SEARCH · Search NASA

Results for “surface physics”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

SourceResearch connectionFrom yearThrough year

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,549 records · Page 86

All sources NASA NTRS DOE OSTI

DOE OSTI2022

Counterions under a Surface-Adsorbed Cationic Surfactant Monolayer: Structure and Thermodynamics

The surface adsorption of ionic surfactants is fundamental for many widespread phenomena in life sciences and for a wide range of technological applications. However, direct atomic-resolution structural experimental studies of noncrystalline surface-adsorbed films are scarce. Thus, even the most central physical aspects of these films, such as their charge density, remain uncertain. Consequently, theoretical models based on contradicting assumptions as for the surface films' ionization are widely used for the description and prediction of surface thermodynamics. We employ X-ray reflectivity to obtain the angstrom Ångström-scale surface-normal structure of surface-adsorbed films of the cationic surfactant cetyltrimethylammonium bromide (CTAB) in aqueous solutions at several different temperatures and concentrations. In conjunction with published neutron reflectivity data, we determine the surface-normal charge distribution due to the dissociated surfactants' headgroups. The distribution appears to be inconsistent with the Gouy-Chapman model yet consistent with a compact Stern layer model of condensed counterions. Here, the experimental surfactant adsorption thermodynamics conforms well to classical, Langmuir and Kralchevsky, adsorption models. Furthermore, the Kralchevsky model correctly reproduces the observed condensation of counterions, allowing the values of the adsorption parameters to be resolved, based on the combination of the present data and the published surface tension measurements.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2021

Surface Fermi contours and phonon anomalies at the surface of the random alloy

Abstract The impact of compositional disorder on physical properties is a subject of prime focus in many materials systems. In this paper, we report photoemission measurements of Mo 1− x Re x (110)-(1 × 1)H alloy surfaces to probe the relationship between the surface Fermi contours and giant Kohn anomalies observed in the surface phonon dispersion relations. Our measured nesting vectors precisely predict the composition dependence of the anomalous wave vectors.

Okada, Michio (ORCID:0000000276894288)↗

DOE OSTI2025

Interplay of surface energy and rheology in biopolymer soil enhancement

Biopolymers such as xanthan gum (XG) and locust bean gum (LBG) hold great potential as eco-friendly alternative soil binders. In this work, we investigated the impact of XG/LBG mixtures on the unconfined compressive strength (UCS) of sand. The high strength of dry biopolymer/sand arises from the cohesion between solid polymer films and sand particles which supported by work of adhesion calculation and soil mechanics measurement. LBG exhibits much lower sand reinforcement efficacy because polymers unevenly distributed within sand matrix. The formation of a core-shell structure in LBG/sand is an interplay of surface free energy and viscoelastic properties of polymer solutions. This structure is altered when LBG mixed with XG at varying ratios as those physical properties changed due to the complexity of polymer chains association. By probing these factors, we aim to elucidate the role of surface energies and polymer physics in governing the strength of the sand/polymer network, thereby contributing to a more comprehensive understanding polymer-sand interface. The low strength of gels (G’ ∼10Pa) cannot solely account for the increased UCS of wet sand over 10 kPa. Instead, the high strength of biopolymer/sand is more likely derived from the granular particles with biopolymers as solid glue.

36 MATERIALS SCIENCE↗

NASA NTRS1971

In situ analysis of planetary surfaces for organic materials.

Discussion of the possibility of investigating the physical, chemical, and biological state of other planets in the hope of encountering one or more that is presently in a state prior to or just after the evolution of living systems. It may then be possible to observe the chemistry at and near the surface, evaluate the sources of energy available, and search for the presence or absence of living systems, and their degree of similarity to terrestrial ones. The mass spectrometry technique is considered to be the most appropriate. A system consisting of a series of sample ovens which can be consecutively attached to the gas stream of a small gas chromatograph which is in turn connected to a mass spectrometer via a carrier gas separator has been developed for the exploration of the surface of Mars.

