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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 199 records · Page 11

Scaling behavior and giant field enhancement of the thermal conductivity in the honeycomb antiferromagnet BaCo 2⁢ (AsO 4 ) 2

The layered honeycomb material BaCo 2 (AsO 4 ) 2 is of topical interest because its magnetic state is related to that of the Kitaev magnet α-RuCl 3 . Using thermal transport to probe how magnetic excitations interact with phonons in the magnetically disordered regime, we have uncovered an unusually large enhancement of the thermal conductivity κ xx in an in-plane magnetic field H. Just above the Néel temperature T N , a field of 13 T increases κ xx by a factor of ∼ 211, which is very large compared to other magnetic insulators. Interestingly, κ xx (H, T) exhibits a scaling behavior in the entire magnetically disordered region that surrounds the ordered zigzag state. The ratio Δκ xx (H, T)/κ xx (13, T), measured throughout the disordered region, collapses to a one-parameter scaling function exp(−1/gx) (where x = μ B B/k B T and g is a constant).

36 MATERIALS SCIENCE↗

2010-2012 Minneapolis - St. Paul Travel Behavior Inventory

The 2010-2012 Travel Behavior Inventory (TBI) provided Minnesota policymakers and researchers with data about travel in the Minneapolis - St. Paul region. It also updated the region's travel demand forecasting, including transit ridership for major transportation projects. The Metropolitan Council in the Minneapolis-St. Paul area conducted the survey. The TBI consists of a paper-based survey and a wearable global positioning system survey. The data collection process for these two surveys was independent, and the results are not intended to function together.

1Hz data↗

2000 Knoxville Urban Area Household Travel Behavior Survey

This survey, conducted by NuStats, was a comprehensive study of travel behavior in Knox and Blount counties in the Knoxville urban area. The purpose of the survey was to collect weekday travel characteristics of household members (ages five and older) in the counties during a 24-hour timeframe. The data will be used by the Knoxville Urban Area Metropolitan Planning Organization and local agencies to update transportation and air quality models and to identify transportation needs in the region. The survey was conducted between November 2000 and February 2001. In total, 2,674 households were recruited to participate in the survey. Of these, 1,538 households reported data from a one-day travel log, totaling 12,631 trips by 3,522 persons. Of all trips originating in the study area, three-fourths were made by persons residing in Knox County.

1Hz data↗

1982 The Twin Cities Metropolitan Area Travel Behavior Inventory

The purpose of the 1982 Travel Behavior Inventory was to update socioeconomic and travel data gathered in a 1970 home interview survey. The area in Minnesota studied included the counties of Ramsey, Hennepin, Dakota, Anoka, Washington, Carver, and Scott. The inventory collected demographic and travel data from September 1, 1982, to February 27, 1983. The survey contains data from 2,640 participating households. From participants' travel records, a total of 21,944 trips were reported by 6,059 household members for a 24-hour period.

1Hz data↗

1990 The Twin Cities Metropolitan Area Travel Behavior Inventory

The Twin Cities Metropolitan Area 1990 Travel Behavior Inventory, or home interview survey, was conducted by Twin Cities Metropolitan Council—Saint Paul to document how Twin Cities residents use the streets, highways, and transit services in the region. The survey collected demographic, socioeconomic, and travel data for 9,476 households. Respondents were asked to record their travel and activities for a 24-hour period, in which 98,535 trips were documented. In addition to the home interview survey, the study included an establishment survey, a transit survey, external station traffic counts, and an external station origin/destination survey.

1Hz data↗

2000 The Twin Cities Metropolitan Area Travel Behavior Inventory

The 2000 Twin Cities Metropolitan Area Travel Behavior Inventory, conducted by Twin Cities Metropolitan Council—Saint Paul, was the first major travel survey in the region since 1990. The 2000 inventory includes a home interview survey, an establishment survey, a transit survey, external station traffic counts, and an external station origin/destination survey. The study area under the household inventory survey included the seven counties of the regional Metropolitan Planning Organization and thirteen adjacent counties. Demographic, socioeconomic, and travel data were gathered for 6,386 households. Of these, 6,219 households completed the travel logs, which includes household members older than five years old.

