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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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155 records · Page 9

Temperature Sensing to Above 1500 °C Using Y 2 SiO 5 :Er Phosphor Thermometry

A transition from metallic to ceramic turbine components that can operate at higher turbine engine temperatures will push component surface temperatures from below 1200 °C into a 1300 to 1500 °C temperature range that is much more challenging for phosphor thermometry measurements. To address this challenge, Y 2 SiO 5 :Er was selected for its high temperature sensing performance by both luminescence lifetime and luminescence intensity ratio (LIR) methods as well as its thermochemical compatibility with the current generation of rare earth silicate environmental barrier coatings (EBCs) that are required to protect SiC/SiC ceramic composite components. Lifetime measurements that monitor the Er3+ 4S3/2→4I15/2 emission decay at 542 nm exhibited a slow decrease in decay time with temperature up to 1300° C, above which the decay decreased steeply to provide good temperature sensitivity in the 1300 to 1500 °C range (Fig. 1). LIR images were obtained where each pixel represented the ratio I488/I561 (I488 and I561 are the detected 488 nm 4F7/2→4I15/2 and the 561 nm 4S3/2→4I15/2 emission band intensities, respectively). Good temperature sensitivity (Fig. 2) and signal-to-background ratios were observed to above 1500 °C. Contrary to conventional guidance on selecting phosphors for high temperature sensing, the detected emission band intensities and decay times exhibited remarkably slow decreases with temperature up into the 1300 to 1500 °C range despite high phonon energies (>900 cm-1) that allow the energy gap between the 4S3/2 emitting reservoir level and the 4F9/2 level below it to be bridged by as few as three phonons. The benefits of utilizing a thermographic phosphor at very high temperatures that exhibits strong nonradiative multiphonon relaxation even at room temperature is explained by a competition between spontaneous and stimulated multiphonon emission, and the more temperature-sensitive decay time above 1300 °C is explained by a transition from high to low effective phonon energies.

temperature measurement↗

Transition Modeling Based on the Dual N-factor Method for the CRM-NLF Wind Tunnel Configuration

The dual N-factor method is used to model the boundary-layer transition over the common research model with natural laminar flow (CRM-NLF) aircraft configuration. The flow conditions match selected test conditions from a wind tunnel experiment in the National Transonic Facility at the NASA Langley Research Center. The paper presents a systematic methodology for transition prediction in the presence of a dual shock system and extends the prior capability for iteratively coupled computational fluid dynamics (CFD) predictions to incorporate three-dimensional, transonic wings. The method employs stability computations based on the linear parabolized stability equations (PSE), along with a dual N-factor criterion. The iterative process begins with the fully turbulent Reynolds-averaged-Navier-Stokes (RANS) mean flow solution. For the first iteration, a mean flow solution is calculated with an imposed transition front that aligns with the shock front from the fully turbulent solution. Subsequently, stability computations are performed along a set of streamlines across the wing to calculate the amplification of planar Tollmien-Schlichting (TS) and stationary crossflow (CF) modes. The transition criterion based on the dual N-factor method is used to infer the updated transition front and the process is successively repeated until convergence of the solution. Within three iterations, the predicted fronts for angles of attack of 1.45, 1.98, 2.46 and 2.94 degrees and a mean-aerodynamic-chord Reynolds number equal to 15 million, approach visual convergence in most regions of the studied cases, and the resulting predictions are in good agreement with the transition fronts deduced from measurements of temperature-sensitive paint. Even though surface pressure measurements based on fully-turbulent flow agree well with the measured pressure coefficient distributions, strong viscous-inviscid interaction effects cause significant shifts in the shock locations based on the imposed transition front, underscoring the intrusive nature of static pressure measurements using surface mounted ports on the CRM-NLF configuration.

Boundary Layer Transition↗

A Sub-THz CMOS Molecular Clock with 20 ppt Stability at 10,000 s Based on A Dual-Loop Spectroscopic Detection and Digital Frequency Error Integration

This paper presents a dual-loop chip-scale molecular clock (CSMC), which enhances the Allan Deviation performance by combining high signal-to-noise ratio of using fundamental mode and long-term stability of using higher order modes in derivative molecular absorption spectroscopy. In addition, digital frequency-error integration is adopted in the frequency-locked loop to provide an infinite open-loop DC gain, which fully suppresses any frequency drift caused by the temperature-sensitive crystal oscillator. This new generation CSMC is implemented in 65-nm CMOS, and achieves 20 ppt (part-per-trillion) Allan Deviation at 10,000 s averaging time with 71-mW power consumption.

