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At least 127 records · Page 7

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NASA NTRS1994

NiAl-base composite containing high volume fraction of AlN for advanced engines

A particulate reinforced NiAl-AlN composite alloy has a NiAl matrix and greater than about 13 volume percent fine particles of AlN within the matrix. The particles preferably have a diameter from about 15 nanometers to about 50 nanometers. The particulate reinforced NiAl-AlN composite alloy may be prepared by cryomilling prealloyed NiAl in liquid nitrogen using grinding media having a diameter of from about 2 to 6 mm at an impeller speed of from about 450 RPM to about 800 RPM. The cryomilling may be done for a duration of from about 4 hours to about 20 hours to obtain a cryomilled powder. The cryomilled powder may be consolidated to form the particulate reinforced NiAl-AlN composite alloy. The particulate reinforced alloy can further include a toughening alloy. The toughening alloy may include NiCrAlY, FeCrAlY, and FeAl.

Hebsur, Mohan↗

NASA NTRS1995

Spectroscopic ellipsometry as a sensitive monitor of materials contamination

Spectroscopic ellipsometry is demonstrated to be extremely sensitive to contamination layers in the thickness range from 0.1 nm to 10 microns. In the present experiments we deposit either a thin lubricating oil (WD-40) or mineral oil continuously onto Ir, Cu, Al, Au, and V substrates from a bubbler, and monitor its thickness growth from sub-nanometer to tens of nanometers as a function of time. Re-evaporation of contaminant oils is also monitored in real-time by ellipsometry.

Hale, Jeffrey S.↗

NASA NTRS1995

Observation of Shoemaker-Levy Impacts by the Galileo Photopolarimeter Radiometer

The Galileo Photopolarimeter Radiometer experiment made direct photometric observations at 678 and 945 nanometers of several comet Shoemaker-Levy 9 fragments impacting with Jupiter. Initial flashes occurred at (fragment G) 18 July 1994 07:33:32, (H) 18 July 19:31:58, (L) 19 July 22:16:48, and (Q1) 20 July 20:13:52, equivalent Universal Time Coordinated (UTC) observed at Earth, with relative peak 945-nanometer brightnesses of 0.87, 0.67, 1.00, and 0.42, respectively. The light curves show a 2-second to maximum, a 10-second plateau, and an accelerating falloff. The Ql event, observed at both wavelengths, yielded a color temperature of more than 1 0,000 kelvin at its peak.

Martin, Terry Z.↗

NASA NTRS1999

Computational Study of Field Initiated Surface Reactions for Synthesis of Diamond and Silicon

This project involves using quantum chemistry to simulate surface chemical reactions in the presence of an electric field for nanofabrication of diamond and silicon. A field delivered by a scanning tunneling microscope (STM) to a nanometer scale region of a surface affects chemical reaction potential energy surfaces (PES) to direct atomic scale surface modification to fabricate sub-nanometer structures. Our original hypothesis is that the applied voltage polarizes the charge distribution of the valence electrons and that these distorted molecular orbitals can be manipulated with the STM so as to change the relative stabilities of the electronic configurations over the reaction coordinates and thus the topology of the PES and reaction kinetics. Our objective is to investigate the effect of applied bias on surface reactions and the extent to which STM delivered fields can be used to direct surface chemical reactions on an atomic scale on diamond and silicon. To analyze the fundamentals of field induced chemistry and to investigate the application of this technique for the fabrication of nanostructures, we have employed methods capable of accurately describing molecular electronic structure. The methods we employ are density functional theory (DFT) quantum chemical (QC) methods. To determine the effect of applied bias on surface reactions we have calculated the QC PESs in various applied external fields for various reaction steps for depositing or etching diamond and silicon. We have chosen reactions which are thought to play a role in etching and the chemical vapor deposition growth of Si and diamond. The PESs of the elementary reaction steps involved are then calculated under the applied fields, which we vary in magnitude and configuration. We pay special attention to the change in the reaction barriers, and transition state locations, and search for low energy reaction channels which were inaccessible without the applied bias.

