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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 289 records · Page 16

Electrochemical generation of hexacyanoferrate and hexacyanoruthanate electroactive films at nickel electrode surfaces: A promising synthetic approach for new electrode materials in metal ion batteries and supercapacitors

Prussian blue analogues (PBAs) have been recently investigated as promising electrode materials for battery and supercapacitor applications. While most explorations have focused on PBA nanoparticles, very little attention has been focused on PBA films deposited on a metallic support. In this work, we have examined electrogenerating hexacyanoferrate (HCF) and hexacyanoruthenate (HCR) films on nickel surfaces via cyclic voltammetry. We found that the total material deposited was influenced by the metal cation present in the electrolyte solution and that, on average, the rate of deposition of the surface adsorbed/immobilized species was dependent on the species in solution. In particular, films electrogenerated in the presence of Na + and K + had the highest deposition rates. The cyclic voltammetric profiles exhibited dramatic differences depending on the cation present in the electrolyte solution. In addition, we found that all films were electrochemically irreversible in the presence of Li + and Mg 2+ containing electrolyte solutions. Further, and as a proof of concept, we modified high surface area nickel electrodes with HCF in sodium-based electrolytes, finding that these electrodes could operate reversibly at equivalent C-rates as high as 1667C.

25 ENERGY STORAGE↗

Ultra-Light Precision Membrane Optics

SRS Technologies and NASA Marshall Space Flight Center have conducted a research effort to explore the possibility of developing ultra-lightweight membrane optics for future imaging applications. High precision optical flats and spherical mirrors were produced under this research effort. The thin film mirrors were manufactured using surface replication casting of CPI(Trademark), a polyimide material developed specifically for UV hardness and thermal stability. In the course of this program, numerous polyimide films were cast with surface finishes better than 1.5 nanometers rms and thickness variation of less than 63 nanometers. Precision membrane optical flats were manufactured demonstrating better than 1/13 wave figure error when measured at 633 nanometers. The aerial density of these films is 0.037 kilograms per square meter. Several 0.5-meter spherical mirrors were also manufactured. These mirrors had excellent surface finish (1.5 nanometers rms) and figure error on the order of tens of microns. This places their figure error within the demonstrated correctability of advanced wavefront correction technologies such as real time holography.

Moore, Jim↗

Micromechanisms of thermomechanical fatigue: A comparison with isothermal fatigue

Thermomechanical Fatigue (TMF) experiments were conducted on Mar-M 200, B-1900, and PWA-1480 (single crystals) over temperature ranges representative of gas turbine airfoil environments. The results were examined from both a phenomenological basis and a micromechanical basis. Depending on constituents present in the superalloy system, certain micromechanisms dominated the crack initiation process and significantly influenced the TMF lives as well as sensitivity of the material to the type TMF cycle imposed. For instance, high temperature cracking around grain boundary carbides in Mar-M 200 resulted in short in-phase TMF lives compared to either out-of-phase or isothermal lives. In single crystal PWA-1480, the type of coating applied was seen to be the controlling factor in determining sensitivity to the type of TMF cycle imposed. Micromechanisms of deformation were observed over the temperature range of interest to the TMF cycles, and provided some insight as to the differences between TMF damage mechanisms and isothermal damage mechanisms. Finally, the applicability of various life prediction models to TMF results was reviewed. Current life prediction models based on isothermal data must be modified before being generally applied to TMF.

Bill, R. C.↗

The Importance of Inventory for Informing Waste Strategy - 20280

A waste inventory aims to present the best available information about the nature, quantity and location of radioactive wastes and materials at a facility, site or in a country. Quality inventory data is necessary for developing appropriate strategies and plans for managing radioactive wastes and materials, with high standards of protection for people and the environment. The inventory of wastes will change over time due to a wide range of technical, commercial or policy reasons, for example, if reactor lifetimes are extended, if decommissioning strategies change or if new technologies are introduced for managing waste. Inventory information can also improve as better waste characterisation data becomes available. At a facility or site level, good quality inventory data are needed to underpin decision making about the waste management options and to demonstrate compliance with the chosen treatment or disposal route. At a site and country level, knowledge of the inventory can drive the improvement to waste strategy; waste management asset and service planning; and implementation. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Insert Concepts for the Material Science Research Rack (MSRR-1) of the Material Science Research Facility (MSRF) on the International Space Station (ISS)

