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Terrestrial Water Storage

Terrestrial water storage can be defined as the summation of all water on the land surface and in the subsurface. It includes surface soil moisture, root zone soil moisture, groundwater, snow,ice, water stored in the vegetation, river and lake water. Terrestrial water storage (TWS) changes have been observed by the Gravity Recovery and Climate Experiment (GRACE) mission since 2002. GRACE has provided an unprecedented view of the terrestrial water storage variations at large scales. Extremes in water storage often are associated with droughts and flooding events because they are driven by the surplus or deficit of water. Few hydrologic observing networks yield sufficient data for comprehensive monitoring of changes in the total amount of water stored in a region. GRACE observations have helped to fill this gap. This book chapter is divided into 4 sections.Section 1 provides an overview of the GRACE mission. Section 2 reviews the terrestrial water storage solutions that are available. Section 3 describes regional to global applications of GRACE for monitoring extremes in the terrestrial water storage, including droughts and flooding events. Conclusions and future directions are reported in Section 4.

Terrestrial Water Storage↗

Pilot Development Progress to Demonstrate Electric Thermal Energy Storage (ETES) Using Low-Cost Particles

The rapid growth of future energy demand increases the need to economically store electrical energy over durations up to several days in long-duration energy storage (LDES) applications. LDES can reduce the grid stress for improving the resilience of the grid. The integration of renewable power and storage has several significant and positive impacts including expanding the renewable energy portion of electricity generation, meeting peak-load demand, and coordinating supply and demand. Several energy storage approaches including mechanical, chemical and electrochemical methods are currently deployed or under development. However, LDES requirements pose unique challenges for scalability, energy capacity, and cost. Thermal energy storage (TES) has the ability to store a large capacity of energy with improved site flexibility compared to incumbent LDES technologies (i.e., pumped hydro) and has attracted significant interest. Our development in TES technology using solid particles as the storage medium has shown feasibility and potential in serving LDES purposes. Particle TES has various advantages over commercialized molten nitrate salt TES and has emerged as a promising storage technology originating from Generation 3 concentrating solar power (CSP) development. Stable, inexpensive silica sand produced in the Midwestern U.S. was identified as a suitable storage medium and has been validated through lab heating and cycling tests. We have successfully developed particle TES for bidirectional electric energy storage to broaden the applications for TES beyond CSP technologies and into standalone electric-thermal energy storage (ETES) systems. Key component designs and performance were verified with prototype testing and model simulations. The ETES system uses high-temperature, low-cost particle thermal energy storage coupled with a unique pressurized fluidized bed heat exchanger that supports a high-efficiency, air-Brayton combined power cycle. At times of low energy demand or high renewable production, an electric particle heater heats large quantities of solid particles to high temperatures in excess of 1100 degrees C. The particles are stored in internally insulated silos. At times of high electricity demand, the hot particles are gravity-fed through the heat exchanger where stored thermal energy is transferred to the power cycle working fluid to drive the gas turbine power generation system, thereby converting the thermal energy back into electricity for the grid. The cold particles leaving the heat exchanger are returned to the storage silos by a well-insulated particle conveyor. This ETES technology using particle TES can be sited anywhere and is predicted to be economic and efficient. Moreover, this ETES technology could be co-located with a retired coal or gas plant to leverage existing power generation and grid infrastructure. Our work has focused on the development of each of the key components (e.g., the electric particle heater, particle storage silos, and the particle-to-gas pressurized fluidized bed heat exchanger) through conceptual designs, prototype testing, and computational modeling. These developments demonstrate technological feasibility and are an important step towards the next phase of development of this promising LDES technology. This presentation will show the progress in developing a pilot demonstration of the ETES system on a commercially relevant scale.

25 ENERGY STORAGE↗

Improved Cost Estimates to Boost Pumped Storage Hydropower Construction

Pumped storage hydropower is often overlooked in future grid planning efforts, in part because the cost to build a new facility is not always clear. That's why the National Renewable Energy Laboratory (NREL), along with the U.S. Department of Energy's Water Power Technologies Office, is developing improved cost estimates and cost models to reduce that uncertainty and give developers the data they need to decide where and when to construct new PSH facilities to support the country's evolving energy grid.

ENERGY PLANNING, POLICY, AND ECONOMY,HYDRO ENERGY↗

U.S. Solar Photovoltaic System and Energy Storage Cost Benchmarks, With Minimum Sustainable Price Analysis: Q1 2022

NREL's bottom-up cost models can be used to assess the minimum sustainable price (MSP) and modeled market price (MMP) of PV and storage systems having various configurations. MSP can be used to estimate future potential cost-reduction opportunities for PV and PV-plus-storage systems, thus helping guide research and development aimed at advancing cost-effective system configurations. MMP can be used to understand the cost of systems under recent market conditions. The MSP data in this annual benchmarking report will be used to inform the formulation of, and track progress toward, the Solar Energy Technologies Office's Government Performance and Reporting Act cost targets.