Biemann, K.↗

NASA NTRS2017

Global Statistics of Microphysical Properties of Cloud-Top Ice Crystals

Ice crystals in clouds are highly complex. Their sizes, macroscale shape (i.e., habit), mesoscale shape (i.e., aspect ratio of components) and microscale shape (i.e., surface roughness) determine optical properties and affect physical properties such as fall speeds, growth rates and aggregation efficiency. Our current understanding on the formation and evolution of ice crystals under various conditions can be considered poor. Commonly, ice crystal size and shape are related to ambient temperature and humidity, but global observational statistics on the variation of ice crystal size and particularly shape have not been available. Here we show results of a project aiming to infer ice crystal size, shape and scattering properties from a combination of MODIS measurements and POLDER-PARASOL multi-angle polarimetry. The shape retrieval procedure infers the mean aspect ratios of components of ice crystals and the mean microscale surface roughness levels, which are quantifiable parameters that mostly affect the scattering properties, in contrast to a habit. We present global statistics on the variation of ice effective radius, component aspect ratio, microscale surface roughness and scattering asymmetry parameter as a function of cloud top temperature, latitude, location, cloud type, season, etc. Generally, with increasing height, sizes decrease, roughness increases, asymmetry parameters decrease and aspect ratios increase towards unity. Some systematic differences are observed for clouds warmer and colder than the homogeneous freezing level. Uncertainties in the retrievals will be discussed. These statistics can be used as observational targets for modeling efforts and to better constrain other satellite remote sensing applications and their uncertainties.

Van Diedenhoven, Bastiaan↗

DOE OSTI2026

A Parallel Kinetic Model for Surface and Bulk Charge Storage in ε -MnO 2 Pseudocapacitors

Pseudocapacitive materials such as manganese dioxide (MnO 2 ) are attractive for energy storage applications due to their ability to combine the fast kinetics of capacitors with the higher energy density of battery-type systems. However, the electrochemical behavior of MnO 2 remains difficult to interpret mechanistically, in part because existing models often fail to distinguish between surface-based redox processes and bulk intercalation mechanisms. In this work, we develop a physics-based model that represents MnO 2 pseudocapacitance as a linear combination of two independent, parallel electrochemical processes: (i) the surface or near-surface redox storage and (ii) lithium ion intercalation into the bulk material. These two processes are treated with distinct kinetic and thermodynamic parameters and are assumed to proceed independently. The total measured current is assumed to be the sum of these two partial currents. We validate the model using rate-dependent cyclic voltammetry experiments, demonstrating that it captures key trends and provides physically interpretable parameters reflecting the relative contributions of surface and bulk processes. By enabling a clear separation between these mechanisms, the model offers a useful framework for analyzing pseudocapacitive materials and can guide the rational design of high-performance energy storage electrodes.

Energy - Storage↗

DOE OSTI2018

Extending the Service Life of High–Ni Layered Oxides by Tuning the Electrode–Electrolyte Interphase

As a high-energy-density cathode for Li-ion batteries, high-Ni layered oxides, especially with ultrahigh Ni-content, suffer from short lifespans, due in part to their unstable electrode–electrolyte interphase (EEI). Herein, the cycle life of LiNi 0.94 Co 0.06 O 2 is greatly extended by manipulating the EEI with a lithium bis(oxalate) (LiBOB) additive even when operated at a moderately high voltage (4.4 V vs Li/Li + ). Impressively, the capacity retention can be increased from 61 to 80% after 500 cycles in a full cell paired with a graphite anode. Additionally, the presence of LiBOB enables a robust boron- and oxygen-enriched EEI that effectively inhibits continual electrolyte decomposition and offers a stable cathode surface. Moreover, the layered architecture of the cathode–electrolyte interphase (CEI) and the anode–electrolyte interphase (AEI) at the nanometer scale is revealed by time-of-flight secondary ion mass spectrometry. It is demonstrated that the cathode surface chemistry can significantly influence the AEI both chemically and physically, and AEI is modified from a thick “three-layer” to a thin “two-layer” architecture by tuning the cathode surface chemistry with LiBOB. Finally, this work presents a correlation between the EEI characteristics and battery performance and highlights the significance of manipulating surface chemistry in developing stable high-energy-density Li-ion batteries.