Musgrave, Charles Bruce↗

NASA NTRS1998

SSBUV and NOAA-11 SBUV/2 Solar Variability Measurements

The Shuttle Solar Backscatter Ultraviolet (SSBUV) and NOAA-II Solar Backscatter Ultraviolet/2 (SBUV/2) instruments measured solar spectral Ultraviolet (UV) irradiance during the maximum and declining phase of solar cycle 22. The SSB UV data accurately represent the absolute solar UV irradiance between 200-405 nanometers, and also show the long-term variations during eight flights between October 1989 and January, 1996. These data have been used to correct long-term sensitivity changes in the NOAA-II SBUV/2 data, which provide a near-daily record of solar UV variations over the 170 to 400 nanometer region between December 1988 and October 1994. The NOAA-II data demonstrate the evolution of short-term solar UV activity during solar cycle 22.

Deland, Matthew T.↗

NASA NTRS2001

Protective Fullerene (C60) Packaging System for Microelectromechanical Systems Applications

The invention involves a method for locating the probe of a scanning tunneling micrograph a predetermined distance from its conducting surface, and specifically the deposition of a monolayer of fullerene C 60 onto the conducting plate. The Fullerene C 60 molecule is approximately spherical and a monolayer of fullerene has a thickness of one nanometer. By providing a monolayer of fullerene on the conducting surface and locating the probe on the surface of the monolayer, a distance of one nanometer can be established between the probe tip and the conducting surface.

John D Olivas↗

NASA NTRS2001

Photoemission Experiments for Charge Characteristics of Individual Dust Grains

Photoemission experiments with UV radiation have been performed to investigate the microphysics and charge characteristics of individual isolated dust grains of various compositions and sizes by using the electrodynamic balance facility at NASA Marshall Space Flight Center. Dust particles of 1 - 100 micrometer diameter are levitated in a vacuum chamber at pressures approx. 10(exp -5) torr and exposed to a collimated beam of UV radiation in the 120-300 nanometers spectral range from a deuterium lamp source with a MgF2 window. A monochromator is used to select the UV radiation wavelength with a spectral resolution of 8 nanometers. The electrodynamic facility permits measurements of the charge and diameters of particles of known composition, and monitoring of photoemission rates with the incident UV radiation. Experiments have been conducted on Al2O3 and silicate particles, and in particular on JSC-1 Mars regolith simulants, to determine the photoelectron yields and surface equilibrium potentials of dust particles when exposed to UV radiation in the 120-250 micrometers spectral range. A brief discussion of the experimental procedure, the results of photoemission experiments, and comparisons with theoretical models will be presented.

Abbas, M. M.↗

NASA NTRS2002

Preparation and Characterization of Polyimide Nanocomposites

Many properties of polymeric materials can be enhanced by dispersing small quantities of clay nanocomposites throughout the polymer. Among the enhancements are increases in modulus and resistance to erosion by atomic oxygen and reductions in thermal expansivity, gas permeability, and flammability. To achieve the full extent of enhancement with these polymer-clay nanocomposites, the clay nanoparticles, which have thicknesses of only one-to-several nanometers and lengths and widths of hundreds of nanometers to micrometers, must be exfoliated one from another and then individually dispersed throughout the polymer. This dispersion is achieved only after alkali metal cations (usually Na(+)) that reside on the surfaces of the nanoparticles have been replaced by organocations (typically a quaternary amine cation). This renders the surface of the nanoparticle a more hospitable interface for the organic polymer matrix. Following the cation exchange, the organic clay is either mixed directly into the polymer or is dispersed in monomer which is later polymerized around the nanoparticle.

Orwoll, Robert A.↗

NASA NTRS2003

All-Optical Micro Motors Based on Moving Gratings in Photosensitive Media

This research effort was a feasibility study of the concept of an all-optical micro motor with a rotor driven by a traveling wave. The wave was a result of a photo induced surface deformation of a photosensitive material produced by a traveling holographic grating. Two phases modulated coherent optical beams were used to generate the grating in two types of photosensitive materials. The materials that were studied were photorefractive crystals and thin polymer films. Theoretical studies were performed on lithium niobate giving predictions of deformations of the order of nanometers. The experimental deformation size was also on the order of nanometers. The deformations were deep enough to provide conditions for the implementation of the all-optical motor using lithium niobate. We also were able to align micron-size dielectric particles along the holographic gratings by means of the periodic electric forces generated by the grating. These forces can also move the particles along the surface if the grating is moving. We then turned our attention on thin films and obtained a deformation visible on the order of 100 microns. An experimental breadboard demonstration of a prototype was done in the summer of 2001 at Glenn Research Center (GRC). The demonstration included the movement of clocks mechanical workings by an optically driven motor based on a polymer film. The application of this technology can be adapted to government as well as industrial uses. One such project is to make a chemical sensor for the detection of hazardous chemicals. The thin polymer film is highly suited for this purpose since a marker dye could be easily placed on the film in order to detect chemical compounds. This system could be a self-regulating chemical monitoring system used on launches of the space shuttle or locations where hazardous chemicals are present. The project provided support for two black minority graduate students targeting MS and PhD degrees in Applied Optics.

