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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Discrete element modeling of switchgrass particles under compression and rotational shear

Switchgrass is a perennial herbaceous plant regarded as a biomass energy crop in the United States for its highadaptability and yield potential. Processing and handling of switchgrass particles are challenging due to the erratic mechanical and flow behavior originating from their intrinsic particulate properties. Here, we present a bonded-sphere discrete element model designed specifically for switchgrass particles. The model simultaneously captures three key particulate features, i.e., fibrous particle shapes, a wide range of particle sizes, and particle deformability. Realistic yet computationally efficient particle shape templates are created based on the image analysis data of switchgrass specimens. A fitting procedure is proposed to ensure both the particle width and length distributions are captured, a unique requirement for fibrous particles. Two full-scale numerical models, i.e., a uniaxial compression model and a Schulze ring shear model, are developed using information fromphysical experiments. The model is calibrated using experimental data of chopped-small switchgrass specimens, and then, is validated using data of chopped-large specimens in both compression and ring-shear tests. Numerical results show that the numerical models capture bulk densities accurately (with an error of 3%) while slightly underestimate the bulk friction angle. Furthermore, an extensive sensitivity analysis reveals that (1) switchgrass particles with rougher edges (due to different processing techniques) exhibit a higher shear strength and a lower flowability; (2) stiffer particles yield a lower bulk density (up to 21% lower) compared to more deformable particles, indicating particle deformability should be incorporated when modeling biomass flow in a preprocessing system.

09 BIOMASS FUELS↗

Flowability of JSC-1a

We have done a complete flowability characterization of the lunar soil simulant, JSC-1a, following closely the ASTM-6773 standard for the Schulze ring shear test. The measurements, which involve pre-shearing the material before each yield point, show JSC-1a to be cohesionless, with an angle of internal friction near 40 deg. We also measured yield loci after consolidating the material in a vibration table which show it to have significant cohesion (approximately equal to 1 kPa) and an angle of internal friction of about 60 deg. Hopper designs based on each type of flowability test differ significantly. These differences highlight the need to discern the condition of the lunar soil in the specific process where flowability is an issue. We close with a list not necessarily comprehensive of engineering rules of thumb that apply to powder flow in hoppers.

Rame, Enrique↗

Tests of Ring-stiffened Circular Cylinders Subjected to a Transverse Shear Load

Thirty-four circular cylinders stiffened by heavy rings were loaded to failure in combined bending and shear with a transverse shear load. The results are presented in the form of an interaction curve which is applicable to the design of ring-stiffened cylinders that fail as a result of local buckling. (author)

Peterson, James P↗

Characterization of Ceramic Matrix Composite Combustor Components: Pre and Post Exposure

The pursuit of lower emissions and higher performance from gas turbine engines requires the development of innovative concepts and the use of advanced materials for key engine components. One key engine component is the combustor, where innovative design and material improvements have the potential to lower emissions. Efforts to develop a High Speed Civil Transport with low emissions were focused on the evaluation of combustor concepts with liners fabricated from a ceramic matrix composite of silicon carbide fibers in a silicon carbide matrix (SiC/SiC). The evaluation of SiC/SiC composites progressed from simple coupons (to establish a first-order database and identify operant failure mechanisms and damage accumulation processes), to feature-based subelements (to assess fabricability and in situ material response), to actual components (to assess structural integrity, dimensional, and compositional fidelity) tested under simulated engine conditions. As in the case of all evolutionary material and process work, a key element to resolving fabrication issues is the evaluation of witness areas taken from fabricated components before testing the actual component. The witness material from these components allowed microstructural and mechanical testing to be performed and compared to the ideal, flat panel, conditions and data that are typical of basic characterization. This also allowed samples of similar design to be taken from components after 115 hours of combustion exposure. Testing consisted of tensile, double notch shear, ring burst, and thermal conductivity that sampled various regions of the components. The evaluation of the witness material allowed an understanding of the fabrication process, highlighting critical issues, in an early phase of the learning curve development of these configuration and material unique parts. Residual property testing, after exposure, showed if degradation of the material under actual service conditions was occurring. This paper will present the results of this critical testing. Evaluations that consider the degree of complexity of the fabricated part were established to relate in situ performance to that of flat panel based coupons. Nondestructive evaluation was used throughout the evaluation process. These results will also be discussed as an aid in understanding the test results.

