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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 433 records · Page 24

Impact of multimode range and location on urban fuel economy on a light-duty spark-ignition based powertrain using vehicle system simulations

Multimode engine operation uses two or more combustion modes to maximize engine efficiency across the operational range of a vehicle to achieve higher overall vehicle fuel economy than is possible with a single combustion mode. More specifically for this study, multimode solutions are explored that make use of boosted SI under high load operation and other advanced combustion modes such as advanced compression ignition (ACI) under part-load conditions to enable additional engine efficiency improvements across a broader range of the engine operating map. ACI combustion has well-documented potential to improve efficiency and emissions under part-load operation but poses challenges that limit full engine speed-load range. This study investigates the potential impact of ACI operational range on simulated fuel economy to help focus research on areas with the most opportunity for improving fuel economy. These simulations make use of a vehicle model, discretized engine data, and employ a systematic exploration of ACI operational range to estimate multimode fuel economy for a mid-size passenger vehicle over U.S. Environmental Protection Agency’s Urban Dynamometer Driving Schedule. The results of this study highlight operational ranges with the highest potential fuel economy and correspondingly areas of focus for multimode research and ACI engine operation1.

Curran, Scott↗

Airborne flux measurements of ammonia over the southern Great Plains using chemical ionization mass spectrometry

Abstract. Ammonia (NH3) is an abundant trace gas in the atmosphere and an important player in atmospheric chemistry, aerosol formation and the atmosphere–surface exchange of nitrogen. The accurate determination of NH3 emission rates remains a challenge, partly due to the propensity of NH3 to interact with instrument surfaces, leading to high detection limits and slow response times. In this paper, we present a new method for quantifying ambient NH3, using chemical ionization mass spectrometry (CIMS) with deuterated benzene cations as reagents. The setup aimed at limiting sample–surface interactions and achieved a 1σ precision of 10–20 pptv and an immediate 1/e response rate of < 0.4 s, which compares favorably to the existing state of the art. The sensitivity exhibited an inverse humidity dependence, in particular in relatively dry conditions. Background of up to 10 % of the total signal required consideration as well, as it responded on the order of a few minutes. To showcase the method's capabilities, we quantified NH3 mixing ratios from measurements obtained during deployment on a Gulfstream I aircraft during the HI-SCALE (Holistic Interactions of Shallow Clouds, Aerosols, and Land-Ecosystems) field campaign in rural Oklahoma during May 2016. Typical mixing ratios were 1–10 parts per billion by volume (ppbv) for the boundary layer and 0.1–1 ppbv in the lower free troposphere. Sharp plumes of up to tens of ppbv of NH3 were encountered as well. We identified two of their sources as a large fertilizer plant and a cattle farm, and our mixing ratio measurements yielded upper bounds of 350 ± 50 and 0.6 kg NH3 h−1 for their respective momentary source rates. The fast response of the CIMS also allowed us to derive vertical NH3 fluxes within the turbulent boundary layer via eddy covariance, for which we chiefly used the continuous wavelet transform technique. As expected for a region dominated by agriculture, we observed predominantly upward fluxes, implying net NH3 emissions from the surface. The corresponding analysis focused on the most suitable flight, which contained two straight-and-level legs at ∼ 300 m above ground. We derived NH3 fluxes between 1 and 11 mol km−2 h−1 for these legs, at an effective spatial resolution of 1–2 km. The analysis demonstrated how flux measurements benefit from suitably arranged flight tracks with sufficiently long straight-and-level legs, and it explores the detrimental effect of measurement discontinuities. Following flux footprint estimations, comparison to the NH3 area emissions inventory provided by the U.S. Environmental Protection Agency indicated overall agreement but also the absence of some sources, for instance the identified cattle farm. Our study concludes that high-precision CIMS measurements are a powerful tool for in situ measurements of ambient NH3 mixing ratios, and even allow for the airborne mapping of the air–surface exchange of NH3.

