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DOE OSTI · 1706682

Oxidation of Ammonia with Molecular Complexes

Dunn, Peter L.·Cook, Brian J.·Johnson, Samantha I.·Appel, Aaron M.·Bullock, R. Morris
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Abstract

Oxidation of ammonia by molecular complexes is a burgeoning area of research. Several scientific challenges underpin these efforts, requiring a fundamental understanding of individual reactions steps, particularly for cleavage of N-H bonds and formation of N-N bonds. Overall, this perspective evaluates the challenges of designing molecular catalysts for oxidation of ammonia, and highlights recent key contributions to realizing the goals of viable energy storage and retrieval based on the N-H bonds of ammonia in a carbon-free energy cycle.

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRYoxidation, ammonia, catalysis

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Dunn, Peter L., Cook, Brian J., Johnson, Samantha I., Appel, Aaron M., Bullock, R. Morris. 2020-09-25. Oxidation of Ammonia with Molecular Complexes. https://doi.org/10.1021/jacs.0c08269

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