimized Cold Climate Heat Pump Development and Field Test

Cold climate heat pumps (CCHPs) expand the heat pump market to climates where heating demand is dominant. They can achieve more than 70% energy savings compared with electric resistance heating and operate at lower cost than using tank-stored propane to fuel a furnace. A high-efficiency heat pump with a heating seasonal performance factor (HSPF)—as defined by the Air-Conditioning, Heating, and Refrigeration Institute (AHRI 2008)—greater than 10.0 would be more efficient than gas heating in terms of source energy. However, developing a cost-effective CCHP involves some challenges. A typical single-speed, air-source heat pump (ASHP) with an HSPF of 7.7 Btu/Wh does not work well under cold outdoor temperature conditions typical of cold climate locations for four major reasons: 1. Discharge temperature is too high—The low suction pressure and high compression pressure ratio at low ambient temperatures causes high compressor discharge temperatures in excess of the maximum limit for many of the compressors on the market. Furthermore, system charge of a heat pump is usually optimized in the cooling mode, which leads to overcharge conditions in the heating mode, further increasing the discharge temperature. 2. Heating capacity is insufficient if sized to meet the building design cooling load— Heating capacity of a single-speed heat pump decreases with ambient temperature. The heating capacity at -13°F (-25°C) typically decreases to 20%–40% of the rated heating capacity at 47°F (8.3°C) (~equivalent to the rated cooling capacity at 95°F [35°C]). Therefore, a single-speed heat pump, typically sized to match the building design cooling load, cannot provide adequate heating capacity to match the building heating load at low ambient temperatures. The capacity deficit is filled by inefficient resistance heat, thus lowering the system efficiency and significantly increasing power demand. 3. Cyclic loss is significant if sized to meet the building design heating load—If a single-speed heat pump is sized to meet the heating load, it will be significantly oversized relative to the cooling load in many cold climates. This will cause excessive on/off cyclic loss during the cooling and heating operations at moderately low ambient temperatures. Thus, capacity modulation capability (e.g., using a variable-speed or multi-stage compressor) is necessary for a CCHP, which uses its full capacity to meet the peak heating load and partial capacity to meet the cooling and part-load heating loads. 4. Coefficient of performance (COP) is low—Heating COP degrades significantly at low ambient temperatures owing to the large temperature difference between the heat source and sink. A target CCHP should be sized to meet the building design heating load while minimizing the cyclic loss for the cooling and heating operations at moderate ambient temperatures.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Parametric Studies of Heat Pump Water Heater Using Low GWP Refrigerants

A storage heat pump water heater (HPWH) comprises a vapor compression system and a hot water tank. It can lead to more than 70% energy saving, compared with electric resistance heating. HPWH usually uses a wrapped-tank coil as the water heater. The wrapped coil has a strong interaction with the water tank and impose a new challenge for the engineering design and simulation study. Based on the US DOE/ORNL Heat Pump Design Model (HPDM), i.e., a public-domain, component-based thermal system modelling platform, a segment-to-segment wrapped-tank coil model coupled with a one-dimensional stratified water tank model were developed, which facilitates modeling and design HPWHs having various configurations and components. Additionally, the hardware-based design model was used to evaluate refrigerants having lower global warming potentials to replace R-134a, including R-1234yf, R-1234ze, R-290, R-513A and R-450A, when effects of compressor size, refrigerant charge on 24-hour uniform energy factor (UEF) and first-hour rating (FHR) were investigated.In the drop-in replacements, R-1234ze achieved the best UEF, and R-290 resulted in the lowest UEF. When downsizing the compressor to maximize the UEFs, the UEFs of R-134a, R-290, R1234yf, R-450A and R-513A ascended to the range of 4.4 to 4.53, with R-513A having the highest UEF. The R-1234ze ended up having the lowest UEF of 4.27. Refrigerants having larger volumetric vaporization heat led to higher FHRs if using the fixed-size compressor, that R-290 resulted in the highest FHR.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Solar+Storage for Household Back-up Power: Implications of building efficiency, load flexibility, and electrification for backup during long-duration power interruptions [Slides]