The Material Science Research Rack I (MSRR-1) of the Material Science Research Facility (MSRF) contains an Experiment Module (EM) being developed collaboratively by NASA and the European Space Agency (ESA). This NASA/ESA EM will accommodate several different removable and replaceable Module Inserts (MIs) which are installed on orbit NASA's planned inserts include the Quench Module Insert (QMI) and the Diffusion Module Insert (DMI). The QMI is a high-gradient Bridgman-type vacuum furnace with quench capabilities used for experiments on directional solidification of metal alloys. The DMI is a vacuum Bridgman-Stockbarger-type furnace for experiments on Fickian and Soret diffusion in liquids. This paper discusses specific design features and performance capabilities of each insert. The paper also presents current prototype QMI hardware analysis and testing activities and selected results.

Crouch, Myscha↗

Impact Test and Simulation of Energy Absorbing Concepts for Earth Entry Vehicles

Nonlinear dynamic finite element simulations have been performed to aid in the design of an energy absorbing concept for a highly reliable passive Earth Entry Vehicle (EEV) that will directly impact the Earth without a parachute. EEV's are designed to return materials from asteroids, comets, or planets for laboratory analysis on Earth. The EEV concept uses an energy absorbing cellular structure designed to contain and limit the acceleration of space exploration samples during Earth impact. The spherical shaped cellular structure is composed of solid hexagonal and pentagonal foam-filled cells with hybrid graphite- epoxy/Kevlar cell walls. Space samples fit inside a smaller sphere at the center of the EEV's cellular structure. Comparisons of analytical predictions using MSC,Dytran with test results obtained from impact tests performed at NASA Langley Research Center were made for three impact velocities ranging from 32 to 40 m/s. Acceleration and deformation results compared well with the test results. These finite element models will be useful for parametric studies of off-nominal impact conditions.

Billings, Marcus D.↗

A Novel High-Performance Mission-Enabling Multi-Purpose Radioisotope Heat Source

Recent studies indicate science mission concepts targeting access to the sub-surface oceans of icy moons require ice-penetrating cryobots powered by advanced Radioisotope Power Systems (RPS). These systems would deliver waste heat for ice-melting in the range of 10 kW. Minimizing the transit time through the kilometers-thick ice shells to just a few years requires these RPS to utilize heat sources having a higher thermal energy volumetric density than the existing flight-qualified General-Purpose Heat Source (GPHS). A Compact Heat Source (CPHS)has been conceptualized in which the graphite impact shells(GIS) of the existing GPHS are rearranged in a hexagonal aeroshell containing seven GIS per module, as opposed to the standard two per module; offering a thermal energy density of 0.57 W/cm3versus 0.29 W/cm3 offered by the GPHS simply from the repackaging of Technology Readiness Level (TRL)9 subassemblies. Preliminary thermal modeling of the CPHS integrated into a notional radioisotope thermoelectric generator(RTG) structure further suggests that centerline temperatures are well within allowable limits during nominal operation. Given the need for the CPHS for a subset of missions, it is worth exploring the applicability of the CPHS for more general RTG purposes. We discuss herein how the CPHS may be implemented with either heritage or in-development thermoelectric converter technologies into a Next-Generation RTG concept. Due to a higher energy density, the legacy heat rejection fin arrangement must be modified to permit a sufficiently low cold-side temperature. Preliminary finite element analysis suggests fin-root temperatures can be kept as low as 520 K while allowing the generator to fit within the usable dimensions of currently available United States Department of Energy shipping containers. Such temperatures would certainly be compatible with the use of high temperature thermoelectric converter technologies.. A prime candidate is the heritage silicon-germanium (SiGe) unicouple, whose design could be adapted by approximately halving the leg-length, but without changes in hot and cold junction interfaces, which are features critical to the proven performance and reliability of these devices. The estimated Beginning of Life power for a SiGe-based CPHS-RTG using 12 CPHS for a thermal inventory of 10.5 kW is greater than 600 W under deep space operating conditions. Using higher performance segmented couples currently in development that are based on skutterudite,La3−xTe4and 14-1-11 Zintl thermoelectric materials in lieu of the SiGe unicouples would increase the power level to more than1 kW. The high specific power (We/kg) attribute of CPHS-RTGs found in this study could potentially enable Radioisotope Electric Propulsion (REP) mission concepts. Past NASA REP mission concept studies identified specific power needs in excess of 6to 8 We/kg. Based on a GPHS-RTG-like system configuration, we show that at fin root temperatures between 530 K and 570K (deep space environment), specific powers exceeding 10 We/kg are achievable using high performance segmented thermoelectric converters. The compact sizing and power density of the CPHS-RTG would constitute a significant step upgrade in specific power when compared to heritage GPHS-RTG (approximately5.1 We/kg) and off-the-shelf Multi-Mission RTG (approximately 2.6 We/kg).