Ojard, G.↗

Effect of particle size and moisture on flow performance of loblolly pine anatomical fractions: Experimental findings and model predictions

The rising energy demand has highlighted biomass as a promising next-generation energy source. However, commercializing biomass-derived energy faces challenges, particularly in handling biomass feedstock. Factors like particle size, shape, moisture content, and surface roughness significantly impact biomass flowability. This study addresses a crucial knowledge gap by examining the effects of particle size and moisture content on the flow behavior and shear properties of different anatomical fractions of loblolly pine (Pinus taeda). The bulk shear behavior was examined using a Schulze ring shear tester, while flow performance was tested through gravity-driven flow experiments in a variable wedge-shape hopper. Results were incorporated into empirical and machine learning-based flow prediction models to evaluate their accuracy and limitations. The study found that samples with higher moisture content show higher unconfined yield strength. The critical arching distance increased with particle size, e.g., from approximately 13 and 33 mm for 2- and 6-mm whole chips, respectively at a 32-degree inclination angle. Conversely, the flow rate decreased for a given hopper opening as particle size increased. For instance, at a 60-mm hopper opening and a 32-degree inclination angle, the mass flow rates for 2- and 6-mm whole chips were 7.83 and 6.42 tonne/h, respectively. The empirical model consistently overpredicted the mass flow rate for all anatomical fractions, while the machine learning model more accurately predicted the central tendency of flow rate but was insensitive to varying tissue proportions. These novel findings provide comprehensive characterization of anatomical fractions, reveal significant combined effects of particle size and moisture content on biomass flow behavior, and demonstrate a better predictive accuracy of a machine learning model, all of which are useful for optimizing material handling strategies and biomass utilization technologies in the industry.

09 - BIOMASS FUELS↗

High strain rate properties of unidirectional composites, part 1

Experimental methods were developed for testing and characterization of composite materials at strain rates ranging from quasi-static to over 500 s(sup -1). Three materials were characterized, two graphite/epoxies and a graphite/S-glass/epoxy. Properties were obtained by testing thin rings 10.16 cm (4 in.) in diameter, 2.54 cm (1 in.) wide, and six to eight plies thick under internal pressure. Unidirectional 0 degree, 90 degree, and 10 degree off-axis rings were tested to obtain longitudinal, transverse, and in-plane shear properties. In the dynamic tests internal pressure was applied explosively through a liquid and the pressure was measured with a calibrated steel ring. Strains in the calibration and specimen rings were recorded with a digital processing oscilloscope. The data were processed and the equation of motion solved numerically by the mini-computer attached to the oscilloscope. Results were obtained and plotted in the form of dynamic stress-strain curves. Longitudinal properties which are governed by the fibers do not vary much with strain rate with only a moderate (up to 20 percent) increase in modulus. Transverse modulus and strength increase sharply with strain rate reaching values up to three times the static values. The in-plane shear modulus and shear strength increase noticeably with strain rate by up to approximately 65 percent. In all cases ultimate strains do not vary significantly with strain rates.

Daniel, I. M.↗

Impact Testing and Analysis of Composites for Aircraft Engine Fan Cases

The fan case in a jet engine is a heavy structure because of its size and because of the requirement that it contain a blade released during engine operation. Composite materials offer the potential for reducing the weight of the case. Efficient design, test, and analysis methods are needed to efficiently evaluate the large number of potential composite materials and design concepts. The type of damage expected in a composite case under blade-out conditions was evaluated using a subscale test in which a glass/epoxy composite half-ring target was impacted with a wedge-shaped titanium projectile. Fiber shearing occurred near points of contact between the projectile and target. Delamination and tearing occurred on a larger scale. These damage modes were reproduced in a simpler test in which flat glass/epoxy composites were impacted with a blunt cylindrical projectile. A surface layer of ceramic eliminated fiber shear fracture but did not reduce delamination. Tests on 3D woven carbon/epoxy composites indicated that transverse reinforcement is effective in reducing delamination. A 91 cm (36 in.) diameter full-ring sub-component was proposed for larger scale testing of these and other composite concepts. Explicit, transient, finite element analyses indicated that a full-ring test is needed to simulate complete impact dynamics, but simpler tests using smaller ring sections are adequate when evaluation of initial impact damage is the primary concern.

