Light environment - A. Visible light. B. Ultraviolet light
Visible and ultraviolet light environment as related to human performance and safety during space missions
Finkelstein, S.↗
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Development and Progress in Enabling the Photocatalyst Ti02 Visible-Light-Active
Photocatalytic oxidation (PCO) of organic contaminants is a promising air and water quality management approach which offers energy and cost savings compared to thermal catalytic oxidation (TCO). The most widely used photocatalyst, anatase TiO2, has a wide band gap (3.2 eV) and is activated by UV photons. Since solar radiation consists of less than 4% UV, but contains 45% visible light, catalysts capable of utilizing these visible photons need to be developed to make peo approaches more efficient, economical, and safe. Researchers have attempted various approaches to enable TiO2 to be visible-light-active with varied degrees of success'. Strategies attempted thus far fall into three categories based on their electrochemical' mechanisms: 1) narrowing the band gap of TiO2 by implantation of transition metal elements or nonmetal elements such as N, S, and C, 2) modifying electron-transfer processes during PCO by adsorbing sensitizing dyes, and 3) employing light-induced interfacial electron transfer in the heteronanojunction systems consisting of narrow band gap semiconductors represented by metal sulfides and TiO2. There are diverse technical approaches to implement each of these strategies. This paper presents a review of these approaches and results of the photocatalytic activity and photonic efficiency of the end .products under visible light. Although resulting visible-light-active (VLA) photocatalysts show promise, there is often no comparison with unmodified TiO2 under UV. In a limited number of studies where such comparison was provided, the UV-induced catalytic activity of bare TiO2 is much greater than the visible-light-induced catalytic activity of the VLA catalyst. Furthermore, VLA-catalysts have much lower quantum efficiency compared to the approx.50% quantum efficiency of UV-catalysts. This stresses the need for continuing research in this area.
Levine, Lanfang H.↗
Radio and visible-light observations of a coronal arcade transient
Simultaneous visible-light and radio observations of a coronal transient that occurred on April 9, 1980 are discussed. Visible-light observations of the transient and the associated erupting prominence were available from the Coronagraph/Polarimeter carried aboard SMM, the P78-1 coronagraph, and from the Haleakala Observatory. Radio observations of the related type III-II-IV bursts were available from the Clark Lake and Culgoora Observatories. The transient was extremely complex; it is suggested that an entire coronal arcade rather than just a single loop participated in the event. Type III burst sources observed at the beginning of the event were located along a nearby streamer, which was not disrupted, but was displaced by the outmoving loops. The type II burst showed large tangential motion, but, unlike such sources usually do, it had no related herringbone structure. A moving type IV burst source can be associated with the most dense feature of the white-light transient.
Gergely, T. E.↗
Circularly polarized visible light from Jupiter
Jupiter circularly polarized visible light measurements, using photoelastic polarimeter
Kemp, J. C.↗
Oceanography from manned satellites by means of visible light
Oceanographic observations from manned satellites by visible light
MANNED SPACECRAFT↗
In-Flight Validation of the Metis Visible-Light Polarimeter Coronagraph on Board Solar Orbiter
Context. The Metis coronagraph is one of the remote sensing instruments of the ESA-NASA Solar Orbiter mission. The goal for the instrument is to enable the study of the solar atmosphere and solar wind by simultaneously acquiring images of the solar corona at two different wavelengths: visible light (VL), within a band ranging from 580 nm to 640 nm, and ultraviolet light, in the HI Lyα 121.6 ± 10 nm. The visible-light channel of the coronagraph includes a polarimeter with electro-optically modulating liquid crystal variable retarders to measure the linearly polarized brightness of the K-corona and derive the electron density. Aims. In this paper, we present the first in-flight validation results of the Metis polarimetric channel together with a comparison to the on-ground calibrations. This paper seeks to validate the first use of an electro-optical device, the liquid crystal-based polarimeter, in deep space and within a hard radiation environment. Methods. We used the orientation of the K-corona’s linear polarization vector during the roll maneuvers of the Space Orbiter spacecraft for the in-flight calibration. Results. The Metis coronagraph on board the Solar Orbiter shows good agreement with the on-ground measurements. The in-flight validation confirms the expected performance of the visible-light channel polarimeter. Furthermore, a comparison between the first polarized brightness value obtained by Metis and the polarized brightness values obtained by the space-based coronagraph LASCO and the ground-based coronagraph K-Cor shows the consistency of the Metis calibrated results.