Nesmith, Bill J.↗

Second Annual Transformative Vertical Flight Concepts Workshop: Enabling New Flight Concepts Through Novel Propulsion and Energy Architectures

On August 3rd and 4th, 2015, a workshop was held at the NASA Ames Research Center, located at the Moffett Federal Airfield in California to explore the aviation communities interest in Transformative Vertical Flight (TVF) Concepts. The Workshop was sponsored by the AHS International (AHS), the American Institute of Aeronautics and Astronautics (AIAA), the National Aeronautics and Space Administration (NASA), and hosted by the NASA Aeronautics Research Institute (NARI). This second annual workshop built on the success and enthusiasm generated by the first TVF Workshop held in Washington, DC in August of 2014. The previous Workshop identified the existence of a multi-disciplinary community interested in this topic and established a consensus among the participants that opportunities to establish further collaborations in this area are warranted. The desire to conduct a series of annual workshops augmented by online virtual technical seminars to strengthen the TVF community and continue planning for advocacy and collaboration was a direct outcome of the first Workshop. The second Workshop organizers focused on four desired action-oriented outcomes. The first was to establish and document common stakeholder needs and areas of potential collaborations. This includes advocacy strategies to encourage the future success of unconventional vertiport capable flight concept solutions that are enabled by emerging technologies. The second was to assemble a community that can collaborate on new conceptual design and analysis tools to permit novel configuration paths with far greater multi-disciplinary coupling (i.e., aero-propulsive-control) to be investigated. The third was to establish a community to develop and deploy regulatory guidelines. This community would have the potential to initiate formation of an American Society for Testing and Materials (ASTM) F44 Committee Subgroup for the development of consensus-based certification standards for General Aviation scale vertiport capable flight systems. These standards need to accommodate novel fixed wing concepts that do not fit within the existing Federal Aviation Administration (FAA) rotorcraft certification framework (Code of Federal Regulations, Title 14, Chapter I, Subchapter C, Part 27). The fourth desired outcome was to launch an information campaign to ensure key U.S. Government agencies understand the potential benefits and industry interest in establishing new vertiport capable flight markets. This record of the Workshop proceedings documents Workshop activities and products including summaries of the video recorded technical presentations, overviews of three breakout sessions (Missions Operational Concepts, Prioritized Technical Challenges, Regulatory Roadmap), and a preliminary draft roadmap framework for TVF.

V/STOL↗

Dynamic Finite Element Predictions for Mars Sample Return Cellular Impact Test #4

The nonlinear, transient dynamic finite element code, MSC.Dytran, was used to simulate an impact test of an energy absorbing Earth Entry Vehicle (EEV) that will impact without a parachute. EEVOs are designed to return materials from asteroids, comets, or planets for laboratory analysis on Earth. The EEV concept uses an energy absorbing cellular structure designed to contain and limit the acceleration of space exploration samples during Earth impact. The spherical shaped cellular structure is composed of solid hexagonal and pentagonal foam-filled cells with hybrid graphite-epoxy/Kevlar cell walls. Space samples fit inside a smaller sphere at the center of the EEVOs cellular structure. Pre-test analytical predictions were compared with the test results from a bungee accelerator. The model used to represent the foam and the proper failure criteria for the cell walls were critical in predicting the impact loads of the cellular structure. It was determined that a FOAM1 model for the foam and a 20% failure strain criteria for the cell walls gave an accurate prediction of the acceleration pulse for cellular impact.