Han, Ruonan↗

Sun-as-a-Star Spectral Line Variability in the 300–2390 nm Wavelength Range

Combining the near-daily Ozone Monitoring Instrument (OMI) and Tropospheric Monitoring Instrument (TROPOMI) measurements of solar spectra, we construct line indices (line-core to line-flanks ratios) for various transitions (mainly Fe I) in the 300–2390 nm spectral domain. The indices are supplemented by the wavelength-binned fluxes from OMI and Total and Spectral Solar Irradiance Sensor (TSIS-1). To study the short-term (solar-rotational) patterns, we normalize the indices and fluxes to the minimum-activity epoch, then de-trend them with 81 day running means. Comparisons of the de-trended TSIS-1 and OMI fluxes with the NASA-NOAA-LASP SSI (NNLSSI1) model show excellent agreement, to (0.5–2.2) × 10 -4 in the normalized and de-trended data. The data are subjected to a multiregression analysis against quantities representing the facular brightening and the sunspot darkening. The de-trended line indices and average fluxes show different sensitivities to these two solar magnetic-activity manifestations, with the fluxes being far more susceptible to the sunspot component. The de-trended line indices experience a rapid drop of activity levels towards longer wavelengths, albeit with a large rebound in the short-wave infrared (SWIR) domain that is caused by the ubiquitous, temperature-sensitive CO transitions. The wavelength-dependent activity also falls, however much slower, in the de-trended average fluxes. Qualitatively similar behavior is captured by semiempirical models.

Solar spectral Irradiance↗

Adaptive Curation at NASA Johnson Space Center: Preparing for Artemis Samples by Leveraging Proven Practices and Innovative Solution

The proper curation of returned astromaterial samples is essential to ensure that high-quality scientific investigations can be conducted for decades, enabling future generations to address evolving research questions. The Astromaterials Acquisition and Curation Office at NASA Johnson Space Center (hereafter JSC Curation) is responsible for curating all of NASA’s extraterrestrial samples. Under the governing document, NASA Procedural Requirement (NPR) 7100.5 “Curation of Extraterrestrial Materials”, JSC Curation is charged with “The curation of all extraterrestrial material under NASA control, including future NASA missions.” The Directive goes on to define Curation as including “...documentation, preservation, preparation, and distribution of samples for research, education, and public outreach.” JSC Curation has a long-standing legacy of curating extraterrestrial materials, including but not limited to Apollo and Luna lunar samples, Genesis solar wind samples, Stardust comet samples, asteroid samples (Hayabusa1, Hayabusa2, and OSIRIS-REx), and Antarctic Meteorite samples from a variety of parent bodies. Building on this foundation, the Artemis program introduces new challenges and opportunities for sample curation, requiring both the application of proven practices and the development of innovative solutions. The Artemis Collection will be curated using established protocols refined through decades of experience with Apollo and subsequent sample collections, including but not limited to the utilization of cleanrooms, custom nitrogen gloveboxes, specialized storage containers and tools; all of which have strict material utilization and prohibition requirements. These practices provide a robust framework for contamination control, documentation, and long-term preservation. However, Artemis samples may present unique scientific and operational requirements, including enhanced contamination control measures (relative to Apollo) driven by evolving science objectives. To meet these needs, JSC Curation is actively developing new technologies and protocols that extend beyond traditional approaches, ensuring that the integrity of samples is maintained under increasingly stringent standards. One critical area of innovation is the development of cold sample curation capabilities. Certain Artemis samples, particularly those from Permanently Shadowed Regions (PSRs) and cold environments, are expected to contain ices and volatile components that require preservation and handling at sub-zero or even cryogenic temperatures. JSC Curation is leveraging best practices from the cold and cryogenic sample industries, as well as other government agencies and academic experts, to design facilities and handling procedures that maintain sample integrity while enabling scientific access. The goal is to develop capabilities to allow researchers to investigate volatiles and other temperature-sensitive materials while minimizing chemical and physical alterations from their returned state. In summary, adaptive curation at JSC combines the reliability of proven methodologies with forward-looking innovations to meet the scientific and operational demands of Artemis. Through enhanced contamination control, advanced cold curation capabilities, and an understanding of known and evolving future science priorities, NASA is preparing to maximize the scientific return from Artemis samples and preserve their value for generations of researchers.

Andrea D Harrington↗

Integration of Nutrient and Water Recycling for Sustainable Algal Biorefineries (Final Report)

This project was performed primarily as a partnership between three Universities – The University of Toledo, Montana State University and The University of North Carolina at Chapel Hill – and the industrial collaborator Clearas Water LLC. The University of Minnesota also contributed in the last year of the project. The project addressed constraints/barriers throughout the process of production of biofuels from microalgae – cultivation, harvesting and conversion processes for fuels and value-added chemicals. The most important outcomes of this project were related to (1) developing a microalgae cultivation strategy in alkaline environments to improve culture stability, decrease reliance on concentrated CO 2 sources and high biofuel precursor yields; (2) fundamental understanding of microbial communities in algal/phototrophic environments to allow development of strategies for management of productive algal cultures; (3) low-cost and low-energy harvesting via temperature-sensitive hydrogels for recycling of water and unused nutrients and other media components; (4) development of conversion methods that generate high-value co-products, in addition to fuels, and also provide means for nutrient recycling; and (5) expanding the scope of current LCA/TEA models to inform potential investment in algal biorefineries.

