Feasibility of achieving two-electron K–O 2 batteries
A low-barrier, two-step reaction pathway for peroxide-based K–O chemistry is first realized without any catalysts under the inert argon atmosphere.
Chemistry↗
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Results for “Battery degradation”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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High-entropy solvation chemistry towards affordable and practical Ah-level zinc metal battery
Not provided.
Science & Technology - Other Topics↗
Electrochemical Deconstruction of Ortho-Phthalate Plasticizers and Recovery of Plasticizing Moieties
Electrochemical methods for the direct reduction of alkyl esters have been understudied but provide a potential advantage for addressing specific waste streams given that such strategies often require only a minimal chemical profile. One such waste stream that could benefit from electrochemical remediation is poly(vinyl chloride) (PVC) plastics. PVC recycling often faces challenges due to the complexity of such waste. Solvent-based recycling methods pose several advantages for addressing post-use PVC; however, such methods are complicated by the high amounts of toxic legacy plasticizers (ortho-phthalates) present in PVC. A potential solution to addressing such phthalates is to address them electrochemically, coupled with recovery of the resulting valuable products. Presented herein is an optimized electrochemical method for ester activation that is leveraged to separate and recover the aromatic and alkyl components of ortho-phthalate plasticizers. The resulting aliphatic alcohols may be reused to prepare other non-toxic plasticizers. This electro-degradation method is demonstrated on six phthalates that have been identified to pose health concerns in addition to plasticizers recovered from commercial samples of PVC.
di-(2-ethylhexyl) phthalate↗
Broadening solid ionic conductor selection for sustainable and earth-abundant solid-state lithium metal batteries
We propose a universal solid electrolyte design that broadens the selection of ceramic LICs for solid-state lithium metal batteries, without requirements of electronic insulation or (electro)chemical stability.
Chemistry↗
Synergistic design of g-C 3 N 4 -supported CNTs: experimental and DFT insights for enhanced electrochemical performance in flexible Li–S batteries
A schematic for the preparation of a g-C 3 N 4 -CNT/S composite cathode for lithium–sulfur batteries.
Chemistry↗
Inhibiting inter-layer gliding in transition metal layered oxides through interphase engineering for sodium-ion batteries
Not provided.
Science & Technology - Other Topics↗
Development of Electrolytes under Lean Condition in Lithium–Sulfur Batteries
Lithium–sulfur (Li–S) batteries stand out as one of the promising candidates for next-generation electrochemical energy storage technologies. A key requirement to realize high-specific-energy Li–S batteries is to implement low amount of electrolyte, often characterized by the electrolyte/sulfur (E/S) ratio. Low E/S ratio aggravates the known challenges for Li–S batteries and introduces new ones originated from the high concentration of polysulfides in limited electrolyte reservoir. Here, in this review, the connections between the fundamental properties of electrolytes and the electrochemical/chemical reactions in Li–S batteries under lean electrolyte condition are elucidated. The emphasis is on how the solvating properties of the electrolyte affect the fate of polysulfides. Built upon the mechanistic analysis, different strategies to design lean electrolytes to improve the overall process of Li–S reactions and Li anode protection are discussed.
25 ENERGY STORAGE↗
Enhancing lithium metal batteries with a nano-silicon nitride-based solid electrolyte interface layer
Artificial nano Si 3 N 4 derived solid electrolyte interphase enables dendrite-free lithium cycling, effectively suppressing dendrite growth and delivering stable, long-term Li metal anode performance.
Chemistry↗
Disentangling the role of Al, Co, and Mn dopants in LiNiO 2 cathodes via synchrotron-based probes
Multimodal synchrotron analysis uncovers how Co, Mn, and Al dopants mitigate degradation and reinforce structural integrity in LiNiO 2 cathodes.
Espinosa-Villatoro, Erick [Stanford Synchrotron Ra↗
Freeze-Thaw Engineered Dual Conductivity Polymeric Binder Stabilizes Large-Volume-Change Lithium–Ion Battery Anodes
Explore the source record for details and available documents.