The study analyzes the evolving role of solar+storage for home backup power during long-duration power interruptions. In particular, it evaluates how required storage sizing is impacted as homes become more efficient, flexible, and electrified. The study relies on NREL’s ResStock building modeling platform to create statistically representative distributions of the existing building stock in ten locations across the United States. It then shows how the amount battery storage required for backup power rises or falls as a series of building envelope efficiency, load flexibility, and electrification measures are applied across the building stock in each region. The study also includes sensitivities to show how backup power requirements are impacted by the timing and duration of power interruptions, and explores variation in backup power requirements across the building stock within each study location. The results demonstrate the value of pairing solar+storage with efficiency upgrades, smart home controls, and (in mild winter climates) efficient heat pump retrofits. That value comes in the form of reducing the amount of storage required and/or extending the range of interruption conditions over which a given system can provide backup power (i.e., more extreme weather and/or longer interruptions). Heat pumps in cold-weather climates can pose a challenge for solar+storage backup power, given the amount of storage required, though are a vast improvement over electric-resistance heating. Retaining existing fossil-based heating systems for occasional use during power interruptions, as either the primary or supplementary source of heat, can mitigate this challenge. Other forms of building electrification (e.g., cooking and water heating) generally have marginal impacts on backup battery sizing, given their relatively small energy demand.

14 SOLAR ENERGY↗

From models to reality: a systematic review on simulated and measured residential heat pump energy savings

High-performance HVAC solutions are central to residential energy management. A substantial share of these are electric, reversible-cycle systems, with heat pumps representing the largest portion of current and near-term adoption. This review synthesizes peer-reviewed and grey literature on residential space heating and cooling heat pumps. The academic literature is dominated by modeling (73.8%), with limited field measurement (13.1%). Grey literature from United States serve as a supplemental resource providing measured savings. Conversions from electric-resistance heating consistently show the largest site energy reductions, while oil/propane baselines yield moderate savings, and gas baseline scenario often deliver small and region-dependent savings. This study cross-checks the grey literature measured data with simulation data filtered from the ResStock dataset. The comparison indicates a discrepancy between simulations and measured data: simulated site EUIs are typically lower than measured EUIs, but percentage energy savings fall in similar ranges, implying simulations capture directional effects while underestimating energy use. Factors associated with variability and model–measurement differences include system characterization and control representation (e.g., backup heat engagement, thermostat/setpoint strategies, commissioning/installation quality), occupant behavior, weather normalization, metering scope, and envelope characterization. This paper also outlines the proposed methodology for comparing simulation and measured data for heat pumps. It emphasizes the metrics used for comparison and units harmonization, building characteristics matching, and compact metadata are needed for simulations to match measured data. The proposed methodology is expected to improve the credibility of simulated savings as measured evidence grows.

Yu, Lili↗

Small-moment antiferromagnetic ordering in single-crystalline La 2 Ni 7

Single crystals of La 2 Ni 7 have been grown out of a binary, La-Ni melt. Temperature dependent, zero magnetic field, specific heat, electrical resistivity, and low field magnetization measurements indicate that there is a series of antiferromagnetic phase transitions at T 1 = 61.0 ± 0.2 K, T 2 = 56.5 ± 0.2 K and T 3 = 42.2 ± 0.2 K. The three specific heat anomalies found at these temperatures qualitatively have very small entropy changes associated with them and the anisotropic M(H) data saturate at ~ 0.12 μ B /Ni; both observations strongly suggesting the AFM order is associated with very small, itinerant, moments. Anisotropic, H ||c and H ⟂c , ρ(H) and M(H) isotherms as well as constant field, ρ(T) and M(T) sweeps manifest signatures of multiple phase lines and result in HT phase diagrams that are clearly anisotropic. Analysis of M(T) and M(H) data allow for the identification of the two lower temperature magnetically ordered states as antiferromagnetically ordered, with the moments aligned along the crystallographic c-axis, and the higher temperature, T 2 < T < T 1 , state as having a finite ferromagnetic component. In addition, the metamagnetic transition at low temperatures, for H applied along the crystallographic c-axis (H ||c ) appears to be a near classic example of a spin-flop transition, resulting in a field stabilized antiferromagnetic state with the moments ordered perpendicular to the c-axis. Finally, although the small moment ordering, and existence of multiple phase transitions in field and temperature, suggesting an energetic proximity of these states, could foretell a degree of pressure sensitivity, our measurements of R(T) for applied pressures up to 2.0 GPa indicate that there is very little pressure dependence of T 1 , T 2 and T 3 .