Fasanella, Edwin L.↗

Environmental life cycle impacts of small wastewater treatment plants: Design recommendations for impact mitigation

The objective of this study was to quantify potential mitigation of environmental impacts from the operation and construction of wastewater treatment plants (WWTP) from implementing specific design recommendations. The study investigated small WWTPs, many of which are serving slow growing or declining populations. Life Cycle Assessment methodology was used to evaluate and compare the inventory and environmental impacts of nine small WWTP case studies. Detailed inventory data was collected from the facilities’ engineering design plans and utility bills. One recommended practice was to avoid significant overdesign by planning for no lower than a 75% capacity utilization by the facilities’ end-of-life. A theoretical correction to a 75% capacity utilization was estimated to mitigate 0.4% of lifetime electricity usage and 1% of secondary process concrete for every 1% reduction in design average flow rate. Relatedly, a 0.4% mitigation in the Carcinogenic and Global Warming impacts could be achieved for every 1% reduction in design average flow toward a 75% capacity utilization. Other suggested practices were focused on conveyance, namely, to minimize non-process facility area and to use polyvinyl chloride pipe instead of ductile iron pipe where possible. Furthermore, the latter practice was estimated to mitigate between 1.1 and 4.8% of the Carcinogenic impact in the nine case studies.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Sensing, Spectra and Scaling: What's in Store for Land Observations

Bill Pecora's 1960's vision of the future, using spacecraft-based sensors for mapping the environment and exploring for resources, is being implemented today. New technology has produced better sensors in space such as the Landsat Thematic Mapper (TM) and SPOT, and creative researchers are continuing to find new applications. However, with existing sensors, and those intended for launch in this century, the potential for extracting information from the land surface is far from being exploited. The most recent technology development is imaging spectrometry, the acquisition of images in hundreds of contiguous spectral bands, such that for any pixel a complete reflectance spectrum can be acquired. Experience with Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) has shown that, with proper attention paid to absolute calibration, it is possible to acquire apparent surface reflectance to 5% accuracy without any ground-based measurement. The data reduction incorporates in educated guess of the aerosol scattering, development of a precipitable water vapor map from the data and mapping of cirrus clouds in the 1.38 micrometer band. This is not possible with TM. The pixel size in images of the earth plays and important role in the type and quality of information that can be derived. Less understood is the coupling between spatial and spectral resolution in a sensor. Recent work has shown that in processing the data to derive the relative abundance of materials in a pixel, also known is unmixing, the pixel size is an important parameter. A variance in the relative abundance of materials among the pixels is necessary to be able to derive the endmembers or pure material constituent spectra. In most cases, the 1 km pixel size for the Earth Observing System Moderate Resolution Imaging Spectroradiometer (MODIS) instrument is too large to meet the variance criterion. A pointable high spatial and spectral resolution imaging spectrometer in orbit will be necessary to make the major next step in our understanding of the solid earth surface and its changing face.

Goetz, Alexander F. H.↗

The CubeSat Infrared Atmospheric Sounder (CIRAS), Pathfinder for the Earth Observing Nanosatellite-Infrared (EON-IR)

The CubeSat Infrared Atmospheric Sounder (CIRAS) will measure upwelling infrared radiation of the Earth in the MWIR region of the spectrum from space on a CubeSat. CIRAS will demonstrate two new infrared sounding technologies. The first is a 2D array of High Operating Temperature Barrier Infrared Detector (HOT-BIRD) material, selected for its high uniformity, low cost, low noise and higher operating temperatures than traditional materials. The detectors are hybridized to a commercial ROIC and commercial camera electronics. The second technology is an MWIR Grating Spectrometer (MGS) to be designed and developed by Ball Aerospace to provide imaging spectroscopy for atmospheric sounding in a CubeSat volume. The MGS has no moving parts and is based on heritage spectrometers including the Ball Aerospace Spaceborne Infrared Atmospheric Sounder for GEO (SIRAS-G) IIP of 2007. JPL will develop the mechanical, electronic and thermal subsystems for CIRAS. The spacecraft will be a commercially available CubeSat. The integrated system will be a complete 6U CubeSat capable of measuring temperature and water vapor profiles with good lower tropospheric sensitivity. The CIRAS is the first step towards the development of an Earth Observing Nanosatellite Infrared (EON-IR) for potential use in a future operational forecasting system.