14 SOLAR ENERGY↗

Electronic and Geometric Contributors to Hydrogen Binding in Uranium Oxide Grain Boundaries

Hydrogen induced corrosion of uranium, which leads to the formation of toxic and pyrophoric UH 3 , raises significant safety concerns for long-term storage of nuclear materials. Previous work suggests hydrogen diffuses through the grain boundaries (GBs) of the passivating oxide layer to initiate hydriding reactions. However, the atomistic mechanisms underlying this phenomenon and the structural factors that control its initiation are not well understood. To address this knowledge gap, here we use a high-throughput density functional theory (DFT) workflow to investigate the adsorption of H and H 2 in the defective bulk UO 2 . Specifically, we have exhaustively investigated the adsorption of H (107 sites) and H 2 (26 sites) in three different coincident site lattice (CSL) GBs: Σ3, Σ5, and Σ9. Compared to the binding energies in pristine UO 2 , we observe significantly stronger hydrogen adsorption at these GB sites. Interestingly, we find that the trends in H and H 2 adsorption vary considerably across the three GB models. In particular, while a small number of sites in Σ5 and Σ9 show exothermic adsorption of H and H 2 , respectively, no such sites are found in Σ3. These results provide fundamental atomistic insights that could guide the development of future corrosion mitigation strategies for the storage of nuclear materials.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Quantum computing and quantum information storage

Quantum storage, transmission, and processing is the future of information technology. Here, the promise of quantum hardware stems from the inherent complexity of an entangled quantum system—the size of the wave-function scales exponentially with the number of particles, whether represented in real space or in a parameter space. In contrast, a classical N-body system can be completely represented by only 6N variables (positions and momenta of all particles). This complexity of quantum systems creates a yet-unsolved challenge of modeling quantum systems by means of classical computing—the curse of dimensionality. Indeed, although we can easily write the Schrödinger equation for any system of interacting nuclei and electrons, we can only solve it exactly on classical computers for very small systems.

97 MATHEMATICS AND COMPUTING↗

Tank Pressure Control Experiment - A low-g mixing investigation

The Tank Pressure Control Experiment (TPCE) was conceived to meet the need for an aspect of cryogenic fluid management technology that is critical to several future national space missions: control of cryogenic storage tank pressures by active mixing. In-space testing is the only means of obtaining the fluid dynamic data necessary to develop and test predictive models of mixing. These models, when validated, will allow future cryogenic systems to be designed with more efficient and reliable pressure control systems. The objectives of the TPCE project are to characterize the fluid dynamics of jet-induced mixing in low gravity, evaluate the validity of empirical models and correlations, and provide data for use in developing and validating computational fluid dynamic models. This paper discusses prior studies of low-g mixing, the objectives and benefits of TPCE, the design and status of the payload, and preliminary results obtained from low-g aircraft testing.

Bentz, M. D.↗

Valuing the Future Electric Grid: A Bid-Based Approach

Energy storage resources (ESRs) and other zero marginal cost (ZMC) resources have unique characteristics that are not fully captured in today’s electricity planning and operations modeling tools. Because the modeling assumptions used in these tools are simplified approximations of how operations and investment decisions occur in the real-world, accurately representing cost and operational characteristics are key for determining how these resources impact price formation. Questions such as—Where should we build new transmission? Will a small modular reactor earn enough revenue to participate in the future electric grid? Is retrofitting a coal plant with carbon capture technology economically feasible?—all require accurate electricity prices, which aren’t available from today’s electricity planning and operations modeling tools. As an example, production cost models (PCMs) are heavily utilized tools that determine the cost and reliability of the electric system. However, as PCMs were developed to help thermal generators manage their fuel inventories, production cost modeling is largely based on fuel prices. Because ESRs do not incur fuel costs, they are often modeled as ZMC resources. In reality, ESRs incur opportunity costs as well as technology-specific (degradation) costs that are non-trivial to calculate but are important for price formation. In this research, we identify options to incorporate more realistic opportunity and degradation costs in ESR bidding algorithms. Expanding available bidding assumptions allows energy system modelers to develop more accurate economic valuations for ESRs, leading to more accurate price formation from leading energy system modeling tools.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Cost-Effective High Reliability for Space Life Support Requires Using Storage

Cost-effective high reliability can be achieved in future space life support systems through careful systems analysis and design. This paper outlines a comprehensive approach. Potential future human space missions are described. The mission parameter impacts on life support system design and reliability requirements are discussed. Not all human space missions require high reliability life support. The potential reliability and cost of storage and of recycling life support systems are investigated. Simple storage systems can provide cost-effective high reliability life support where it is needed. More complex recycling systems with lower reliability and higher cost can be used when suitable.