58 GEOSCIENCES↗

DOE Cold Climate Heat Pump Challenge: Development, Metrics, and Early Field Observations

Space heating in residential buildings is a major contributor of Greenhouse Gas (GHG) emissions in the United States. New, advanced electric heat pumps are poised to provide a low carbon alternative to traditional fossil-based heating, especially in colder climates. Widespread deployment of cold climate heat pumps could help address the significant portion of building emissions and primary energy used in American households, but these gains will require broader acceptance from consumers and decision makers. As part of the “Energy, Emissions, and Equity” (E3) initiative, the U.S. Department of Energy launched the Cold Climate Heat Pump Challenge (CCHP) in 2021 to accelerate the deployment of the next generation of air source heat pumps. The Challenge is currently focused on residential, centrally ducted, electric heat pumps, with a nominal cooling capacity greater than or equal to 24,000 Btu/h (2 tons) and less than or equal to 65,000 Btu/h (5 tons). The Challenge specifications represent a best-in-class heat pump product that provides high-efficiency heating performance in cold climates, employs environmentally friendly low-Global Warming Potential (GWP) refrigerants, and is designed to be grid interactive. Spearheaded by DOE in partnership with the US Environmental Protection Agency (EPA) and Natural Resources Canada (NRCan), the CCHP Challenge brings together numerous major heat pump manufacturers and key stakeholders including utilities and state agencies across the country. In addition to performance testing in a laboratory environment, a key component of this research is evaluating the in-field performance of the prototype heat pumps developed as part of the Challenge. This paper will discuss the development of the CCHP Challenge, key performance specifications, and the energy and non-energy metrics that will be evaluated through the field study. The types of data that are being collected from the units installed in homes across North America as part of the field validation will be described, including details about the sensors and data acquisition system. Data cleaning and analysis methodologies will be discussed, along with early observations from the winter 2022-2023, spring and summer performance periods, and an assessment of non-energy metrics through pre- and post-installation homeowner surveys. Challenges uncovered and lessons learned throughout the process will also be discussed. Finally, the paper will discuss next steps for the second winter assessment period, areas needing additional research, and potential applications of the data collected and analyzed through this work.

Mendon, Vrushali V.↗

Flexible Operation of Natural Gas Power Plants in Texas: Startup and Shutdown Durations and Nitrogen Dioxide Emissions

This dataset provides insights into historical flexible operation of natural gas power plants in Texas, with a focus on startup and shutdown events. The dataset includes tables summarizing startup and shutdown durations as well as nitrogen oxide (NOx) emission factors during these events, and compares these emission factors with those observed during all other operating phases (referred to here as “steady-state operation”). The dataset is derived using the U.S. Environmental Protection Agency (EPA)’s Clean Air Markets Program Data (CAMPD). Historical hourly data from 2015–2024, including electricity generation, heat input, and NOx emission factors, are used for natural gas combined cycle units, combustion turbine units, and steam turbine units in Texas. This work was authored by the National Laboratory of the Rockies, operated by the Alliance for Energy Innovation, LLC, for the U.S Department of Energy (DOE) under contract no. DE-AC36-08GO28308. Funding was provided by the U.S. Department of Energy as part of its Grid Modernization Laboratory Consortium, a strategic partnership between DOE and the national laboratories to bring together leading experts, technologies, and resources to collaborate on the goal of modernizing the nation’s grid. The views expressed in the dataset do not necessarily represent the views of the DOE or the U.S. Government.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Nuclear Energy Model Intercomparison Project

This document summarizes the current status and future plans of the Nuclear Model Intercomparison Project. The objectives of this project are to understand how issues central to nuclear energy are modeled in long-term capacity expansion models, to investigate how model structures and input assumptions impact projections for nuclear’s role, to refine model representations of nuclear energy, and to communicate findings to the research community and decision-makers. High-level goals are discussed for each of the four participating model groups: the U.S. Energy Information Administration (EIA), U.S. Environmental Protection Agency (EPA), Electric Power Research Institute (EPRI), and National Renewable Energy Laboratory (NREL). This document summarizes scenarios and assumptions for the model comparison, outcomes from the first workshop, and next steps.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Promoting Domestic and International Consensus - Program Area 1: Carbon Capture & Storage & Clean Energy Systems

