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Surampudi, S.

Publications and source records attributed to Surampudi, S..

At least 145 records · Page 8
All sourcesNASA NTRSDOE OSTI
NASA NTRS1994

The JPL Direct Methanol Liquid-feed PEM Fuel Cell

Recently, there has been a breakthrough in fuel cell technology in the Energy Storage Systems Group at the Jet Propulsion Laboratory with the develpment of a direct methanol, liquid-feed, solid polymer electrolyte membrane (PEM) fuel cell... The methanol liquid-feed, solid polymer electrolyte (PEM) design has numerous system level advantages over the gas-feed design. These include:...

fuel cells methanol pem methanol water↗
NASA NTRS1994

Advances in Direct Oxidation Methanol Fuel Cells

Fuel cells that can operate directly on fuel cells such as methanol are extremely attractive for low to medium power applications in view of their low weight and volume relative to other power sources.

fuel↗
NASA NTRS1993

Status of the development of rechargeable lithium cells

The progress in the development of the ambient temperature lithium - titanium disulfide rechargeable cell under development at the Jet Propulsion Laboratory is described in this paper. Originally aimed at achieving a specific energy of 100 Wh/kg, 'AA' cells have demonstrated 125 Wh/kg at the C/3 discharge rate. The results of evaluating cell design parameters are discussed and cycling test data are also included in the paper. Safety tests results at various over-charge and over discharge conditions and rates proved to be uneventful. The test results of cell with built-in overcharge mechanism proved the concept was feasible. Replacing the lithium foil electrode with a Li(x)C resulted in a capacity at 1mA/cm(exp 2) of 200 mAh/gm and 235 mAh/gm at 0.167 mA.

Halpert, G.↗
NASA NTRS1993

Advances in direct oxidation methanol fuel cells

Fuel cells that can operate directly on fuels such as methanol are attractive for low to medium power applications in view of their low weight and volume relative to other power sources. A liquid feed direct methanol fuel cell has been developed based on a proton exchange membrane electrolyte and Pt/Ru and Pt catalyzed fuel and air/O2 electrodes, respectively. The cell has been shown to deliver significant power outputs at temperatures of 60 to 90 C. The cell voltage is near 0.5 V at 300 mA/cm(exp 2) current density and an operating temperature of 90 C. A deterrent to performance appears to be methanol crossover through the membrane to the oxygen electrode. Further improvements in performance appear possible by minimizing the methanol crossover rate.

Surampudi, S.↗
NASA NTRS1993

Evaluation of Carbon Anodes for Rechargeable Lithium Cells

Both liquid phase intercalation technique and electrochemical intercalation technique were examined for the Li-carbon material preparation. The electrochemical techniques include a intermittent discharge method and a two step method. These two electrochemical techniques can ensure to achieve the maximum reversible Li capacity for common commercially available carbon materials. The carbon materials evaluated by the intercalacation method includes: pitch coke, petroleum cole, PAN fiber and graphite materials. Their reversible Li capacity were determined and compared. In this paper, we also demonstrate the importance of EPDM binder composition in the carbon electrode. Our results indicated that it can impact the Li intercalation and de-intercalation capacity in carbon materials. Finally, two possibilities that may help explain the capacity degradation during practical cell cycling were proposed.

carbon anodes rechargeable lithium cells material ↗
NASA NTRS1993

(abstract) Effect of Electrolyte Composition on Carbon Electrode Performance

Rechargeable lithium cells containing lithium foil anodes are reported to have limited cycle life (at 100% DOD) performance and safety problems. These limitations are understood to be due to the high reactivity of elemental Li with the electrolyte and the formation of high surface area Li during cycling. To mitigate these problems, several lithium alloys and lithium intercalation compounds are being investigated as alternate lithium anode materials. Li(sub x)C has been identified as a promising lithium anode material due to its low equivalent weight, low voltage vs. Li, and improved stability towards various electrolytes. In this paper, we report the results of our studies on the electrolyte evaluation for the Li(sub x)C anode.

lithium carbon electrode electrolyte rechargeable ↗
NASA NTRS1993

Advanced Energy Storage for Space Applications

NASA is planning a number of space science and space exploration missions into the early 21st century. The JPL Advanced Battery Program, which has the goal of developing batteries for these missions, is described. Under program consideration are Li-SOCl(sub 2) cells, secondary lithium cells, advanced metal hydride cells, and high-temperature sodium-nickel chloride cells.

JPL Advanced Battery Program energy storage batter↗
NASA NTRS1993

Electrochemical impedance spectroscopy of lithium-titanium disulfide rechargeable cells

The two-terminal alternating current impedance of Li/TiS2 rechargeable cells was studied as a function of frequency, state-of-charge, and extended cycling. Analysis based on a plausible equivalent circuit model for the Li/TiS2 cell leads to evaluation of kinetic parameters for the various physicochemical processes occurring at the electrode/electrolyte interfaces. To investigate the causes of cell degradation during extended cycling, the parameters evaluated for cells cycled 5 times were compared with the parameters of cells cycled over 600 times. The findings are that the combined ohmic resistance of the electrolyte and electrodes suffers a tenfold increase after extended cycling, while the charge-transfer resistance and diffusional impedance at the TiS2/electrolyte interface are not significantIy affected. The results reflect the morphological change and increase in area of the anode due to cycling. The study also shows that overdischarge of a cathode-limited cell causes a decrease in the diffusion coefficient of the lithium ion in the cathode.

Narayanan, S. R.↗
NASA NTRS1993

Effect of cycling on the lithium/electrolyte interface in organic electrolytes

Nondestructive methods such as ac impedance spectroscopy and microcalorimetry are used to study the effect of cell cycling on the lithium/electrolyte interface. The reactivity of both uncycled and cycled lithium towards various electrolytes is examined by measuring the heat evolved from the cells under open-circuit conditions at 25 C by microcalorimetry. Cycled cells at the end of charge/discharge exhibited considerably higher heat output compared with the uncycled cells. After 30 d of storage, the heat output of the cycled cells is similar to that of the uncycled cells. The cell internal resistance increases with cycling, and this is attributed to the degradation of the electrolyte with cycling.

Surampudi, S.↗