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Technology Development and Field Monitoring in nZEB - US Country report IEA HPT Annex 49 Task 3

The International Energy Agency (IEA) Heat Pumping Technologies (HPT) Annex 49, “Design and Integration of Heat Pumps for Nearly Zero Energy Buildings,” deals with the application of heat pumps (HPs) as a core component of the HVAC system for nearly or net-zero energy buildings. This report covers the Task 3 activities of the US team. Three institutions are involved on the US team and have worked on the following projects. 1) Oak Ridge National Laboratory (ORNL) summarized development activities since the conclusion of IEA HPT Annex 40 for several integrated HP (IHP) systems - electric ground-source IHP and air-source IHP versions and engine-driven AS-IHP version. 2) The University of Maryland partnered with ORNL and Blue Bear Management to develop a personal cooling device called RoCo that can provide personalized conditioned air to occupants in inadequately or unconditioned environments. With RoCo, building facility management can elevate the HVAC thermostat settings without compromising occupants’ thermal comfort. Researchers have found that a 4°F increase in thermostat settings can save 12–30% energy savings. Therefore, RoCo is a promising technology that can help reduce building energy consumption and facilitate achievement of net-zero energy building performance. 3) The National Institute of Standards and Technology (NIST) is working on a field study effort on the NIST Net-Zero Energy Residential Test Facility. Two air-source split-system HPs were installed in a residential, net-zero energy home that was constructed as a laboratory on the NIST campus in Gaithersburg, Maryland. The first HP was a two-stage, 7 kW (2 ton), 15.8 seasonal energy efficiency ratio (SEER), 9.05 heating seasonal performance factor (HSPF) conventionally ducted system; the second HP was a variable-speed, 10.6 kW (3 ton), 14 SEER, 8.35 HSPF, high-velocity ducted system. These two systems operated side by side, using separate supply ducts and a common return duct, on a weekly alternating schedule to condition the home that was operated with very consistent simulated thermal loads. The team wanted to determine whether the high-velocity system could provide comparable energy-use efficiency to the conventional system. The results of this study showed that it did meet the required loads and had slightly greater efficiency; the average cooling coefficient of performance (COP) was (0.40 ± 0.11) higher, and the average heating COP was statistically equal. A new firmware was provided at the end of the heating season that greatly improved the performance of the high-velocity system; its average heating COP went from (1.8 ± 0.9) to (2.5 ± 1.1) at a 95% confidence level. The new firmware heating COP averaged (1.05 ± 0.23) higher than the old firmware over the same outdoor temperatures. The defrost performance is very different for these two systems, yet they consumed equivalent energy per HDD. The conventional system uses a timed-initiate, temperature-terminate algorithm with auxiliary electric resistive heating, whereas the high-velocity system uses calculated evaporator parameters with a hot-gas bypass before a full reverse-cycle defrost with no supplementary resistive heat.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

A Simulation Study of 120V Heat Pump Water Heaters

A 120 V heat pump water heater (HPWH) is a direct plug-in option to replace gas water heater (WH) without needing expensive electric panel upgrade to 220 V. To enable the smooth transition, the HPWH should provide comparable water heating capacity as the gas WH. WH capacities are rated in the form of first hour rating (FHR). Typical home gas WHs have FHRs > 65 gallon with a 40-gallon water tank. It imposes a major challenge on 120V HPWHs. Most 120V circuits in US can provide 1,800 to 2,400W, not adequate to drive electric resistance heat to boost FHRs. Thus, all the heat needs to come from the heat pump with its top power below 1500 Watts, which is constraint by the installation footprint. This study uses a hardware based, HPWH design model, i.e. the DOE/ORNL Heat Pump Design Model to design a 120V unit with a brazed plate condenser, fin-and-tube evaporator and an adequately sized compressor. To maximize the FHR, multiple strategies were simulated, including use of a mixing valve, overheating the tank temperature to 140F, a new sensing method for quicker response, and an innovative water circulation path. We also simulated 24-hour unform energy factors (UEF) to show the tradeoff between the capacity and operation efficiency. Additionally, we evaluated the impact of insulation thickness on FHR and UEF, to seek further footprint reduction or stretch the tank volume.