This is the Final Report for the U.S. Department of Energy Cooperative Agreement DE-FE-0024159, Promoting Domestic and International Consensus on Fossil Energy Technologies: Carbon Capture and Storage and Clean Energy Systems carried out by the United States Energy Association. It is a compendium of each quarterly report submitted over the 7-year period of the agreement accounting for all accomplishments, including major activities, significant results, major findings or conclusions, key outcomes or other achievements. Changes in approach or aims, and reasons for those changes, are included as well as any problems or delays and actions taken and planned to resolve them. It also summarizes budget statuses and any changes in key personnel throughout the life of the agreement. Originally planned for 5 years, the agreement was extended twice through back-to-back no-cost extensions, one to enable full completion of tasks critical to the program’s success and the other due to the Covid-19 Pandemic. The goals of the program were to provide increased knowledge regarding Carbon, Capture, and Storage (CCS) and Clean Energy Systems (CES) to Industry and Government decision makers, technology developers, educators, policymakers, environmental and other stakeholders, and the public by sharing research, technologies, and best practices with domestic and international partners. Increasing such knowledge was key to the other goals of the program of building of a broad consensus among domestic and international decision makers, stakeholders, and the public to take action to support and implement CCS and CES technologies and systems to ensure clean, secure, and affordable energy while enhancing environmental protection. The program accomplished these goals through a series of activities including hosting of conferences and workshops, in-person briefings, virtual webinars, reports and white papers, and keeping stakeholders informed of industry happenings through email distribution lists. It is the belief of the authors of this report, that these activities can be considered to have been successful in their goals.

01 COAL, LIGNITE, AND PEAT↗

Testing Rod Seal Leakage of a 700 HP Reciprocating Compressor

Methane emissions from reciprocating compressors in the U.S. natural gas industry account for over 72.4 Bcf per year according to a 2006 statement by the United States Environmental Protection Agency. Methane also has a global warming potential 50 times greater than carbon monoxide. Reciprocating compressors are the machinery type with the highest contribution to methane emissions at natural gas transmissions stations. The largest contributing factor comes from the sealing components in the packing components around the piston rod. SwRI, therefore, designed and setup a test loop to perform baseline packing leakage measurements on a four stage 700 HP JGT/4 compressor. The goal was to improve upon current packing leakage models and to compare new seals vs. used seals. The test loop design is described including the limits of operation. The Data Acquisition System (DAQ), including data measurements, is also fully described. The project shows the results of the commissioning process that verified the operation of all the components. Once the loop was commissioned, SwRI performed baseline packing leakage for multiple pressure ratios on each of the four stages of the compressor. The data was collected to develop an analytical model of the packing leakage. Finally, similar testing was performed after replacing the typical rod seal packing with used packing. The used packing leakage was compared to the baseline packing leakage.

03 NATURAL GAS↗

Long-term trends in connected thermostat performance

Internet-connected thermostats (CTs) control heating and cooling systems in about 30% of North American homes, and capture half of annual thermostat sales. In 2017 the U.S. Environmental Protection Agency created a program to certify the performance of ENERGY STAR® Connected Thermostats. To demonstrate compliance with energy-saving criteria, thermostat vendors must submit performance summaries for a representative sample of up to 1250 homes. Vendors must then re-submit results from a new, representative sample every six months in order to maintain their ENERGY STAR certification. This procedure has created a unique record of each thermostat’s long-term performance in response to changes in weather, customer demographics, building stock, and algorithms. Our analysis covers submissions from 13 different vendors, who submitted data up to 7 times over four years. We found that these semi-annual samples generated relatively stable trends for comfort temperatures and Heating, Ventilating and Air Conditioning (HVAC) runtimes over the study period. However, some vendors achieved consistently more energy-conserving comfort temperatures and shorter HVAC runtimes than others. The most recent submission runtimes averaged 700 hours for heating and 1,300 hours for cooling, but some vendors achieved runtimes as much as 17% below the mean. This implies lower energy consumption is due in large part to more successful algorithms and control strategies used by those vendors.