Sun: corona↗
Far Ultraviolet and Visible Light Scatter Measurements for CVD Silicon Carbide Mirrors for SOHO
Chemically-vapor-deposited (CVD) silicon carbide (SiC) has become a popular mirror material for spaceborne solar instrumentation for the vacuum ultraviolet wavelength range due to its appreciable broadband reflectance and favorable thermal and opto-mechanical properties. Scatter from surfaces of mirrors operating in this wavelength range can destroy otherwise good image contrast especially for extended targets such as the sun. While visible light scatter measurements are relatively easy to conduct, far ultraviolet (FUV) scatter measurements are not so easy. Visible light (633 nm) scatter measurements were performed on CVD SiC telescope mirrors (from the same vendor) for two instruments on the Solar and Heliospheric Observatory (SOHO) -- Ultraviolet Coronagraph Spectrometer (UVCS) and Solar Ultraviolet Measurement of Emitted Radiation (SUMER). Additionally, extensive FUV scatter measurements were made for SUMER telescope mirrors. We attempt to correlate the results for those visible light scatter measurements and to explore the usefulness of visible scatter measurements to predictions of FUV scatter for this important material.
Leviton, Douglas B.↗
Correspondence between AXAF TMA X-ray performance and models based upon mechanical and visible light measurements
The AXAF Technology Mirror Assembly (TMA) was characterized prior to X-ray testing by properties measured mechanically or with visible light; these include alignment offsets, roundness and global-axial-slope errors, axial-figure errors with characteristic lengths greater than about five mm, and surface roughness with scale lengths between about 0.005 and 0.5 mm. The X-ray data of Schwartz et al. (1985) are compared with predictions based upon the mechanical and visible light measurements.
Van Speybroeck, L.↗
Effects of surface contamination on the infrared emissivity and visible-light scattering of highly reflective surfaces at cryogenic temperatures
A technique is described for the simultaneous in situ measurement of film thickness, refractive index, total normal emissivity, visible light scattering, and reflectance of contaminant films on a highly reflective liquid nitrogen-cooled, stainless steel substrate. Emissivities and scattering data were obtained for films of water, carbon dioxide, silicone oil, and a number of aromatic and aliphatic hydrocarbons as a function of film thickness between zero and 20 microns. Water had the greatest effect on emissivity, followed by silicone oil, aliphatic hydrocarbons, aromatic hydrocarbons, and carbon dioxide. Emissivity increased more rapidly with film thickness between zero and 2.5 microns, than at thickness greater than 2.5 microns. Scattering of visible light changed little below 2-microns thickness but increased rapidly with thickness beyond 2 to 3 microns. The effect of contaminant films on passive radiation coolers is discussed.
Viehmann, W.↗
Effects of surface contamination on the infrared emissivity and visible-light scattering of highly reflective surfaces at cryogenic temperatures
A technique is described for the simultaneous in situ measurement of film thickness, refractive index, total normal emissivity, visible-light scattering, and reflectance of contaminant films on a highly reflective liquid-nitrogen cooled, stainless steel substrate. Emissivities and scattering data are obtained for films of water, carbon dioxide, silicone oil, and a number of aromatic and aliphatic hydrocarbons as a function of film thickness between zero and 20 microns. Of the contaminants investigated, water has by far the greatest effect on emissivity, followed by silicone oil, aliphatic hydrocarbons, aromatic hydrocarbons, and carbon dioxide. The emissivity increases more rapidly with film thickness between zero and 2.5 microns than at thicknesses greater than 2.5 microns. Scattering of visible light changes very little below 2 microns thickness but increases rapidly with thickness beyond 2 to 3 microns. The effect of contaminant films on passive radiation coolers is discussed.
Viehmann, W.↗
Visible light scatter measurements of the Advanced X-ray Astronomical Facility /AXAF/ mirror samples
NASA is studying the properties of mirror surfaces for X-ray telescopes, the data of which will be used to develop the telescope system for the Advanced X-ray Astronomical Facility. Visible light scatter measurements, using a computer controlled scanner, are made of various mirror samples to determine surface roughness. Total diffuse scatter is calculated using numerical integration techniques and used to estimate the rms surface roughness. The data measurements are then compared with X-ray scatter measurements of the same samples. A summary of the data generated is presented, along with graphs showing changes in scatter on samples before and after cleaning. Results show that very smooth surfaces can be polished on the common substrate materials (from 2 to 10 Angstroms), and nickel appears to give the lowest visible light scatter.
Griner, D. B.↗
Occulting-filter method for obtaining flashing-light visibility data
Occulting-filter technique allows several types of flashing-light visibility data necessary for rendezvous and docking maneuvers, to be obtained for studying the perception of flashes at the visual threshold. The indications are that the method can be used to compare sources of radically different spectral composition.
Hardy, A. C.↗
Radio and visible light observations of matter ejected from the sun
An initial set of visible light and radio observations of a coronal transient made with the Coronagraph/Polarimeter experiment on SMM and the radioheliograph at Culgoora, Australia is presented. It is noted that an enormous loop-shaped transient observed on April 7, 1980, exhibited bright material having whiplike, nonradial motions, as well as moving and stationary radio sources. The data make it possible to establish that a moving type IV radio source was located on or very close to the fast-moving loop. The thermal, kinetic, and magnetic energies in the transient are estimated and, for the first time, compared with the radiative energy of the associated flare.