Adamovsky, Gregory↗

NASA NTRS2003

Nanophase, Low-Ni Metal Grains in Fine-grained Rims in the Murchison CM2 Chondrite: Insights into the Survival of Metal Grains During Aqueous Alteration

Aqueous alteration has played a significant role in the geological evolution of almost all the chondrite groups and attests to the importance of water during the earliest history of the solar system. Among the chondrites that show evidence of aqueous alteration the CM chondrites, in particular, have received considerable attention, because of their primitive composition and the fact that they preserve a record of incomplete hydration. Petrologic studies of this group of meteorites have helped provide important insights into aqueous alteration processes and the nature of the alteration products. However, due to the complex history of these chondrites, important details of the alteration remain enigmatic. Among the major problems to be resolved are the location and timing of aqueous alteration as well as the relationship between alteration and brecciation. Although many authors favor aqueous alteration within a parent body environment, there is also evidence that some of the components of CM chondrites may have experienced aqueous alteration prior to accretion. One of the key lines of evidence for alteration in a pre-accretionary environment is the presence of unaltered metal grains associated with hydrated phases. Low-Ni metal (kamacite) is typically one of the first phases in CM chondrites that alters in the presence of water. However, in some CM chondrites, such as Yamato 791198, micron-sized metal grains are present within the hydrated fine-grained rim material around chondrules. In addition, nanometer-sized grains that have been interpreted as being unaltered metal particles have been reported in the relatively heavily altered CM chondrite, ALH 81002. In most cases, these occurrences have been interpreted as being the result of mixing of anhydrous and hydrous materials prior to accretion. According to this hypothesis, the metal grains remain unaltered because little or no post-accretionary alteration took place. Whilst such a scenario is plausible, no alternative explanations such as the presence of submicron protective layers or a minor element chemistry that might inhibit oxidation have been investigated in detail. During a study of the distribution of carbonaceous material in fine-grained rims on chondrules in Murchison, previously unidentified, nanometer-sized metal grains were observed. These grains were characterized in detail using high resolution TEM and energy filtered TEM (EFTEM) and provide important insights into how metal grains in CM chondrites may survive aqueous alteration.

Brearley, Adrian J.↗

NASA NTRS2004

Optics-Only Calibration of a Neural-Net Based Optical NDE Method for Structural Health Monitoring

A calibration process is presented that uses optical measurements alone to calibrate a neural-net based NDE method. The method itself detects small changes in the vibration mode shapes of structures. The optics-only calibration process confirms previous work that the sensitivity to vibration-amplitude changes can be as small as 10 nanometers. A more practical value in an NDE service laboratory is shown to be 50 nanometers. Both model-generated and experimental calibrations are demonstrated using two implementations of the calibration technique. The implementations are based on previously published demonstrations of the NDE method and an alternative calibration procedure that depends on comparing neural-net and point sensor measurements. The optics-only calibration method, unlike the alternative method, does not require modifications of the structure being tested or the creation of calibration objects. The calibration process can be used to test improvements in the NDE process and to develop a vibration-mode-independence of damagedetection sensitivity. The calibration effort was intended to support NASA s objective to promote safety in the operations of ground test facilities or aviation safety, in general, by allowing the detection of the gradual onset of structural changes and damage.

