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DOE OSTI · 1784896

Ternary Nitride Materials: Fundamentals and Emerging Device Applications

Greenaway, Ann L.·Melamed, Celeste L.·Tellekamp, M. Brooks·Woods-Robinson, Rachel·Toberer, Eric S.·Neilson, James R.·Tamboli, Adele C.
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Abstract

Interest in inorganic ternary nitride materials has grown rapidly over the past few decades, as their diverse chemistries and structures make them appealing for a variety of applications. Due to synthetic challenges posed by the stability of N 2 , the number of predicted nitride compounds dwarfs the number that have been synthesized, offering a breadth of opportunity for exploration. This review summarizes the fundamental properties and structural chemistry of ternary nitrides, leveraging metastability and the impact of nitrogen chemical potential. A discussion of prevalent defects, both detrimental and beneficial, is followed by a survey of synthesis techniques and their interplay with metastability. Throughout the review, we highlight applications (such as solid-state lighting, electrochemical energy storage, and electronic devices) in which ternary nitrides show particular promise.

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRYbatterymetastabilitynitride synthesisoptoelectronicsstructural chemistryternary nitride

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Greenaway, Ann L., Melamed, Celeste L., Tellekamp, M. Brooks, Woods-Robinson, Rachel, Toberer, Eric S., Neilson, James R., Tamboli, Adele C.. 2021-05-12. Ternary Nitride Materials: Fundamentals and Emerging Device Applications. https://doi.org/10.1146/annurev-matsci-080819-012444

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