09 BIOMASS FUELS↗

Amino Acids Essential for the Assembly of Cellulose Synthase Complexes

Over 40 years ago, Andrew Staehelin's group showed that plant cellulose microfibrils are synthesized by protein complexes arranged in hexagonal arrays called 'particle rosettes'. Plant cellulose synthases (CESAs) differ from their bacterial ancestral forms by insertion of three unique sequences responsible for the assembly into compact multimeric units that aggregate further into rosettes. We used site-directed mutagenesis to replace amino acids within these sequences predicted to be essential for assembly and developed an in vivo method to determine the ability of mutated CesA1 transgenes to complement an Arabidopsis temperature-sensitive root-swelling1 (rsw1) mutant. Replacement of a Cys residue in the Class-Specific Region (CSR) or Pro417 and Arg453 of the Plant-Conserved Region (P-CR) rendered an AtCesA1 transgene unable to complement the rsw1 mutation. Despite an expected role for Arg457 in the trimerization of CESA proteins, AtCesA1 transgenes with Arg457Ala mutations were able to fully restore the wild-type phenotype in rsw1. Staehelin observed a third order of assembly in Micrasterias dendiculata, where hundreds of rosettes form large hexagonal arrays during the synthesis of secondary wall cellulose macrofibrils. We found by SEM of cytosolic faces of Micrasterias cell fragments that these arrays are associated with fields of regularly spaced slime secretion pore complexes.

arabidopsis↗

FET Junction Temperature Monitoring Using Novel On-Chip Solution

A novel junction temperature monitoring sensor is proposed and experimentally demonstrated for application in MOS-gate power devices. The sensor is created using the polycide gate electrode layer of the devices to create a temperature-sensitive resistor without any additional fabrication steps. The resistor is located on the field oxide with one end grounded at the device reference terminal to isolate it from the device current and voltage transients. It allows in-situ monitoring of the device junction temperature during active circuit operation. The technology has been implemented to monitor the junction temperature of Silicon Carbide Junction Barrier Schottky Field Effect Transistors (SiC JBSFETs) with the bi-directional FET (BiDFET).

Bidirectional switches, SiC bidirectional FET, BiD↗

Thermal Optimization and Experimental Demonstration of a Silicon Carbide, Half-Bridge Power Module

This paper describes modeling and experimental work to design and demonstrate a silicon carbide (SiC), single-side-cooled power module. Two SiC metal-oxide-semiconductor field-effect transistors (MOSFET) were used for each switch position and packaged on a metalized ceramic substrate. Thermal modeling was first conducted to optimize the module packaging to minimize junction-to-fluid thermal resistance and device temperature variations. This procedure identified the optimal device placement and baseplate thickness to maximize thermal performance. A heat exchanger - incorporating impinging jets of water-ethylene glycol - was designed to cool the module's baseplate to minimize thermal resistance and pumping power. The heat exchanger used relatively low fluid velocities (<1.5 m/s) to minimize erosion-corrosion effects and relatively large fluid channel sizes (>=1 mm) to prevent clogging. The power module concept was fabricated, and experiments were conducted to measure its thermal performance. Direct current was used to power the module devices, and junction temperatures were measured via device temperature-sensitive parameters. The experimental results were found to be in good agreement with model predictions (within 2%) and yielded junction-to-fluid thermal resistance values as low as about 15 mm2 K/W at relatively low pumping power values. The results demonstrate the improved performance associated with jet impingement cooling and represent an improvement over existing channel-flow-type cold plates, which can enable improvements to power density and reliability.

36 MATERIALS SCIENCE↗

Low–severity fire as a mechanism of organic matter protection in global peatlands: Thermal alteration slows decomposition

Worldwide, regularly-recurring wildfires shape many peatland ecosystems to the extent that fire-adapted species often dominate plant communities, suggesting that wildfire is an integral part of peatland ecology rather than an anomaly. The most destructive blazes are smoldering fires that are usually initiated in periods of drought and can combust entire peatland carbon stores. However, peatland wildfires more typically occur as low-severity surface-burns that arise in the dormant season when vegetation is desiccated, and soil moisture is high. In such low-severity fires, surface layers experience flash heating, but there is little loss of underlying peat to combustion. This study examines the potential importance of such processes in several peatlands that span a gradient from hemiboreal to tropical ecozones and experience a wide range of fire return intervals. We show that low-severity fires can increase the pool of stable soil carbon by thermally altering the chemistry of soil organic matter (SOM), thereby reducing rates of microbial respiration. Using XPS and FTIR, we demonstrate that low-severity fires significantly increase the degree of carbon-condensation and aromatization of SOM functional groups, particularly on the surface of peat aggregates. Laboratory incubations show lower CO 2 emissions from peat subjected to low-severity fire, and predict lower cumulative CO 2 emissions from burned peat after one to three years. Also, low-severity fires reduce the temperature sensitivity (Q 10 ) of peat, indicating that these fires can inhibit microbial access to SOM. The increased stability of thermally-altered SOM may allow a greater proportion of organic matter to survive vertical migration into saturated and anaerobic zones of peatlands where environmental conditions physiochemically protect carbon stores from decomposition for thousands of years. Furthermore, across latitudes, low-severity fire is an overlooked factor influencing carbon cycling in peatlands, which is relevant to global carbon budgets as climate-change alters fire regimes worldwide.

54 ENVIRONMENTAL SCIENCES↗