Decker, Arthur J.↗

NASA NTRS2004

Alignment and Performance of the Infrared Multi-Object Spectrometer

The Infrared Multi-Object Spectrometer (IRMOS) is a principle investigator class instrument for the Kitt Peak National Observatory 4 and 2.1 meter telescopes. IRMOS is a near-IR (0.8 - 2.5 micron) spectrometer with low-to mid-resolving power (R = 300 - 3000). IRMOS produces simultaneous spectra of approximately 100 objects in its 2.8 x 2.0 arc-min field of view (4 m telescope) using a commercial Micro Electro-Mechanical Systems (MEMS) micro-mirror array (MMA) from Texas Instruments. The IRMOS optical design consists of two imaging subsystems. The focal reducer images the focal plane of the telescope onto the MMA field stop, and the spectrograph images the MMA onto the detector. We describe ambient breadboard subsystem alignment and imaging performance of each stage independently, and ambient imaging performance of the fully assembled instrument. Interferometric measurements of subsystem wavefront error serve as a qualitative alignment guide, and are accomplished using a commercial, modified Twyman-Green laser unequal path interferometer. Image testing provides verification of the optomechanical alignment method and a measurement of near-angle scattered light due to mirror small-scale surface error. Image testing is performed at multiple field points. A mercury-argon pencil lamp provides a spectral line at 546.1 nanometers, a blackbody source provides a line at 1550 nanometers, and a CCD camera and IR camera are used as detectors. We use commercial optical modeling software to predict the point-spread function and its effect on instrument slit transmission and resolution. Our breadboard and instrument level test results validate this prediction. We conclude with an instrument performance prediction for cryogenic operation and first light in late 2003.

Connelly, Joseph A.↗

NASA NTRS1993

Spirosymplokos deltaeiberi nov. gen., nov. sp.: variable-diameter composite spirochete from microbial mats

Large (up to 100 micrometers long), loosely coiled, free-living spirochetes with variable diameters (from 0.4 to 3 micrometers in the same cell) were seen at least 40 times between August 1990 and January 1993. These spirochetes were observed in mud water and enrichment media from highly specific habitats in intertidal evaporite flats at three disjunct localities, one in Spain and two in Mexico. All three are sites of commercial saltworks. Associated with Microcoleus chthonoplastes the large spirochetes from Spain display phototaxis and a composite organization. Shorter and smaller-diameter spirochetes are seen inside both healthy and spent periplasm of larger ones. Small spirochetes attached to large ones have been observed live. From two to twelve spirochete protoplasmic cylinders were seen inside a single common outer membrane. A distinctive granulated cytoplasm in which the granules are of similar diameter (20-32 nanometers) to that of the flagella (26 nanometers) was present. Granule diameters were measured in thin section and in negatively-stained whole-mount preparations. Based on their ultrastructure, large size, variable diameter, number of flagella (3 to 6), and phototactic behavior these unique spirochetes are formally named Spirosymplokos deltaeiberi. Under anoxic (or low oxygen) conditions they formed blooms in mixed culture in media selective for spirochetes. Cellobiose was the major carbon source in 80% seawater, the antibiotic rifampicin was added, mat from the original field site was present and tubes were incubated in the light at from 18-31 degrees C. Within 1-2 weeks populations of the large spirochete developed at 25 degrees C but they could not be transferred to fresh medium.

Non-NASA Center↗

NASA NTRS1992

Time threshold for second positive phototropism is decreased by a preirradiation with red light

A second positive phototropic response is exhibited by a plant after the time of irradiation has exceeded a time threshold. The time threshold of dark-grown seedlings is about 15 minutes for Arabidopsis thaliana. This threshold is decreased to about 4 minutes by a 669-nanometer preirradiation. Tobacco (Nicotiana tabacum) seedlings show a similar response. The time threshold of dark-grown seedlings is about 60 minutes for tobacco, and is decreased to about 15 minutes after a preirradiation with either 450- or 669- nanometer light. The existence of a time threshold for second positive phototropism and the dependence of this threshold on the irradiation history of the seedling contribute to the complexity of the fluence response relationship for phototropism.