Meier, Alan↗

Waste Reduction Network Waste Glossary

This document contains relevant industry definitions to support partners in the Better Buildings, Better Plants Waste Reduction Network. Definitions were compiled using the CalRecycle Glossary, SWANA’s Waste Glossary, the U.S. Environmental Protection Agency, the State of Washington’s Department of Ecology, the Ellen MacArthur Foundation, and Metro Oregon. Some terms contain multiple complementary definitions.

Better Buildings, waste glossary, compost, waste d↗

Preprocessing of municipal solid waste towards thermal insulating material

Municipal solid waste (MSW) is one of the significant challenges in today’s world. A continuous surge in population, increasing living standards, and rapid urbanization are generating an enormous quantity of MSW. For example, the Environmental Protection Agency (EPA) reported that the total generation of MSW in the United States in 2018 was 292.4 million tons. Improper management of this MSW often leads to the release of greenhouse gases, emission of particulate matters, and formation of dioxins, which all ultimately contributes to climate change. Recycling these wastes via landfills with gas recovery and/or energy and material production via thermal and chemical conversions could be viable options to manage these challenges. Depending on the inherent chemical and structural properties of unrecycled wastes, the carbon structures can be tailored for processing and reuse in manufacturing of structural composites, building materials such as insulation, carbon dense reactant materials such as activated carbon, and so on. According to the EPA’s estimation, MSW in the United States is approximately 23% paper and paperboard, 12% plastics, 6% wood and 6% is textiles. Thus, this research focused on the feasibility of using the MSW as insulation material for the construction sector. The goal of this work was to determine the range of particle sizes, consolidation ratios, and component blends that can achieve insulation R-values within at least 70% that of traditional blown cellulose fiber. To achieve this goal, we designed the testing matrix based on five different component blends, three different particle sizes, and three different compaction level. An American Society for Testing and Materials (ASTM) method (C-739) was used to measure the R-value of the insulation material. Results showed that, adding more paper component in addition to smaller particle size and loose compaction made the insulation similar to the traditional blown cellulose fiber insulation as the R-value was within a range of 2.5-3.0 per inch.

42 ENGINEERING↗

B^dragon2002F

Report will be submitted to the Nevada Division of Environmental Protection

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Technical Assistance 101 - How Can the Joint Office Support You?

The Joint Office of Energy and Transportation (Joint Office), in partnership with the Federal Highway Administration (FHWA), National Renewable Energy Laboratory (NREL), the Federal Transit Administration (FTA), and the Environmental Protection Agency (EPA), provides free technical assistance on the planning, deployment, operation, and maintenance of a national network of electric vehicle chargers, zero-emission fueling infrastructure, and zero-emission transit and school buses. This help sheet shares how technical assistance can support stakeholders.

ADVANCED PROPULSION SYSTEMS,ENERGY PLANNING, POLIC↗

Generating Emissions Inventory for Carbon Capture and Storage Analysis for Carbon-Intensive Industrial Sectors