25 ENERGY STORAGE↗

DOE OSTI2025

Spatially Patterned Architectures to Modulate CO 2 Reduction Cascade Catalysis Kinetics

Electrochemical CO 2 reduction using renewable sources of electrical energy holds promise for converting CO 2 into fuels and chemicals. The complex interactions among chemical/electrochemical reactions and mass transport make it difficult to analyze the effect of an individual process on electrode performance based only on experimental methods. Here, we developed a generalized steady-state simulation to describe an electrode surface in which sequential cascade catalysts are patterned in a periodic trench design. If appropriately constructed, this trench geometry is hypothesized to be able to yield a higher net current density for a CO 2 reduction (CO 2 R) cascade reaction. We have used realistic experimental reaction kinetics to investigate the role of trench geometry in mass transport, local microenvironments, and selectivity for a model CO 2 R cascade reaction. The model considers local concentration gradients of bicarbonate species at quasi-equilibrium and catalytic surface reactions based on concentration-dependent Butler–Volmer kinetics. Our results suggest that varying the spatial distribution of active sites plays a significant role in facilitating effective mass transport between active sites, modulating selectivity for the cascade reaction, and enhancing the yield of desirable cascade products. Moreover, we observe that this trench geometry significantly alters the cascade reaction rate by affecting the local pH, which can cause inadvertent depletion of available aqueous CO 2 to limit the CO 2 R cascade kinetics and modest suppression of the hydrogen evolution reaction (HER). The results highlight the trade-offs between mass transport, pH, and reaction kinetics that become apparent only when considering the coupled physics of all processes at the electrode surface. Here, this model can thus serve as a primary tool to build more selective and efficient patterned architectures for the CO 2 R cascade catalysis.

CO2 reduction↗

NASA NTRS2012

Chondritic Models of 4 Vesta: Comparison of Predicted Internal Structure and Surface Composition/Mineralogy with Data from the Dawn Mission

Understanding the physical and chemical processes which led to the formation of the terrestrial planets remains one of the principal challenges of the Earth and planetary science communities. However, direct traces of the earliest stages of planet building have generally been wiped out on larger bodies such as the Earth or Mars, obscuring our view of how that process occurred. On the other hand, the planet building process would appear to have been arrested prematurely in the region between Mars and Jupiter, now populated by several hundred thousand compositionally diverse objects that escaped accretion into larger planets. Of these, the asteroid 4 Vesta is of particular interest as it is large (520 km diameter), and known to have a basaltic surface dominated by pyroxenes [1, 2]. Furthermore, visible-IR spectra of Vesta obtained by ground and space-based telescopes are remarkably similar to laboratory spectra measured on meteorites of the Howardite-Eucrite-Diogenite clan (HED), leading to the paradigm that the HEDs came from Vesta [2]. Geochemical and petrological studies of the HEDs confirm the differentiated nature of the near-surface region of their parent body, and imply that crust extraction occurred well within the first 10Ma of solar system history [3]. Vesta is therefore a prime target for studies that aim to constrain the earliest stages of planet building, and for that reason it is currently the subject of the Dawn mission [4].

Toplis, M. J.↗

NASA NTRS2026

Performance Optimization for Lunar Extravehicular Activity Readiness (POLAR) Study: Methods Paper