Shen, Bo↗

Geophysical borehole logging data of wells ER-GLS1, ER-GUM1, ER-PLM7, and ER-PLM8 at the East River Watershed, Colorado

The purpose of this data set is to provide a means of characterizing the bedrock variability both within a single borehole location and across the East River Watershed. The East River is part of the Watershed Function Scientific Focus Area (WFSFA) located in the Upper Colorado River Basin, United States, and all boreholes are located within Mancos shale bedrock. The data set contains geophysical borehole logging data acquired in October 2018 in boreholes ER-GUM1 (East River- Gothic Upper Montane Borehole #1) and ER-GLS1 (East River- Gothic Lower Subalpine Borehole #1), and acquired in October 2019 in boreholes ER-PLM7 (East River- Pumphouse Lower Montane Borehole #7) and ER-PLM8 (East River- Pumphouse Lower Montane Borehole #8). It contains depth, natural gamma ray emission, spectral gamma ray emission(Th, K, U), magnetic susceptibility, fluid temperature and electrical conductivity, electromagnetic (EM) induction derived rock electrical resistivity, heat pulse and spinner flow measurements to estimate groundwater flow, and Nuclear Magnetic Resonance (NMR) derived water content and hydraulic conductivity. Data for each borehole are provided as comma delimited text files. For each borehole accurate location information is provided (based on RTK GPS (Real Time Kinematic Global Positioning System) surveying). Borehole logging data were acquired using Mount Sopris borehole tools, and Vista Clara Javelin for NMR data.

54 ENVIRONMENTAL SCIENCES↗

Dissolution of Nb(C,N) During Post-weld Heat-Treatment of Electric Resistance Welded X70 Line Pipe

The effect of peak temperature for post-weld heat treatment (PWHT) on the dissolution of Nb-rich carbonitrides, Nb(C,N), in the weldline of an electric resistance welded (ERW) X70 grade pipeline steel was investigated. Selected-area electron diffraction patterns and corresponding electron energy loss spectroscopy mappings revealed both Nb-rich carbonitrides and Ti-rich nitrides, (Ti,Nb)N, in the sample heat-treated to 1080 °C peak temperature. However, only Ti-rich nitrides were revealed in the sample heat-treated to 1220 °C peak temperature. During continuous heating to higher than the Ac3 temperature, i.e., near 1100 °C temperature, the dissolution of Nb(C,N) was observed in dilation and derivative of dilation. Notably, this experimental result agreed with the predictions by a DICTRA model. Furthermore, a phenomenological model was developed to explain the volume shrinkage during the dissolution of Nb(C,N) precipitates.

36 MATERIALS SCIENCE↗

Building Energy Analysis of Manufactured and Multifamily Housing Types in Juneau, Alaska

This report details the results of building energy modeling analysis evaluating the potential energy savings, economic outcomes, and grid-level electricity reduction associated with cold climate air source heat pump (ccASHP) adoption across multifamily and manufactured housing (MMFH) building typologies in the City and Borough of Juneau (CBJ). Three building archetypes were evaluated: multifamily 4-plex apartments, multifamily 8-plex apartments, and manufactured housing units. Building energy models were developed using OpenStudio-HPXML and calibrated to actual utility consumption data and local meteorological data from the Juneau International Airport weather station using an automated calibration tool following the BPI-2400-S-2015 v.2 standard for model calibration. Occupant behaviors present the greatest variability in successful calibrations. Calibrated models were benchmarked against a baseline electric resistance heating condition, with the selected ccASHP modeled as the retrofit condition and typical meteorological year weather data for all results generation.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Superconductivity by alloying the topological insulator SnBi 2 Te 4

Alloying indium into the topological insulator SnBi 2 Te 4 induces bulk superconductivity with critical temperatures T c up to 1.85 K and upper critical fields up to about 14 kOe. This is confirmed by electrical resistivity, heat capacity, and magnetic susceptibility measurements. The heat capacity shows a discontinuity at T c and temperature dependence below T c consistent with weak coupling BCS theory, and suggests a superconducting gap near 0.25 meV. The superconductivity is type-II and the topological surface states have been verified by photoemission. Here, a simple picture suggests analogies with the isostructural magnetic topological insulator MnBi 2 Te 4 , in which a natural heterostructure hosts complementary properties on different sublattices, and motivates new interest in this large family of compounds. The existence of both topological surface states and superconductivity in Sn 1-x In x Bi 2 Te 4 identifies these materials as promising candidates for the study of topological superconductivity.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