Jones, Harry W.↗

Pumped Storage Hydropower (PSH) FAST Commissioning Prize Technical Analysis

The US energy landscape has undergone major changes over the past 10 years and will continue to see significant changes in future decades as the power grid increases its reliance on variable renewable energy resources. Because of the inherent variability of these resources, renewable energy growth may require additional energy storage capacity to provide flexible load-following capabilities and other grid services that can quickly adjust to changes in energy demand and generation. Pumped storage hydropower (PSH)—one such energy storage technology—uses pumps to convey water from a lower reservoir to an upper reservoir for energy storage and releases water back to the lower reservoir via a powerhouse for hydropower generation. PSH facility pump and generation cycling often follows economic and energy demand conditions. Across the United States, 43 PSH facilities are in operation and 55 projects are in various permitting or licensing stages. Altogether, the 43 operational projects provide the wide majority (95%) of utility-scale electricity storage in the United States. These facilities also provide significant power and nonpower grid benefits, including large-scale electrical system reserve capacity, grid reliability support, and electricity supply-demand balancing through quick-response capabilities and operational flexibility. PSH systems can accomplish these at a scale (e.g., size) and cost that makes these systems highly attractive from a technical standpoint. Although these research concepts are still in their infancy, they demonstrate promising potential as future PSH energy storage technologies. Although PSH has many advantages, development in the United States has effectively stalled since the 1990s, partially because of the magnitude of project costs and financing interest during development and construction, the length of time from project investment until project revenue begins, permitting challenges, construction risks, competition from other storage technologies (e.g., batteries, hydrogen storage), and electricity market evolution and uncertainty. In short, the time, cost, and risk associated with modern PSH development have resulted in limited growth in the United States recently, despite the growing energy storage demand stemming from increased wind and solar power deployment. Technology innovation is needed to help reduce PSH commissioning time, cost, and risk, particularly during the post-licensing phase of project development. To address challenges facing the PSH industry and to improve PSH commissioning timelines, the US Department of Energy (DOE) Water Power Technologies Office (WPTO) initiated the PSH Furthering Advancements to Shorten Time to (FAST) Commissioning Prize project.

13 HYDRO ENERGY↗

Current status and future directions of multivalent metal-ion batteries

Batteries based on multivalent metals have the potential to meet the future needs of large-scale energy storage, due to the relatively high abundance of elements such as magnesium, calcium, aluminium and zinc in the Earth’s crust. However, the com- plexity of multivalent metal-ion chemistries has led to rampant confusions, technical challenges, and eventually doubts and uncertainties about the future of these technologies. In this Review, we clarify the key strengths as well as common misconceptions of multivalent metal-based batteries. We then examine the growth behaviour of metal anodes, which is crucial for their safety promises but hitherto unestablished. We further discuss scrutiny of anode efficiency and cathode storage mechanism pertaining to complications arising from electrolyte solutions. Lastly, we critically review existing cathode materials and discuss design strategies to enable genuine multivalent metal-ion-based energy storage materials with competitive performance.

25 ENERGY STORAGE↗

Human mononuclear cell function after 4 degrees C storage during 1-G and microgravity conditions of spaceflight

Future space missions of long duration may require that autologous leukocytes be stored in flight for infusion to restore normal immune competence in crewmembers. Peripheral blood mononuclear cells (PBMNCs), as leukocyte concentrates in autologous plasma and 2% dextrose, were stored in the microgravity conditions provided by the U.S. Space Shuttle Columbia (Mission 61-C). Activity of PBMNC after space flight was compared with that from a series of preflight ground control experiments, which demonstrated in culture a progressive daily loss in mitogen-stimulated protein synthesis at 24 h and thymidine uptake at 72 h after storage for 7 d at 4 degrees C. Post-storage viabilities were at least 90% as determined by trypan dye exclusion. A progressive reduction in the percentage of PBMNC expressing cell-surface phenotype markers, which was similar for monocytes, B cells, and T-cell subsets, also occurred after storage. The ability of PBMNC, stored for 8 d in Columbia's middeck, to become activated and proliferate in vitro was similar to that of cells that remained in identical flight lockers on the ground as 1-G controls, thus indicating that PBMNCs were not adversely affected by storage under microgravity conditions.