To better understand which aspects of physical fitness may be most related to performance during Lunar surface operations and thereby help to inform the current NASA fitness standards, much can be learned from fields encompassing the “tactical athlete.” Other physically demanding professions such as law enforcement, military, or rescue professionals often require candidates to meet occupationally-relevant fitness standards. The determination of such standards is a multistep process, including both objective and subjective measures, to determine tasks essential to occupational performance and identify the minimal fitness profile needed to meet physical demands of the job. Notably, fitness is only one component which may contribute to the demands of astronaut selection, flight assignment, and occupational performance. Utilizing a framework to systematically determine which domains of fitness most contribute to relevant job tasks can aid in the refinement of current NASA-STD-3001 fitness standards. Therefore, NASA’s Exercise Physiology & Countermeasures Laboratory conducted the Performance Optimization for Lunar Extravehicular Activity Readiness (POLAR) study to identify and examine a comprehensive list of fitness tests (including NASA-STD-3001 assessments: 1-Repetition Maximum [1-RM] bench press and deadlift) and determine preliminary relationships between identified fitness parameters and novel Artemis-relevant tasks to help inform future investigations for the continued development of aerobic and muscular fitness standards for surface EVAs. This was accomplished through 1) a review of the literature relating fitness assessments to simulated or real EVA performance to identify fitness tests that are most correlated with simulated EVA task performance; 2) a task analysis following a modified framework for physical employment standards development to down select mission critical tasks; and 3) development and pilot testing of a novel, portable Artemis-relevant EVA task circuit to relate to a battery of fitness assessments. The current report describes the methodology used to complete the task analysis, EVA task circuit development, and the pilot study.

Nicole C Strock↗

NASA NTRS1983

Analysis of the reflective multibandgap solar cell concept

A new and unique approach to improving photovoltaic conversion efficiency, the reflective multiband gap solar cell concept, was examined. This concept uses back surface reflectors and light trapping with several physically separated cells of different bandgaps to make more effective use of energy from different portions of the solar spectrum. Preliminary tests performed under General Dynamics Independent Research and Development (IRAD) funding have demonstrated the capability for achieving in excess of 20% conversion efficiency with aluminum gallium arsenide and silicon. This study analyzed the ultimate potential for high conversion efficiency with 2, 3, 4, and 5 different bandgap materials, determined the appropriate bandgaps needed to achieve this optimized efficiency, and identified potential problems or constraints. The analysis indicated that an improvement in efficiency of better than 40% could be attained in this multibandgap approach, compared to a single bandgap converter under the same assumptions. Increased absorption loss on the back surface reflector was found to incur a minimal penalty on efficiency for two and three bandgap systems. Current models for bulk absorption losses in 3-5 materials were found to be inadequate for explaining laboratory observed transmission losses. Recommendations included the continued development of high bandgap back surface reflector cells and basic research on semiconductor absorption mechanisms.

Stern, T. G.↗

NASA NTRS2004

Lunar and Planetary Science XXXV: Asteroids, Meteors, Comets

Reports included:Long Term Stability of Mars Trojans; Horseshoe Asteroids and Quasi-satellites in Earth-like Orbits; Effect of Roughness on Visible Reflectance Spectra of Planetary Surface; SUBARU Spectroscopy of Asteroid (832) Karin; Determining Time Scale of Space Weathering; Change of Asteroid Reflectance Spectra by Space Weathering: Pulse Laser Irradiation on Meteorite Samples; Reflectance Spectra of CM2 Chondrite Mighei Irradiated with Pulsed Laser and Implications for Low-Albedo Asteroids and Martian Moons; Meteorite Porosities and Densities: A Review of Trends in the Data; Small Craters in the Inner Solar System: Primaries or Secondaries or Both?; Generation of an Ordinary-Chondrite Regolith by Repetitive Impact; Asteroid Modal Mineralogy Using Hapke Mixing Models: Validation with HED Meteorites; Particle Size Effect in X-Ray Fluorescence at a Large Phase Angle: Importance on Elemental Analysis of Asteroid Eros (433); An Investigation into Solar Wind Depletion of Sulfur in Troilite; Photometric Behaviour Dependent on Solar Phase Angle and Physical Characteristics of Binary Near-Earth-Asteroid (65803) 1996 GT; Spectroscopic Observations of Asteroid 4 Vesta from 1.9 to 3.5 micron: Evidence of Hydrated and/or Hydroxylated Minerals; Multi-Wavelength Observations of Asteroid 2100 Ra-Shalom: Visible, Infrared, and Thermal Spectroscopy Results; New Peculiarities of Cometary Outburst Activity; Preliminary Shape Modeling for the Asteroid (25143) Itokawa, AMICA of Hayabusa Mission; Scientific Capability of MINERVA Rover in Hayabusa Asteroid Mission; Characteristics and Current Status of Near Infrared Spectrometer for Hayabusa Mission; Sampling Strategy and Curation Plan of Hayabusa Asteroid Sample Return Mission; Visible/Near-Infrared Spectral Properties of MUSES C Target Asteroid 25143 Itokawa; Calibration of the NEAR XRS Solar Monitor; Modeling Mosaic Degradation of X-Ray Measurements of 433 Eros by NEAR-Shoemaker; Scattered Light Remediation and Recalibration of near Sheomaker s NIS Global Dataaset at 433 Eros; Evaluation of Preparation and Measuring Techniques for Interplanetary Dust Particles for the MIDAS Experiment on Rosetta; Chiron: a Proposed Remote Sensing Prompt Gamma Ray Activation Analysis Instrument for a Nuclear Powered Prometheus Mission;From Present Surveying to Future Prospecting of the Asteroid Belt; Asteroid Physical Properties Probe Microgravity Testing of a Surface Sampling System for Sample Return from Small Solar System Bodies;and Penetrator Coring Apparatus for Cometary Surfaces.