Roberts, Gary D.↗

Carbon fiber composites for cryogenic filament-wound vessels

Advanced unidirectional and bidirectional carbon fiber/epoxy resin composites were evaluated for physical and mechanical properties over a cryogenic to room temperature range for potential application to cryogenic vessels. The results showed that Courtaulds HTS carbon fiber was the superior fiber in terms of cryogenic strength properties in epoxy composites. Of the resin systems tested in ring composites, CTBN/ERLB 4617 exhibited the highest composite strengths at cryogenic temperatures, but very low interlaminar shear strengths at room temperature. Tests of unidirectional and bidirectional composite bars showed that the Epon 828/Empol 1040 resin was better at all test temperatures. Neither fatigue cycling nor thermal shock had a significant effect on composite strengths or moduli. Thermal expansion measurements gave negative values in the fiber direction and positive values in the transverse direction of the composites.

Larsen, J. V.↗

Development of procedures for calculating stiffness and damping properties of elastomers. Part 3: The effects of temperature, dissipation level and geometry

Effects of temperature, dissipation level and geometry on the dynamic behavior of elastomer elements were investigated. Force displacement relationships in elastomer elements and the effects of frequency, geometry and temperature upon these relationships are reviewed. Based on this review, methods of reducing stiffness and damping data for shear and compression test elements to material properties (storage and loss moduli) and empirical geometric factors are developed and tested using previously generated experimental data. A prediction method which accounts for large amplitudes of deformation is developed on the assumption that their effect is to increase temperature through the elastomers, thereby modifying the local material properties. Various simple methods of predicting the radial stiffness of ring cartridge elements are developed and compared. Material properties were determined from the shear specimen tests as a function of frequency and temperature. Using these material properties, numerical predictions of stiffness and damping for cartridge and compression specimens were made and compared with corresponding measurements at different temperatures, with encouraging results.

Smalley, A. J.↗

Evaluation of polyimide/glass fiber composites for construction of light weight pressure vessels for cryogenic propellants

The application of polyimide resin as a matrix for glass filament-wound thin metal-lined pressure vessels was studied over a temperature range of (minus) 320 to 600 F. Keramid 601 polyimide was found to perform quite well over the entire range of temperature. Hoop stress values of 425 ksi were determined at 75 F which is equivalent to epoxy resin in similar structures. At -320 and 600 F, 125 and 80% of this strength was retained. Thermal ageing at 500 F for up to 50 hours was studied with severe reduction in strength, but there is evidence that this reduction could be improved. Another polyimide resin studied was P10PA which was found to have processing characteristics inappropriate for filament-winding. NOL ring tensile and shear data was determined from both resins with S-glass. Pressure vessel design, fabrication and test procedures are described in detail.

Petker, I.↗

Theory to test comparisons for selected aerospace multishell structures and their interfaces under thermomechanical loadings

Guidelines for structural shell analyses were obtained on the basis of theory-to-test comparisons made on two large-scale aerospace structures subject to thermomechanical loads. The first structural test was the cylindrical aluminum skin-stringer-ring construction of the S-IC forward skirt and S-II interstage. The second structural test included the truncated, cone-shaped, bonded honeycomb sandwich shell of the Spacecraft Lunar Module Adapter; the cylindrical bonded aluminum honeycomb sandwich construction of the Instrument Unit; and the skin-stringer construction with rings and intercostals of the S-IVB forward skirt. Analyses were made for loadings simulating the flight environment. Elementary shear lag theory was superimposed on shell analysis for interface junctions between stages to obtain favorable theory-to-test stress comparisons.