Pagano, Thomas↗

Challenges and Opportunities in Decarbonizing the U.S. Energy System

The United States has pledged to develop a 100% carbon-free electric power system by 2035 and a net-zero-emissions economy by 2050. While important advancements have been made in the scale, performance, and economics of clean energy technologies, meeting the nation's ambitious goals will not only require their deployment at scale, but also additional innovation and effective integration of different solutions. Technological developments across the broad suite of low-carbon energy solutions are advancing rapidly, with ongoing innovations in renewable electricity generation, industrial processes, and energy-saving technologies and services, including LED lighting, induction heating, electric vehicles, energy storage solutions, and mobility as a service, plus smart devices, controls, and more efficient and smart buildings. Combining renewable electricity with biotic and abiotic pathways to produce chemicals, fuels, and materials promises to deliver new solutions. Grid-interactive buildings and communities, integrating transportation infrastructure and vehicles, are likely to be significant components of any zero-carbon energy strategy. Low-carbon industrial manufacturing will also make strong contributions to a net-zero economy. While the technical prospects appear promising, variations in the state of infrastructure, jurisdictional and social equity, pollution, economic and socio-cultural constraints, energy resource availability, and supply chain dynamics found in different locations present a range of challenges and demand customized solutions. This paper provides a critical review and offers new insights into the technical, infrastructure, analytic, political, and economic challenges faced in translating the nation's ambitious net-zero-emissions goals into feasible and reliable implementation action plans.

circular economy↗

Self Assembled Monolayers for Passivated Contacts

Passivated contacts mitigate defects typically encountered due metallization of solar cells. We deposit amorphous silicon (a-Si:H) on an oxidized silicon wafer via PECVD and anneal at high temperature to crystallize into polysilicon passivated contact. One drawback is the absorption of the polysilicon between grid fingers, so removal of this material is desirable to maximize Jsc. Alternatively, interdigitated back contact cells rely on a gap between n- and p- fingers, which is commonly etched to ensure electronic isolation. We utilize a self assembled monolayer (SAM) using hexamethyldisilazane (HMDS) as a precursor to pattern and etch amorphous silicon (a-Si:H) and polysilicon without the need for photoresist. Ultraviolet light exposure oxidizes the HMDS by photocleaving the organic groups [1] of the SAM leaving a patterned SiO2. Directly soaking this in TMAH will eventually etch the SAM and the silicon, where the SiO2 serves as an etch mask. Inversely, a dilute HF dip selectively etches this SiO2 and the SAM remains. A subsequent soak in TMAH selectively etches the underlying silicon, where the SAM serves as an etch mask. Importantly, we find that the SAM can remain intact for metallization, where we measure 10 mO-cm2 specific contact resistivity on n-type polysilicon.

passivation↗

Periodontal Probe Improves Exams, Alleviates Pain

Dentists, comedian Bill Cosby memorably mused, tell you not to pick your teeth with any sharp metal object. Then you sit in their chair, and the first thing they grab is an iron hook!" Conventional periodontal probing is indeed invasive, uncomfortable for the patient, and the results can vary greatly between dentists and even for repeated measurements by the same dentist. It is a necessary procedure, though, as periodontal disease is the most common dental disease, involving the loss of teeth by the gradual destruction of ligaments that hold teeth in their sockets in the jawbone. The disease usually results from an increased concentration of bacteria in the pocket, or sulcus, between the gums and teeth. These bacteria produce acids and other byproducts, which enlarge the sulcus by eroding the gums and the periodontal ligaments. The sulcus normally has a depth of 1 to 2 millimeters, but in patients with early stages of periodontal disease, it has a depth of 3 to 5 millimeters. By measuring the depth of the sulcus, periodontists can have a good assessment of the disease s progress. Presently, there are no reliable clinical indicators of periodontal disease activity, and the best available diagnostic aid, periodontal probing, can only measure what has already been lost. A method for detecting small increments of periodontal ligament breakdown would permit earlier diagnosis and intervention with less costly and time-consuming therapy, while overcoming the problems associated with conventional probing. The painful, conventional method for probing may be destined for the archives of dental history, thanks to the development of ultrasound probing technologies. The roots of ultrasound probes are in an ultrasound-based time-of-flight technique routinely used to measure material thickness and length in the Nondestructive Evaluation Sciences Laboratory at Langley Research Center. The primary applications of that technology have been for corrosion detection and bolt tension measurements (Spinoff 2005). This ultrasound measurement system was adapted to the Periodontal Structures Mapping System, invented at Langley by John A. Companion, under the supervision of Dr. Joseph S. Heyman. Support of the research and development that led to this invention was provided by NASA s Technology Applications Engineering Program and by the Naval Institute for Dental and Biomedical Research, in Great Lakes, Illinois.