1Hz data↗

Corrosion Behavior of Hydrophobic Coatings in Aqueous CO2 Environments

Internal corrosion is caused by gas impurities such as CO2, moisture, and H2S, leading to material degradation. To combat this, the National Energy Technology Laboratory (NETL) developed a novel hydrophobic coating to reduce surface hydrophobicity and enhance the corrosion resistance of steel. NETL’s approach uses multi-layer hydrophobic coatings, a novel and promising coating that could potentially revolutionize the industry's approach to internal corrosion mitigation. This work aims to investigate the corrosion performance of the hydrophobic coating and determine the water uptake. Electrochemical corrosion experiments were carried out on bare X65 carbon steel without and with coating in 3.5 wt.% NaCl saturated with CO2 at 20 °C to follow the water uptake as a function of exposure time. Linear polarization resistance (LPR) was used to determine the corrosion rate for carbon steel immersed in a NaCl electrolyte saturated with CO2. Electrochemical impedance spectroscopy (EIS) of uncoated and coated bare carbon steel was investigated. The analyses of impedance models and water uptake behaviors of hydrophobic coatings were studied for 200 hours during the corrosion process. The water uptake was estimated using the Brasher and Kingsbury relation. The results showed that the superhydrophobic coating that was developed used innovative nano-based materials to act as protection layers on the surface of metallic parts against mechanical aggressors, corrosion, and fouling agents.

corrosion behavior↗

Blending Behavioral Science and Physics-Based Models Inform Equitable Decarbonization Pathways in the US Housing Stock: Preprint

A just energy transition is an imperative of the Biden-Harris Administration, emphasizing the equitable distribution of benefits through energy-efficient and decarbonizing household technologies. Understanding the factors that increase a household's willingness to adopt these technologies helps policymakers implement more targeted and effective approaches. Our research addresses this by blending 550,000 housing stock types and energy simulation data with a nationally representative survey on residential technology adoption and decision-making (n=10,000). We identify energy equity gaps across tenure and income, highlighting disparities in energy burdens and insecurity. Findings show that households with prior modification experience are more willing to renovate, suggesting that small-scale retrofit programs could foster greater willingness. Energy secure but burdened homeowners are least willing to modify, highlighting the need to consider energy bill perceptions in policy design. Nearly half of US households that are energy burdened also face energy insecurity, with a significant gap in assistance for low-income households. We emphasize the need to understand household perceptions to improve policy. This research underscores the importance of understanding household behaviors to improve policy effectiveness, offering actionable insights for policymakers to promote equitable housing upgrades and advance a decarbonized future.

behavioral science↗

High‐Temperature Mechanical Behavior of Single‐Crystal FeCrAl Alloy Under In Situ Micropillar Compression

FeCrAl cladding is one of the candidate materials for the near‐term accident‐tolerant fuel technologies under development. Research on high‐temperature mechanical behaviors of single‐crystal FeCrAl alloy is rather limited. Previous studies have reported the mechanical property of low‐index orientation in single‐crystal FeCrAl alloy at room temperature. However, the critical resolved shear stress to activate slip systems can be orientation and temperature dependent. Here, single‐crystal grains in a coarse‐grained FeCrAl alloy with different crystallographic orientations are selected to preferentially activate {110}<111> slip systems or {112}<111> slip systems. Micropillars are fabricated in the selected single‐crystal grains and tested at elevated temperatures in situ in a scanning electron microscope. The critical resolved shear stresses of {110}<111> slip systems and {112}<111> slip systems are determined at various temperatures. The critical resolved shear stress shows a temperature dependence and orientation independence. This study provides important insight for understanding the deformation mechanisms of FeCrAl alloys at elevated temperatures.

Sun, Tianyi↗

Entrapment Behavior of Solid Surrogate Fission Products at Engineered UN Nano‐Hetero‐Interfaces Within Metallic Nuclear Fuels

Nanometric hetero-interfaces provide a wealth of scientific and engineering opportunities due to their complex and often misunderstood properties that can differ from their respective bulk constituents. In this work, the ability for engineered nanostructures within a bulk U─Mo alloy to arrest simulant fission products is investigated experimentally and computationally. Nanostructured 90 wt% U/ 10 wt% Mo (U-10Mo) with 7.1 at% Nd is consolidated using spark-plasma- sintering (SPS) techniques and is heat-treated at 500 °C under vacuum for 24, 100, 500, and 1000 h. Analysis on the sintered and heat-treated U-10Mo reveals rapid kinetics in Nd diffusion to nanocluster sites, with evidence of Nd diffusion occurring during sintering and during the following heat-treatment. The segregation behavior of Nd at two different U─Mo/UN interfaces is computationally verified using density functional theory (DFT) to reinforce experimental data.