Ferdie, R. D.↗

Low-Cost, High-Performance Carbon Fiber for Compressed Natural Gas Storage Tanks (Final Technical Report – Down Select Report)

The aim of this project is to reduce the cost of Type IV, carbon fiber (CF) composite overwrap compressed gas storage tanks by reducing the cost of CF and CF composites. The project team worked to reduce the cost of CF by exploring and testing opportunities for a low-cost alternative precursor material for CF production to supplant market-dominant and costly polyacrylonitrile (PAN). Concurrently, the team aimed to reduce the cost of the tanks at the composite level by improving the interfacial adhesion between the fibers and the matrix resin through the incorporation of low-cost nanoparticles recycled from waste materials, which would reduce the volume of costly CF required to achieve the same tank performance. At the end of the first year, the project team selected mesophase pitch as the primary precursor candidate from a field of materials based on the superior mechanical performance and cost-saving potential. During the second year, the team produced CFs derived from mesophase pitch achieving an average tensile strength of 365.6 ksi and average tensile modulus of 40.74 Msi. Facility availability for spinning and converting these fibers at greater scale has hindered scale-up demonstration, but the team has identified opportunities to conduct this work in the near term. Cost modeling shows that these mesophase pitch-derived CFs can be up to 40% less expensive than PAN-derived CFs due to the lower cost of the feedstock material, higher throughput, greater conversion yield, and lower cost spinning method and compared to PAN. Additionally, the team has demonstrated at lab-scale that nanoparticle coating CFs can significantly increase the interfacial shear strength and load transfer efficiency of CFs in a matrix. Single filament pull-out testing showed a 27% average increase in max interfacial shear strength due to this coating. A continuous method of applying these coatings to a tow of CF has been developed for scale-up. 26 m tows of coated CFs were produced using this system and formed into composite ring samples for ASTM ring burst testing. Issues with the testing protocol have limited assessment of these results. A prototype Type IV tank was designed to meet ANSI HGV2 standards, and the design criteria set out by DOE, using the CF properties developed by the team paired with a proprietary resin matrix, a polyamide liner, and aluminum end bosses. The tank weighs 153.1 kg and with a total capacity of 5.8 kg H2 (5.6 kg usable), which yields a gravimetric capacity of 1.17 kWh/kg. Cost modeling predicts that the tank will have a projected cost of $15.73/kWh. Tank performance modeling does not include considerations for fiber-matrix load transfer efficiency improvements offered by nanoparticle coating method.

08 HYDROGEN↗

Strain rate characterization of unidirectional graphite/epoxy composite

For an investigation of problems of composites at high strain rates with dominant wave propagation effects, such as dynamically loaded composite jet engine blades, the longitudinal, transverse, and in-plane shear properties of unidirectional SP 288/AS graphite/epoxy were measured at various strain rates ranging from quasi-static to over 500/s. The test specimens were rings 10.16 cm in diameter, 2.54 cm long, 6 to 8 plies thick, and with fibers at 0, 90, and 10 deg off-axis. Quasi-static testing was conducted in a fixture which applies hydraulic pressure to the ring specimens, and dynamic testing was conducted by applying an internal pressure pulse through a liquid in a special fixture. Dynamic stress-strain curves are presented. For the 0-deg specimens, the modulus increases with strain up to 20 percent of the static value. The modulus and strength increase sharply in the 90-deg rings with strain rate reaching values two to three times the corresponding static rate.

Daniel, I. M.↗

Stability of Shapes Held by Surface Tension and Subjected to Flow

Results of three problems are summarized in this contribution. Each involves the fundamental capillary instability of an interfacial bridge and is an extension of previous work. The first two problems concern equilibrium shapes of liquid bridges near the stability boundary corresponding to maximum length (Plateau-Rayleigh limit). For the first problem, a previously formulated nonlinear theory to account for imposed gravity and interfacial shear disturbances in an isothermal environment is quantitatively tested in experiment. For the second problem, the liquid bridge is subjected to a shear that models the effect of a thermocapillary flow generated by a ring heater in a liquid encapsulated float-zone configuration. In the absence of gravity, this symmetric perturbation can stabilize the bridge to lengths on the order of 30 percent beyond the Plateau-Rayleigh limit, which is on the order of heretofore unexplained Shuttle observations. The third problem considers the dynamics of collapse and pinchoff of a film bridge (no gravity), which happens in the absence of stabilization. Here, we summarize experimental efforts to measure the self-similar cone-and-crater structure predicted by a previous theory.