NASA Discipline Number 00-00↗

Utilizing Commercial Submersible Mixer Pumps for Sludge Removal in Savannah River Site's Tank 26 - 20289

The Savannah River Site (SRS) Liquid Waste System (LWS) safely manages, stores, treats, and dispositions liquid radioactive waste. The LWS consists of 51 underground waste storage tanks (eight of which are operationally closed and filled with grout), waste evaporators, treatment facilities, and solidification facilities, known as the Defense Waste Processing Facility (DWPF) and Saltstone Production Facility (SPF). One of the waste storage tanks, Tank 26, was placed into service in 1980 as an F Tank Farm (FTF) Evaporator Feed Tank. From 1980 to 2013, Tank 26 received F Canyon receipts and dilute supernate that was then transferred to the 242-16F FTF Evaporator for volume reduction. In 2013, the steam tube bundle failed in the FTF Evaporator, and the decision was made not to repair/resume evaporator operation. During operation of Tank 26, solids built up to a level of 2.03 m in the tank with a volume of 1062.9 kL. Due to the evaporator failure and subsequent shutdown, the solids in Tank 26 were selected to feed Sludge Batch 10, which is collected and prepped prior to being sent to DWPF for final disposition. To accomplish solids removal, Commercial Submersible Mixer Pumps (CSMPs) were selected to slurry the solids in preparation to be sent to Tank 51. Four CSMPs were installed in Tank 26 with each one installed in a separate quadrant of Tank 26. This work would mark the first deployment of CSMPs in an SRS waste tank. The CSMPs were developed in response to operational issues from previous mixing pumps and budgetary constraints. The CSMPs use the concept of modifying commercially available equipment for nuclear waste applications. The CSMPs consist of a 230-horsepower submersible mixing pump (manufactured by GPM, Inc.) joined to a mast fabricated at SRS. For this application, Savannah River Remediation (SRR) design services was challenged to provide a mast design that required no steel superstructure support system on top of Tank 26. Also, SRR design services provided a simplified Tank 26 riser interface that did not require extensive machine parts to adjust height of the suction screen of the CSMP within the tank. Other design improvements include no requirements for tank top radiation monitors and no requirements for flushing of the CSMPs during startup/shutdown operations. The CSMPs were operated at an initial height of 2.29 m above the Tank 26 bottom for 10 days. After sludge sounding, the CSMPs were lowered to a height of 1.52 m with no issues due to proper work planning and the simplified riser interface. With the CSMPs lowered to a level of 1.52 meters above the tank bottom, the CSMPs were operated for 12 days and another sounding was performed. The sounding level came back matching the disturbance depth results of the first pump run. Chemistry samples were analyzed while the tank was left to settle. The analysis revealed enough weight percent solids to provide good feed to Sludge Batch 10. Also, the results revealed the supernate within the mixture would provide good salt solution feed to Salt Waste Processing Facility (SWPF) Salt Batch 3. So, the plan was modified to let the disturbed solids settle and decant the salt solution for addition to SWPF Salt Batch 3. Then water will be added back to Tank 26, and the CSMPs run in order to wash the solids to decrease settling time prior to being sent to Tank 51 for Sludge Batch 10. Utilizing CSMPs for waste removal in an SRS Tank has provided a cost-effective means for further waste removal efforts. In addition, the CSMPs are easier to operate by utilizing a robust and simplified design. The CSMPs performed quite well with no process shutdown or delays during operation. As a result, CSMPs are integral to the future of removing radioactive waste from storage tanks at SRS. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Wyoming Carbon Blueprint A Roadmap for Statewide Carbon Capture and Storage

Wyoming stands at a pivotal point in defining its energy future, and the Wyoming Carbon Blueprint positions the state to lead the nation in carbon management through a coordinated buildout of carbon capture, transportation, utilization, and geologic storage. Building on Wyoming’s long history as a major producer of coal, oil, and natural gas, and supported by favorable policies, skilled labor, and robust subsurface resources, the Blueprint outlines a pathway to develop one of the world’s first open-access carbon hubs capable of capturing between 10 and 25 million tonnes of CO₂ per year within five years, and up to 45 million tonnes within a decade. In doing so, it advances the concept of “No Carbon Left Behind”: a statewide strategy that prevents stranded CO₂ by aligning capture, transport, and storage systems into a single coherent infrastructure network.