Decarbonizing the industrial sector is critical to achieve carbon dioxide (CO2) emissions reductions goals of the Biden Administration. Currently available decarbonization options include electrification, fuel switching to zero carbon fuels like green hydrogen (H2) and carbon capture and storage (CCS). Application of post-combustion carbon capture (PCCC) technology in the power sector, as well as research at the U.S. Department of Energy's Fossil Energy and Carbon Management (FECM) Office has shown that its application in the industrial sector could have co-benefits in the form of emissions reductions of non-CO2 regulated pollutants. For example, solvent based PCCC systems require pre-conditioning of flue gas to remove sulfur and particulate matter (PM) upstream of the CO2 absorber. However, there is a lack of understanding about the type of non-CO2 pollutants which can be captured and the amount of reduction possible. PCCC application differs across industrial sectors as it depends on the availability of decarbonization options, characteristics of industrial processes and the amount and composition of pollutant flows. Certain facilities can also have multiple effluent flows with or without a CO2 stream. As such, understanding industrial processes and their effluent flows in detail is required to quantify the co-benefits opportunities presented by PCCC. Considering this requirement, the goal of this analysis is to develop a high-resolution inventory of effluent flows from facilities of 8 industrial sectors in the U.S. These industrial sectors - ethanol, ammonia, cement, steel, natural gas processing, hydrogen, petroleum refining and wood and pulp products - have carbon-intensive effluent flows, and thus are prime candidates for PCCC applications. In this study, we map the composition of pollutant flow from flue stacks across the identified facilities. Using data available in three Environmental Protection Agency (EPA) databases - the Green House Gas Reporting Program (GHGRP), the National Emissions Inventory (NEI) and the Toxic Release Inventory (TRI), we create a combined inventory which lists the type, amount, and concentration of pollutant flows. Using total weight of the pollutant flow back calculated from observed data for CO2 concentrations in flue gas for individual sectors, we calculate the concentration of each pollutant in the flue gas stream. Thus, the resultant emissions inventory includes the following details for each facility in the sector: facility-level and if possible, process-level pollutant flows, concentrations of pollutants in the flue gas, and geographical coordinates of the facilities. A detailed statistical analysis and summary allows us to search for erroneous data and remove them from the final inventory. The generation of the inventory is achieved using a python-based framework which can recreate this inventory for other industrial sectors as well as using newer releases of emission inventories from EPA. The statistical analysis performed on the inventory is also calibrated and automated to identify outliers efficiently.

air pollutants↗

Multi-functional Sorbent Technology (MUST) for the Recovery/Removal of Critical/Heavy Metals from Fossil-Related Wastewater

A collection of remediation and recovery technologies like those predicated on photocatalytic-, electric-, chemical-, membrane-, and adsorptive-based processes currently exists in different stages of development or deployment between these methods of water management. Among these technologies, solid sorbent processes embody an optimal balance between cost-effectiveness, environmental friendliness, and technological maturity. The U.S. Department of Energy’s National Energy Technology Laboratory developed a suit of cross-linked, functionalized silica sorbents tailored to eliminate the most toxic metals regulated by the U.S. Environmental Protection Agency (EPA); critical metals identified by the U.S. Geological Survey (USGS); and harmful organics like the infamous perfluoroalkyl and polyfluoroalkyl substances (PFAS). An array of laboratory and field tests proved that the MUST sorbents removed ppb-level lead from drinking water, selenium from FGD wastewater below EPA limits, aqueous dyes and PFAS; and fractionated low ppm-level critical metals (CM) from AMD and simulated produced water. Proof-of-concept for commercial CM recovery was verified through obtaining milligram-quantities of purified Al solids from a sorbent multi-bed AMD field-site test. Commercial efficacy was further supported by achieving purified fractions of adsorbed Mn upon treating both the AMD and synthetic produced water with the laboratory multi-bed test unit.

Wilfong, Walter C.↗

Risk Considerations of Transitioning CO2-EOR Field to CO2 storage Field: Case Study