Source record↗

DOE OSTI2017

Broadband Photon Spectrum and its Radial Profile of Pulsar Wind Nebulae

The observed radial profiles of the X-ray emission from pulsar wind nebulae (PWNe) have been claimed to contradict the standard 1D steady model. However, the 1D model has not been tested to simultaneously reproduce the volume-integrated spectrum and the radial profile of the surface brightness. We revisit the 1D steady model and apply it to PWNe 3C 58 and G21.5−0.9. We find that the parameters of the pulsar wind, the radius of the termination shock r{sub s}, and magnetization σ greatly affect both the photon spectrum and radial profile of the emission. We have shown that the parameters constrained by the entire spectrum lead to an X-ray nebula smaller than the observed nebula. We have also tested the case that reproduces only the observations in X- and gamma-rays, ignoring the radio and optical components. In this case, there are parameter sets that reproduce both the spectrum and emission profile, but the advection time to the edge of the nebula becomes much smaller than the age. Our detailed discussion clarifies that the standard 1D steady model has severe difficulty to simultaneously reproduce both the volume-integrated spectrum and the surface brightness. This implies that the model should be improved by taking into account extra physical processes such as spatial diffusion of particles. Additionally, we calculate the surface brightness profile of the radio, optical, and TeV gamma-rays. The future observations in these wavelengths are also important to probe the spatial distributions of the relativistic plasma and the magnetic field of PWNe.

79 ASTRONOMY AND ASTROPHYSICS↗

NASA NTRS1984

The accuracy of altimetric surfaces

Estimates of the shape of the sea surface as determined from satellite altimeters have become of increasing importance in geophysics, geodesy and physical oceanography. The most effective error reduction procedures used in producing these surfaces have been some version of a crossing-arc analysis. The problem with this procedure is the absence of an easy means of evaluating the noise structure of the final result. By recasting the problem as one of objective mapping (optimal estimation) the error reduction is optimized and an explicit estimate is obtained of the wave-number structure of the final altimetric surface. Examples, suitable to a small computer, have been generated to show that the error reduction along the sub-satellite tracks is very great, with most of the residual lying in long wavelengths.

Wunsch, C.↗

NASA NTRS1993

Design of a surface deformation measuring instrument for the Surface Tension Driven Convection Experiment (STDCE-2)

This final technical report covers the work accomplished (under NAG3-1300) from 1 October 1991 to 1 October 1993. The grant is a direct result of Dr. H. Philip Stahl's (of Rose-Hulman Institute of Technology) participation in the NASA/ASEE Summer Faculty Fellowship Program at NASA Lewis Research Center sponsored by Case Western Reserve University and the Ohio Aerospace Institute. The Surface Tension Driven Convection Experiment (STDCE) is a fundamental fluid physics experiment designed to provide quantitative data on the thermocapillary flow of fluid under the influence of an increased localized surface temperature. STDCE flew on the Space Shuttle Columbia in the First United States Microgravity Laboratory (USML-1) in June 1992. The second flight of this experiment (STDCE-2) is scheduled for 1995. The specific science objectives of STDCE-2 are to determine the extent and nature of thermocapillary flows, the effect of heating mode and level, the effect of the liquid free-surface shape, and the onset conditions for and nature of oscillatory flows. In order to satisfy one of these objectives, an instrument for measuring the shape of an air/oil free surface must be developed.