Wagner, W. J.↗
Visible-Light-Responsive Catalysts Using Quantum Dot-Modified TiO2 for Air and Water Purification
Photocatalysis, the oxidation or reduction of contaminants by light-activated catalysts, utilizing titanium dioxide (TiO2) as the catalytic substrate has been widely studied for trace contaminant control in both air and water applications. The interest in this process is due primarily to its low energy consumption and capacity for catalyst regeneration. Titanium dioxide requires ultraviolet light for activation due to its relatively large band gap energy of 3.2 eV. Traditionally, Hg-vapor fluorescent light sources are used in PCO reactors; however, the use of mercury precludes the use of this PCO technology in a spaceflight environment due to concerns over crew Hg exposure. The development of a visible-light responsive (VLR) TiO2-based catalyst would eliminate the concerns over mercury contamination. Further, VLR development would allow for the use of ambient visible solar radiation or highly efficient LEDs, both of which would make PCO approaches more efficient, flexible, economical, and safe. Though VLR catalyst development has been an active area of research for the past two decades, there are few commercially available VLR catalysts. Those VLR catalysts that are commercially available do not have adequate catalytic activity, in the visible region, to make them competitive with those operating under UV irradiation. This study was initiated to develop more effective VLR catalysts through a novel method in which quantum dots (QD) consisting of narrow band gap semiconductors (e.g., CdS, CdSe, PbS, ZnSe, etc.) are coupled to TiO2 via two preparation methods: 1) photodeposition and 2) mechanical alloying using a high-speed ball mill. A library of catalysts was developed and screened for gas and aqueous phase applications using ethanol and 4-chlorophenol as the target contaminants, respectively. Both target compounds are well studied in photocatalytic systems and served as model contaminants for this research. Synthesized catalysts were compared in terms of preparation method, nature of the quantum dots, and dosage of quantum dots.
visible light↗
Visible Light Responsive Catalyst for Air Water Purification Project
Investigate and develop viable approaches to render the normally UV-activated TIO2 catalyst visible light responsive (VLR) and achieve high and sustaining catalytic activity under the visible region of the solar spectrum.
Technology Portfolio System↗
Visible-Light-Responsive Catalyst Development for Volatile Organic Carbon Remediation Project
Photocatalysis is a process in which light energy is used to 'activate' oxidation/reduction reactions. Unmodified titanium dioxide (TiO2), a common photocatalyst, requires high-energy UV light for activation due to its large band gap (3.2 eV). Modification of TiO2 can reduce this band gap, leading to visible-light-responsive (VLR) photocatalysts. These catalysts can utilize solar and/or visible wavelength LED lamps as an activation source, replacing mercury-containing UV lamps, to create a "greener," more energy-efficient means for air and water revitalization. Recently, KSC developed several VLR catalysts that, on preliminary evaluation, possessed high catalytic activity within the visible spectrum; these samples out-performed existing commercial VLR catalysts.
Technology Portfolio System↗
A visible light terrestrial planet finder - planet detection and spectroscopy by nulling interferometry with a single aperture telescope
Planet detection around a bright star depends the resolution of the imaging system and the degree of light suppression of the star relative to the planet. We present a concept for a visible light Terrestrial Planet Finding (VTPF) mission. Its major feature is an imaging system for planet detection using a nulling interferometer behind a single aperture telescope. This configuration is capable of detecting earth-like planets with a 5m aperture using both imaging and spectroscopic imaging modes. We will describe the principles of the system, and show results of studies demonstrating its feasibility.
planet↗
Visible-Light-Responsive Photocatalysis: Ag-Doped TiO2 Catalyst Development and Reactor Design Testing
In recent years, the alteration of titanium dioxide to become visible-light-responsive (VLR) has been a major focus in the field of photocatalysis. Currently, bare titanium dioxide requires ultraviolet light for activation due to its band gap energy of 3.2 eV. Hg-vapor fluorescent light sources are used in photocatalytic oxidation (PCO) reactors to provide adequate levels of ultraviolet light for catalyst activation; these mercury-containing lamps, however, hinder the use of this PCO technology in a spaceflight environment due to concerns over crew Hg exposure. VLR-TiO2 would allow for use of ambient visible solar radiation or highly efficient visible wavelength LEDs, both of which would make PCO approaches more efficient, flexible, economical, and safe. Over the past three years, Kennedy Space Center has developed a VLR Ag-doped TiO2 catalyst with a band gap of 2.72 eV and promising photocatalytic activity. Catalyst immobilization techniques, including incorporation of the catalyst into a sorbent material, were examined. Extensive modeling of a reactor test bed mimicking air duct work with throughput similar to that seen on the International Space Station was completed to determine optimal reactor design. A bench-scale reactor with the novel catalyst and high-efficiency blue LEDs was challenged with several common volatile organic compounds (VOCs) found in ISS cabin air to evaluate the system's ability to perform high-throughput trace contaminant removal. The ultimate goal for this testing was to determine if the unit would be useful in pre-heat exchanger operations to lessen condensed VOCs in recovered water thus lowering the burden of VOC removal for water purification systems.
Photocatalysis↗