36 MATERIALS SCIENCE↗
Mechanical, Electrochemical & Thermal Modeling of Electric Vehicle Batteries for Crash Simulation (CRADA CRD-19-00811 Final Report)
Under the proposed effort in partnership with Hyundai Motor Company (HMC), the National Laboratory of the Rockies (NLR) will cooperate with HMC to develop mathematical models for battery cells and modules for simulating abuse response in batteries subject to the type of mechanical crushing that can occur in a full motor vehicle crash.
33 ADVANCED PROPULSION SYSTEMS↗
Protection of battery electrodes against side reactions
A battery electrode composition is provided that comprises composite particles. Each of the composite particles in the composition (which may represent all or a portion of a larger composition) may comprise a porous electrode particle and a filler material. The porous electrode particle may comprise active material provided to store and release ions during battery operation. The filler material may occupy at least a portion of the pores of the electrode particle. The filler material may be liquid and not substantially conductive with respect to electron transport.
Yushin, Gleb↗
In Situ Embedded Catalytic Sites Accelerate Redox Kinetics for High-Performance Sodium-Sulfur Batteries
Explore the source record for details and available documents.
Energy - Storage↗
2,5‐Dimercapto‐1,3,4‐Thiadiazole (DMCT)‐Based Polymers for Rechargeable Metal–Sulfur Batteries
Organosulfur materials are a sustainable alternative to the present-day layered oxide cathodes in lithium-based batteries. One such organosulfur material that was intensely explored from the 1990s to early 2010s is 2,5-dimercapto-1,3,4-thiadiazole (DMCT). However, research interest declined as the electrode reactions with DMCT were assumed to be too sluggish to be practical. Armed with the advances in metal–sulfur batteries, we revisit DMCT-based materials in the form of poly[tetrathio-2,5-(1,3,4-thiadiazole)], referred to as pDMCT-S. With an appropriate choice of electrode design and electrolyte, pDMCT-S cathode paired with a Li-metal anode shows a capacity of 715 mA h g −1 and a Coulombic efficiency of 97.7% at a C/10 rate, thus quelling the concerns of sluggish reactions. Surprisingly, pDMCT-S shows significantly improved long-term cyclability compared to a sulfur cathode. Investigations into the origin of the stability reveals that the discharge product Li-DMCT in its mesomeric form can strongly bind to polysulfides, preventing their dissolution into the electrolyte and shuttling. This unique mechanism solves a critical problem faced by sulfur cathodes. Encouragingly, this mechanism results in a stable performance of pDMCT-S with Na-metal cells as well. In conclusion, this study opens the potential for exploring other organic materials that have inherent polysulfide sequestering capabilities, enabling long-life metal–sulfur batteries.
2,5-dimercapto-1,3,4-thiadiazole↗
Vehicle Technologies Program: Energy Storage R&D (2008 Annual Progress Report)
One of the primary objectives of the Energy Storage effort is the development of durable and affordable advanced batteries (and ultracapacitors) for use in a full range of vehicle applications, from start/stop to full-power HEVs, EVs, and PHEVs. The battery technology development activity spans three areas: system development of full battery systems; benchmark testing of emerging technologies in order to remain abreast of the latest industry developments; and Small Business Innovative Research (SBIR) to fund early-stage R&D for small businesses/entrepreneurs.
25 ENERGY STORAGE↗
Methods and recommendations for large-scale deflagration testing of battery energy storage system enclosures
UL Solutions produced this report as a summary of a test series executed at Sandia National Laboratories that they funded. This report was approved for release by UL Solutions in October 2025 and released in 2026 on their website at https://www.ul.com/insights/methods-and-recommendations-large-scale-deflagration-testing-battery-energy-storage-system.
Gaudet, Benjamin [UL Solutions] (ORCID:00090006419↗