NASA Discipline Number 40-50↗

NASA NTRS1988

Cytoplasmic membrane changes during adaptation of the fresh water cyanobacterium Synechococcus 6311 to salinity

In this investigation, changes were characterized in cell structure and cytoplasmic membrane organization that occur when the freshwater cyanobacterium Synechococcus 6311 is transferred from 'low salt' (0.03 molar NaCl) to 'high salt' (0.5 molar NaCl) media (i.e. sea water concentration). Cells were examined at several time points after the imposition of the salt stress and compared to control cells, in thin sections and freeze fracture electron microscopy, and by flow cytometry. One minute after exposure to high salt, i.e. 'salt shock', virtually all intracellular granules disappeared, the density of the cytoplasm decreased, and the appearance of DNA material was changed. Glycogen and other granules, however, reappeared by 4 hours after salt exposure. The organization of the cytoplasmic membrane undergoes major reorganization following salt shock. Freeze-fracture electron microscopy showed that small intramembrane particles (diameter 7.5 and 8.5 nanometers) are reduced in number by two- to fivefold, whereas large particles, (diameters 14.5 and 17.5 nanometers) increase two- to fourfold in frequency, compared to control cells grown in low salt medium. The changes in particle size distribution suggest synthesis of new membrane proteins, in agreement with the known increases in respiration, cytochrome oxidase, and sodium proton exchange activity of the cytoplasmic membrane.

NASA Discipline Number 61-10↗

NASA NTRS2004

Evidence for Natural Variability in Marine Stratocumulus Cloud Properties Due to Cloud-Aerosol

In this study, aircraft observations from the Interdisciplinary Remotely-Piloted Aircraft Studies (CIRPAS) Twin Otter are used to characterize the variability in drizzle, cloud, and aerosol properties associated with cloud rifts and the surrounding solid clouds observed off the coast of California. A flight made on 16 July 1999 provided measurements directly across an interface between solid and rift cloud conditions. Aircraft instrumentation allowed for measurements of aerosol, cloud droplet, and drizzle spectra. CCN concentrations were measured in addition to standard thermodynamic variables and the winds. A Forward Scatter Spectrometer Probe (FSSP) measured size distribution of cloud-sized droplets. A Cloud Imaging Probe (CIP) was used to measure distributions of drizzle-sized droplets. Aerosol distributions were obtained from a Cloud Aerosol Scatterprobe (CAS). The CAS probe measured aerosols, cloud droplets and drizzle-sized drops; for this study. The CAS probe was used to measure aerosols in the size range of 0.5 micron - 1 micron. Smaller aerosols were characterized using an Ultrafine Condensation Particle Counter (CPC) sensor. The CPC was used to measure particles with diameters greater than 0.003 micron. By subtracting different count concentrations measured with the CPC, this probe was capable of identifying ultrafine particles those falling in the size range of 3 nanometers - 7 nanometers that are believed to be associated with new particle production.

Albrecht, Bruce↗

NASA NTRS2004

Protective Fullerene (C60) Packaging System for Microelectromechanical Systems Applications

The invention involves tunneling tips to their conducting surface, and specifically the deposition of a monolayer of fullerene C 60 onto the conducting plate surface to protect the tunneling tip from contact. The Fullerene C 60 molecule is approximately spherical, and a monolayer of fullerene has a thickness of one nanometer, such that a monolayer thereby establishing the theoretical distance desired between the MEMS tunneling tip and the conducting plate. Exploiting the electrical conductivity of C 60 the tip can be accurately positioned by simply monitoring conductivity between the fullerene and the tunneling tip. By monitoring the Conductivity between the tip and the fullerene layer as the tip is brought in proximity, the surfaces can be brought together without risk of contacting the underlying conducting surface. Once the tunneling tip is positioned at the one nanometer spacing, with only the monolayer of fullerene between the tunneling tip and the conducting plate, the monolayer of C 60 , can be broken down thermally and removed chemically leaving only the tunneling tip and the conducting plate at the ideal tunneling spacing. Alternatively, the properties of fullerene allow the tunneling process to occur directly across the fullerene monolayer.

John D Olivas↗

NASA NTRS2004

Wavefront Sensing via High Speed DSP

Future light-weighted and segmented primary mirror systems require active optical control to maintain mirror positioning and figure to within nanometer tolerances. Current image-based wavefront sensing approaches rely on post-processing techniques to return an estimate of the aberrated optical wavefront with accuracies to the nanometer level. But the lag times between wavefront sensing, and then control, contributes to a significant latency in the wavefront sensing implementation. In this analysis we demonstrate accelerated image-based wavefront sensing performance using multiple digital signal processors (DSP's). The computational architecture is discussed as well as the heritage leading to the approach.

Smith, J. Scott↗