11 - NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Phase Transformation and Water Adsorption Behavior of As‐Deposited and Annealed Ru Metal Thin Films Prepared by Atomic Layer Deposition

ABSTRACT Surfaces play a central role in catalytic processes, and understanding the transformation of ruthenium metal into ruthenium oxide during annealing is essential for tailoring functional catalytic interfaces. In this study, we systematically investigate ≈22 nm thick Ru metal films deposited by atomic layer deposition (ALD) at 300°C, focusing on their chemical composition, structural evolution, and surface hydration behavior following post‐deposition annealing in air from 400 to 600°C. Lab‐based and synchrotron X‐ray photoelectron spectroscopy (XPS) reveal a gradual conversion from metallic Ru to fully oxidized Ru 4+ with increasing annealing temperature, accompanied by a corresponding increase in lattice oxygen. X‐ray diffraction (XRD) shows amorphous Ru oxide phases at 400°C and 500°C that evolve into crystalline RuO 2 at 600°C, while atomic force microscopy (AFM) indicates enhanced grain growth and surface roughening upon annealing. Ambient‐pressure XPS (AP‐XPS) under controlled H 2 O vapor environments (1–17 Torr) demonstrates that samples annealed at 400°C and 500°C exhibit initially high hydroxyl coverage that decreases with increasing water vapor pressure, concurrent with a rise in molecular H 2 O adsorption. In contrast, the crystalline RuO 2 surface formed at 600°C maintains stable hydroxylation and supports increased water uptake. Overall, this work provides fundamental insight into Ru oxide–H 2 O interactions and establishes design principles for engineering oxide surfaces optimized for electrocatalytic applications.

APXPS↗

Li Stripping Behavior of Anode‐Free Solid‐State Batteries Under Intermittent‐Current Discharge Conditions

Anode‐free manufacturing holds promise to enable high energy densities and lower Lithium (Li)‐metal solid‐state batteries (LMSSBs). Nevertheless, in contrast to thick Li foil (>50 µm), the stripping capacity of in situ‐formed Li (10–30 µm) is limited due to diminished creep flow, resulting in reduced accessible capacity. This study explores the correlation between stripping capacity and surface roughness of garnet Li 7 La 3 Zr 2 O 12 (LLZO) solid electrolyte. The results reveal that stripping capacity can be enhanced through the surface modification of solid electrolytes. Additionally, this study scrutinizes the stripping behavior of in situ Li under intermittent‐current discharge conditions, which are more relevant to the operational conditions of electric vehicles (EVs). It is demonstrated that, when compared to constant‐current stripping, intermittent‐current stripping effectively suppresses void formation and enhances the stripping capacity of in situ Li by 40%. It is considered that the intermittent current inhibits the accumulation of Li vacancies, thereby delaying the void formation. These findings provide valuable insights into the development of high‐performance anode‐free LMSSBs for EVs.

25 ENERGY STORAGE↗

Influence of Air and Ethanol Dehydration on Structure, Behavior, and Function of Type I Collagen Scaffolds

Ethanol dehydration is a common step in both scaffold manufacturing and tissue processing, yet the influence of ethanol on collagen is not well understood. This study examined the effects of dehydration, via ethanol treatment and air drying, on collagen structure, behavior, mechanics, and rehydration capacity. Multiple material characterization methods were used including Fourier Transform infrared spectroscopy (FTIR), Raman spectroscopy, scanning electron microscopy, thermogravimetric analysis, small/medium angle x‐ray scattering, volumetric swelling analysis, and tensile testing. Ethanol dehydration removed bulk water from scaffolds, making them stronger and stiffer, but also showed loss of molecular water. This molecular water appears to act as a collagen stabilizer, resulting in less thermally stable scaffolds. The loss of molecular water is also evident in the molecular d‐spacing. Secondary structure of scaffolds was also altered by ethanol, resulting in significantly enhanced rehydration capacity. Bulk water, both before and after rehydration, largely determined mechanical properties, which did not correlate with other structural measures such as FTIR. While rehydration largely returned collagen spacing to pre‐ethanol treated state, structural alterations seen in FTIR cannot be recovered. These results have implications for not only collagen scaffolds, but in many tissue engineering and processing applications.

77 NANOSCIENCE AND NANOTECHNOLOGY↗

Lithium Storage Mechanisms and Electrochemical Behavior of a Molybdenum Disulfide Nanoparticle Anode

This study investigates the electrochemical behavior of molybdenum disulfide (MoS 2 ) as an anode in Li-ion batteries, focusing on the extra capacity phenomenon. Employing advanced characterization methods such as in situ and ex situ X-ray diffraction, Raman spectroscopy, X-ray photoelectron spectroscopy, and transmission electron microscopy, the research unravels the complex structural and chemical evolution of MoS 2 throughout its cycling. A key discovery is the identification of a unique Li intercalation mechanism in MoS 2 , leading to the formation of reversible Li x MoS 2 phases that contribute to the extra capacity of the MoS 2 electrode. Density function theory calculations suggest the potential for overlithiation in MoS 2 , predicting Li 5 MoS 2 as the most energetically favorable phase within the lithiation–delithiation process. Additionally, the formation of a Li-rich phase on the surface of Li 4 MoS 2 is considered energetically advantageous. After the first discharge, the battery system engages in two main reactions. One involves operation as a Li-sulfur battery within the carbonate electrolyte, and the other is the reversible intercalation and deintercalation of Li in Li x MoS 2 . The latter reaction contributes to the extra capacity of the battery. The incorporation of reduced graphene oxide as a conductive additive in MoS 2 electrodes notably improves their rate capability and cycling stability.