54 ENVIRONMENTAL SCIENCES↗

A Highly Soluble Iron–Based Posolyte Species with High Redox Potential for Aqueous Redox Flow Batteries

A novel iron-based posolyte redox species are presented for an aqueous redox flow battery, (Tetrakis(2-pyridylmethyl)ethylenediamine)iron(II) dichloride, which is obtained by a simple synthetic route, shows a high redox potential of 0.788 V versus SHE, and exhibits exceptional aqueous solubility of 1.46 M. Paired with bis(3-trimethylammonio)propyl viologen tetrachloride at neutral pH, the battery demonstrates an open-circuit voltage of 1.19 V and delivers good cycling performance, with a capacity fade rate of 0.28% per day and coulombic efficiency of 99.3%. Postmortem chemical and electrochemical analyses of the posolyte species suggest future routes for stabilization of the complex. Among all the iron complexes with a redox potential above 0.4 V versus SHE, this compound exhibits the highest solubility. Furthermore, these results offer valuable insights that can be applied to the development of future posolyte species for sustainable energy storage solutions.

25 ENERGY STORAGE↗

The Ethanol–Ethyl Acetate System as a Biogenic Hydrogen Carrier

Liquid organic hydrogen carriers will likely be a key element of a future hydrogen economy by enabling the storage and transport of large quantities of hydrogen. Ethanol is a liquid organic hydrogen carrier that is readily available from biological resources, which undergoes a reversible reaction to yield hydrogen and ethyl acetate. The objective of the present study is to obtain a better understanding of the thermodynamic and environmental suitability of the ethanol–ethyl acetate cycle for hydrogen storage applications. The analysis covers three aspects: thermodynamics of the chemical reaction, energy balance of the process, and a first‐order assessment of greenhouse gas emissions. Thermodynamics of the reaction are characterized by a standard Gibbs energy of reaction close to zero which allows the reaction to be shifted between hydrogenation and dehydrogenation within a moderate window of temperature and pressure conditions. The energy demand for dehydrogenation is comparatively small, resulting in an overall system efficiency of 88%. A life cycle greenhouse gas analysis over a 20‐year storage system lifetime gives a carbon intensity of 7.0 kg‐CO 2eq /kg‐H 2 delivered. These results indicate that the ethanol–ethyl acetate system has considerable promise as a hydrogen carrier and should be the subject of further research.

08 HYDROGEN↗

Design Principles of Single Atoms on Carbons for Lithium–Sulfur Batteries

The study of lithium-sulfur (Li-S) batteries has generated various rationally designed cathodes and modified separators. However, the shuttle of soluble lithium polysulfides (LiPSs) and the sluggish kinetics of transformation of LiPSs to Li2S2/Li2S still hinder the achievement of long-life cycling and high-rate of Li-S batteries. Even though several kinds of nanocatalysts have been studied, the catalytic effects for Li-S batteries are not ideal. Single atoms (SAs) with high surface free energy are found to serve as both anchoring and electrocatalytic centers for LiPSs. Furthermore, atomically dispersed metal catalyst on carbon provide conductive and flexible host for dielectric sulfur. Moreover, SAs as the uniform lithiophilic sites can reduce the nucleation overpotential and ensure uniformly plating of Li. In this review, the latest strategies for preparation of SAs supported on carbons are provided on the application of Li-S batteries, including cathode, modified separator and Li metal anode. In addition, it also discusses how SAs with high catalytic activity can help build better Li-S batteries and the design principles for SAs. Finally, the future directions of SAs in energy storage applications is proposed.

25 ENERGY STORAGE↗

Vacuum-Free, All-Solution, and All-Air Processed Organic Photovoltaics with over 11% Efficiency and Promoted Stability Using Layer-by-Layer Codoped Polymeric Electrodes

Nonfullerene organic photovoltaics (OPVs) have achieved a breakthrough in pushing the efficiency beyond 15%. Although this sheds light on OPV commercialization, the high cost associated with the scalable device fabrications remains a giant challenge. Herein, a vacuum-free, all-solution and all-air processed OPV is reported that yields 11.12% efficiency with a fill factor of 0.725, due to the usages of high-merit polymeric electrodes and modified active blends. The design principle toward the high-merit electrodes is to induce heavy acid doping into the matrices for a raised carrier concentration and mobility, make a large removal of insulating components in the whole matrices rather than surfaces, and restrain the formation of large-domain aggregates. A unique layer-by-layer doping is developed to enable the polymeric electrodes with record-high trade-offs between optical transmittance and electrical conductivity. Moreover, solvent vapor annealing is proposed to boost device efficiency and it has the advantages of finely adjusting the active blend morphology and raising the electron mobility. The resulting devices are highly efficient and most (≈91%) of the initial efficiency are maintained in 30 day storage. Finally, this work indicates bright future for making cost-effective all-solution processed OPVs in air.

14 SOLAR ENERGY↗