Chen, Yi-Ju↗

Feasibility of liquid-metal vacuum seals

A basic component of any ultrahigh-vacuum system is a seal capable of isolating a test chamber from its higher pressure surroundings. Two of the most common vacuum seals now in use are the elastomer O-ring seal and the metallic shear seal. The former has the problem of outgassing and gas permeation; the latter requires a large force per unit seal-length to maintain the sealing action. The search for a seal which would provide minimal virtual and real leak rates in a chamber, without requiring a large force to consummate the seal, led to investigation of a liquid-metal seal.

SEALANT↗

Polyhalohydrins: Investigating Vicinal Functionalities by Ring-Opening of Epoxides on Polyolefins

Halohydrins are functional groups that are underexplored in polymer science. This study synthesized and examined structure–property relationships of halohydrin-functionalized polymers derived from polycyclooctene (PCOE), which was obtained via ring-opening metathesis polymerization (ROMP). The polyhalohydrins, including polychlorohydrin, polybromohydrin, and polyiodohydrin, were produced through a two-step process involving epoxidation of PCOE followed by epoxide ring-opening using hydrochloric, hydrobromic, or hydroiodic acid. These stereoirregular and regioirregular polymers are amorphous as measured by differential scanning calorimetry and X-ray scattering. Lap joint shear testing revealed an enhanced adhesive performance in polychlorohydrin and polybromohydrin, with the former demonstrating nearly three times the ultimate shear stress compared to a model polyethylene, hydrogenated PCOE. Additionally, contact angle measurements and surface free energy analysis showed an increase in hydrophilicity and polarity from iodine- to bromine- to chlorine-functionalized polyhalohydrins, aligning with trends in adhesion strength. Furthermore, these results underscore the potential of halohydrin functionalization as a versatile approach for tuning surface properties, offering new opportunities for polymer-to-polymer transformations.

Functional groups↗

A mechanical property and stress corrosion evaluation of 431 stainless steel alloy

The mechanical properties of type 431 stainless steel in two conditions: annealed bar and hardened and tempered bar are presented. Test specimens, manufactured from approximately 1.0 inch (2.54 cm) diameter bar stock, were tested at temperatures of 80 F (+26.7 C), 0 F (-17.8 C), -100 F (-73 C), and -200 F (-129 C). The test data indicated excellent tensile strength, notched/unnotched tensile ratio, ductility, shear, and impact properties at all testing temperatures. Results of the alternate immersion stress corrosion tests on stressed and unstressed longitudinal tensile specimens 0.1250 inch (0.3175 cm) diameter and transverse C-ring specimens, machined from 1.0 inch (2.54 cm) diameter bar stock, indicated that the material is not susceptible to stress corrosion cracking when tested in a 3.5 percent NaCl solution for 180 days.

Montano, J. W.↗

TO252: Parabolic Flight Demonstration of Fluid Dispensing Tube Performance Limits for Drop Delivery

Ring Shear Drop (RSD) ISS flight hardware failed to pin sample fluid drops between two rings, likely due to dynamic instability inherent to the dispensing tube (D-Tube) design. The first parabolic flight tested 5 D-tube tip designs with two bounding surface tension fluids, enabling an engineering design decision. D-tube Tip Cage Design was selected based on the November 2020 parabolic flight test data. Flight Operations Program (FOP) approved a reflight proposal to include 2 parabolic flight days during the April/May 2021 campaign with following objectives: • Validate ISS hardware flight design with actual flight fluids (test as you fly), demonstrating the ability to deliver 1” fluid drops in near-microgravity conditions. • Demonstrate pinning of 1” flight fluid drops: a secondary pinning ring is planned to be installed in the parabolic flight hardware to meet this objective. Fluid flow rates will also be varied as needed and as possible. • Provide data to validate computational models used to guide ISS operational deployment decisions and demonstrate the viability of the redesigned hardware to accommodate a range of future flight investigations. This presentation introduces highlights and lessons learned during this recent flight campaign for discussion in the Flight Opportunities Program Panel, “Leveraging Suborbital Flight Tests to Advance Science and Technology."

Sridhar Gorti↗