In the United States (U.S.), carbon dioxide (CO2) injection wells at EOR sites are currently regulated as Class II wells under the U.S. Environmental Protection Agency’s (EPA) Underground Injection Control (UIC) program while dedicated geological CO2 storage (GCS) wells are considered Class VI wells. A CO2-EOR facility considering a transitioning from tertiary oil recovery to injecting CO2 for the primary purpose of long-term storage is required to obtain a Class VI permit where this transition poses an increased risk to underground sources of drinking water. This study considers how transitioning operations from CO2-EOR to storage can impact reservoir plume and pressure transient in the storage envelope, and how these changes could impact area of review and potential unwanted fluid migration. We developed a case study to assess subsurface response and leakage risks associated with a representative, hypothetical operation in a carbonate reservoir. This reservoir transitions from tertiary hydrocarbon recovery to dedicated GCS. Reservoir simulations were run for a set of credible CO2-EOR scenarios to estimate distributions of fluids phases and pressures throughout the model domain after CO2 flooding as well as forecasting the behavior of the reservoir after the transition to a dedicated storage phase. The evolutions from all simulated scenarios were used as the basis for leakage risk quantification using the National Risk Assessment Partnership’s Open-Source Integrated Assessment Model (NRAP-Open-IAM) with a novel reduced-order model to estimate time-dependent leakage of CO2, brine, and hydrocarbon fluids through potentially leaky wells. Results include a description of reservoir response, an estimate of the areal extent that could potentially be impacted by leakage to underground sources of drinking water, and estimates of the magnitude of potential leakage. Considerations for dedicated storage injection well selection, injectivity, and injection scheme performance and potential leakage risk are presented, with implications for risk assessment of well transition discussed. This study presents a risk-based workflow for the Class II to Class VI well transition. Integrating credible numerical simulation of viable CO2-EOR to dedicated CO2 storage with quantitative risk assessment tools, such as the NRAP-Open-IAM, will provide a valuable means to devise operational scenarios and inform decision-making related to storage benefit, leakage risk, and liability. Presented at the SPE/AAPG/SEG Carbon Capture Utilization and Storage Conference in Houston, TX, March 11-13, 2024.

Liu, Guoxiang↗

Human Health Risk Assessment for Improper Landfill Disposal of End-of-Life CdTe Modules

The present work is a continuation of the 2020 IEA PVPS Task 12 Human Health Risk Assessment Methods for PV Part 3: Module Disposal Risks. The 2020 report performed a human health risk assessment (HHRA) for disposal of a cadmium telluride (CdTe) PV module in an unlined landfill, focusing solely on risks from cadmium. This study extends the 2020 HHRA on CdTe PV, analyzing eleven constituent elements: Cd, Se, Te, Cu, Si, Cr(III), Mo, Sn, Zn, Ni, and Al. The present HHRA was performed through two methods: utilization of the U.S. Environmental Protection Agency's (USEPA) Delisting Risk Assessment Software (DRAS V.4.0) on eight exposure pathways for cancer risk and non-cancer hazards; and comparison of exposure point concentrations to federal standards for groundwater, surface water, air, and soil exposure pathways. Cancer risks and non-cancer hazards posed by elemental leaching through all evaluated exposure pathways, using both methods, were found to be several orders of magnitude below USEPA health-protective thresholds. Cadmium exhibited both the highest risks and lowest uncertainty considering data availability on chemical content, leachate, and federal screening levels.

CdTe↗

Transportation Electrification Impact Study (TEIS)

Recent U.S. Environmental Protection Agency (EPA) notices of proposed rulemakings for GHG emissions standards for light-, medium-, and heavy-duty on-road vehicles would accelerate ongoing advancements already happening in the industry because of private investment, consumer demand, state-level policies, and federal incentives. As the EPA finalizes these regulations, questions persist regarding the cost of the requisite charging infrastructure and associated upgrades to the nation's electric grid. With support from the U.S. Department of Energy, U.S. Joint Office of Energy and Transportation, and the EPA, a multidisciplinary team conducted a Multi-State Transportation Electrification Impact Study that quantitatively assesses the incremental investment necessary to enable the levels of vehicle electrification expected to be induced by pending EPA regulations and to estimate the potential value of deferred investments in electric distribution infrastructure stemming from proactive vehicle-grid integration planning and deployment. This study finds the simulated incremental capital cost of charging infrastructure (including grid upgrades) to be at least 2.5 times smaller than the lifetime net benefits of vehicle electrification (including fuel savings but excluding the value of avoided emissions). Additionally, the incremental distribution grid upgrade cost of the EPA Action-Unmanaged scenario was found to be approximately 3% of existing utility distribution system investments (on an annual basis). Finally, the potential for managed charging to defer distribution grid upgrades was found to be significant with costs found to decrease from $2.3 billion to an incremental cost of $1 billion across five states in the Action-Managed scenario (relative to the No Action-Unmanaged scenario).

ADVANCED PROPULSION SYSTEMS,POWER TRANSMISSION AND↗