Stahl, H. Philip↗

DOE OSTI2023

Revealing a 3D Fermi Surface Pocket and Electron-Hole Tunneling in UTe 2 with Quantum Oscillations

Spin triplet superconductor UTe 2 is widely believed to host a quasi-two-dimensional Fermi surface, revealed by first-principles calculations, photoemission and quantum oscillation measurements. An outstanding question still remains as to the existence of a three-dimensional Fermi surface pocket, which is crucial for our understanding of the exotic superconducting and topological properties of UTe 2 . This 3D Fermi surface pocket appears in various theoretical models with different physics origins, but has not been unambiguously detected in experiment. Here, in this study, for the first time we provide concrete evidence for a relatively isotropic, small Fermi surface pocket of UTe 2 via quantum oscillation measurements. In addition, we observed high frequency quantum oscillations corresponding to electron-hole tunneling between adjacent electron and hole pockets. The coexistence of 2D and 3D Fermi surface pockets, as well as the breakdown orbits, provides a test bed for theoretical models and aid the realization of a unified understanding of superconducting state of UTe 2 from the first-principles approach.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

NASA NTRS1987

Parameterization of radiative flux profiles within layer clouds

This paper presents simple formulations for the vertical structure of solar and infrared radiative fluxes within a layer cloud overlying a partially reflective surface. The parameterized profile shapes are analytic, with governing parameters derived from bulk radiative properties and more physically based radiative transfer models. The bulk cloud, subcloud layer, and surface radiative properties are assumed to be known. The parameterizations are based on exponential functions of height, with decay scales related to cloud liquid water content. Although the results presented here are based on very simple assumptions about the cloud structure in the vertical, the method used is applicable to more general cases as well as to various other analytic and/or numerical radiative transfer calculations.

Hanson, Howard P.↗

DOE OSTI2018

Investigating the role of anhydrous oxidative weathering on sedimentary rocks in the Transantarctic Mountains and implications for the modern weathering of sedimentary lithologies on Mars

We present that alteration of the uppermost surfaces of geologic materials is a pervasive process on planetary surfaces that is dependent upon factors including parent composition and the environment under which alteration is occurring. While rapid and pervasive in hot and humid climates on Earth, chemical weathering of rock surfaces has also been found to dominate in some of Earth's coldest and driest landscapes as well. Specifically, surfaces dominated by resistant fine-grained igneous rocks in the Antarctic preserve evidence of oxidative weathering processes, which represent the initial immature surface alteration processes that stagnate due to the lack of available water and kinetics necessary for the production of more mature alteration phases. In this study, we test the hypothesis that oxidative weathering also dominates the surfaces of sedimentary rocks throughout the Antarctic. We investigated the chemistry and mineralogy of a suite of sedimentary rocks from the Transantarctic Mountains ranging from fine-grained tuffs to coarse-grained sandstones and conglomerates. Additionally, our results show that, like the previously studied fine-grained igneous rocks in the Antarctic, sedimentary rocks generally showed only minor chemical weathering signatures at their surfaces relative to their interiors. However, unlike the igneous rocks in this earlier study, the sedimentary rocks exhibited a wide variety of non-systematic differences between surface and interior compositions. This variability of surface weathering signatures is equally as complex as the physical properties and compositions inherently present within these different sedimentary lithologies. Based on these analyses, it is apparent that oxidative weathering products do not dominate the surfaces of sedimentary rocks throughout the Transantarctic Mountains, which instead exhibit a wide array of weathering signatures that are likely dependent on both lithological and environmental factors. Considering that sedimentary lithologies are widespread across a significant fraction of the martian surface, our results suggest that observed alteration signatures limited to the surfaces of martian sedimentary rocks are most likely to be minor and to vary as a result of the lithological properties of the specific rock unit and not as a result of the widespread influences of the modern cold and dry climatic conditions.

58 GEOSCIENCES↗