Source record↗

Ln 10 S 14 O (Ln = La, Pr, Nd, Sm) Oxysulfides: A Series of Direct n-Type Semiconductors

Lanthanoid oxysulfides are promising materials for technological applications owing to their magnetic, photoluminescent, catalytic, and optoelectronic properties. In this work, we report the solid-state synthesis and structural characterization of Ln 10 S 14 O (Ln = La, Ce, Pr, Nd, Sm) oxysulfides. Then, we present a thorough discussion on their electronic and photophysical properties. Through Tauc plot analysis and the derivation of the absorption spectrum fitting method (DASF), we determine that all oxysulfides have direct band gaps with energies of 2.84 eV (La), 2.02 eV (Ce), 2.56 eV (Pr), 2.64 eV (Nd), and 2.41 eV (Sm). Furthermore, surface photovoltage spectroscopy (SPS) shows photovoltage (ΔCPD) values of –0.4 to –1.1 V for La-, Pr-, Nd-, and Sm-containing compounds when illuminated near the optical band gap, indicating that these oxysulfides are n-type semiconductors, which is consistent with Mott–Schottky analysis. Photovoltages under sub-band gap illumination energy and photovoltage decay data suggest mid-band gap states possibly arising from the lanthanoid 4f orbitals and/or defects within the crystal structure or at the particle surfaces. These photophysical properties suggest possible applications of the oxysulfides in photoelectrochemical and photovoltaic energy conversion.

14 SOLAR ENERGY↗

NuMI Graphite Target Fin Removal Assembly

Materials scientists want to study the irradiated graphite target from the Neutrino at the Main Injector (NuMI) beam line. In order to gather these irradiated graphite fins from the target canister, it will have to be done remotely. Therefore, a removal assembly will need to be created in order to do this efficiently and well. This project aims to make progressive steps towards deploying the final target removal assembly. Furthermore, calculations related to the removal assembly design were done, and tests were planned to discover further information about the feasibility of this design. The main result from this project is the deflection of the cantilever arm, which is 0.354 inches due to the weight of the beam and cutting tool. Additionally, more results of this project are the testing assembly CAD model and the feasibility of design. This project concludes that there is still more work that needs to be done for the removal assembly to be deployed, but there were foundational steps that were made in the implementation of this design. Finally, there should be further steps and tests to determine the feasibility of this removal assembly.

Malovski, Azra [NIU, DeKalb]↗

Monitoring Based Commissioning: Step-by-Step Approach to Implementation in Chiller Plants

Chilled water systems consume a significant portion of the energy in manufacturing, and inefficient operation could significantly influence utility bills and the environmental footprint of a facility. One way to ensure long-term energy-efficient plant operation is to ensure that chilled water system equipment, such as chillers, cooling towers, and pumps, are running at their best. Periodic operational assessments help to meet efficiency objectives for cooling plants. However, occasional set point and operational changes resulting from short-term fluctuations cause the plant operation to deviate from optimal. These changes accumulate over time, and operational efficiency deteriorates. Significant energy efficiency improvement potential in chilled water systems can be achieved by operational changes alone. Recent developments in information technology and the industrial internet of things data processing ability have overcome traditional problems and given rise to a new paradigm: monitoring-based commissioning (MBCx). Commissioning platforms and fault detection and diagnostics capabilities have evolved over time and presented more sophisticated abilities to efficiently control process cooling plants. The typical architectures of the MBCx process and a detailed approach to implement the process for chilled water systems are presented. A case study highlighting the energy-and cost-savings potential of MBCx systems is also presented.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