Lithium Rich Phase↗

Investigation of Corrosion Behavior of Carbide Phase Strengthened Nickel‐Based Alloy in Molten Fluoride Salt

The corrosion behavior of a high creep strength carbide-phase strengthened Ni-based alloy in molten FLiNaK (LiF-NaF-KF: 46.5-11.5-42 mol%) salt in the temperature range of 700°C–750°C has been investigated as a part of the development of structural alloys for fluoride salt-based molten salt reactors (MSRs). The alloy composition was designed based on Hastelloy-N, but with the goal of improving creep strength. Cr depletion depth, a measure of corrosion, was observed to be single micrometers after several hundred hours of corrosion testing. Sequential corrosion testing involving testing of pre-tested samples in fresh salt coupled with SEM-EDS, scanning transmission electron microscopy (STEM) examinations and thermodynamic and kinetic modeling, suggest that the corrosion rate at the alloy-salt interface is governed by diffusion of elements from the alloy bulk to the surface. The carbide phases in the corrosion-tested sample microstructure were identified to be largely M 6 C-type Mo-rich carbides and MC-type mixed carbides. Atom probe tomography (APT) showed some partitioning of Cr and Ti to the carbide phase and showed the carbide phases to be stable at the salt-facing surface.

Gordon, Ryan [Univ. of Wisconsin, Madison, WI (Uni↗

A supersymmetric SYK model with a curious low energy behavior

We consider N = 2,4 supersymmetric SYK models that have a peculiar low energy behavior, with the entropy going like S = S 0 + (constant)T a , where a ≠ 1. The large N equations for these models are a generalization of equations that have been previously studied as an unjustified truncation of the planar diagrams describing the BFSS matrix quantum mechanics or other related matrix models. Here we reanalyze these equations in order to better understand the low energy physics of these models. We find that the scalar fields develop large expectation values which explore the low energy valleys in the potential. The low energy physics is dominated by quadratic fluctuations around these values. These models were previously conjectured to have a spin glass phase. We did not find any evidence for this phase by using the usual diagnostics, such as searching for replica symmetry breaking solutions.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Effect of Oxidizing Impurities on the Corrosion Behavior of Structural Alloys Exposed to MgCl 2 Molten Salt Vapor

The corrosion behavior of structural alloys SS304 and IN617 when exposed to vapors of MgCl 2 molten salt at 764 °C for 100 h in an argon atmosphere was investigated as a function of the level of oxidizing impurities (e.g., NaOH) present in the salt. Increasing the concentration of oxidizing impurities in the salt caused an increase in corrosion in both structural alloys, as measured by Cr depletion layers. A poorly adhered oxide scale layer containing Mg, Al, and Cr was observed on the surface of the metals, and local attack was observed as well. The Ni-based IN617 showed lower Cr depletion and less scale formation than the Fe-based SS304. These results demonstrate that oxidizing impurities in the molten salt will impact the vapor phase corrosion for structural members exposed to the molten salt headspace. This finding is highly relevant for understanding the effects of the vapor phase in molten salt applications, including molten salt thermal energy storage, molten salt nuclear reactors, and molten salt electrochemistry.

25 ENERGY STORAGE↗

Interaction between the emerging components of online shopping and in-person activities: insights from a behavioral survey

The rise of technological advancements has led to the commonplace practice of online shopping for retail, grocery, and food. However, little research has been conducted on the interplay of these components in burdened communities (BCs) that face issues of marginalization and limited access to digital resources. Here, this study aims to provide a comprehensive understanding of travel behavior changes by analyzing the interconnectedness of the emerging components of online shopping (retail, grocery, and food) and in-person activities in both BCs and non-BCs. A unique household-level database is created by linking the 2021 Puget Sound Household Travel Survey and the US Department of Transportation’s burdened community databases, and a conditional mixed process model is estimated to account for unobserved endogeneity. The findings suggest households living in BCs are less likely to order online retail goods and groceries compared to non-BC households. Additionally, the probability of making more restaurant trips decreases for households living in BCs. The study highlights the digital divide that exists in BCs and the differences in online and in-person shopping activities across socioeconomic levels. Policymakers may address these disparities to promote better access to goods and services for all. Besides, planners may need to improve the travel demand models by accounting for the emerging components of online shopping and the trip frequencies by purpose in BCs.

Digital Divide↗