Search NASA⌕ Search

DOE OSTI · 22004842

Effect of the silicon doping level and features of nanostructural arrangement on decrease in external quantum efficiency in InGaN/GaN light-emitting diodes with increasing current

Abstract

A comprehensive study of blue light-emitting diodes based on quantum-well InGaN/GaN structures with external quantum efficiencies {eta} of up to 40% has been carried out. It is shown that, in the general case, the manner in which the efficiency depends on the current density j is determined by the competition of contributions to the radiative recombination of localized and delocalized carriers. The contribution of the latter grows with worsening structural organization of the nanomaterial, increasing temperature and drive current, and decreasing width of the depleted layer in the active region (under zero bias). The steepest efficiency droop relative to the maximum value (by up to a factor of 2 at j Almost-Equal-To 50 A cm{sup -2}) is observed in the case of heavy doping of the n{sup +}-region (to 10{sup 19} cm{sup -3}) and upon appearance of compensated layers in the active or p{sup +}-region. At j > 50 A cm{sup -2}, the contribution of delocalized carriers is predominant and the current dependences of efficiency are of uniform type, approximated with {eta}(j) {proportional_to} j{sup -b}, where 0.2 < b < 0.3.

Explore related subjects

Keep this discovery

Explore connections, maps & timelines

BibTeXRIS

Ber, B Ya, Bogdanova, E V, Zakgeim, A L, Kazanzev, D Yu, Kartashova, A P, Pavluchenko, A S, Chernyakov, A E, Shabunina, E I, Shmidt, N M, Yakimov, E B. 2011-03-15. Effect of the silicon doping level and features of nanostructural arrangement on decrease in external quantum efficiency in InGaN/GaN light-emitting diodes with increasing current. https://doi.org/10.1134/s1063782611030079

Cite the original work for its findings. Save a collection to share your selection of sources.

KEEP EXPLORING

Related reports

Cyclic moisture reactivation of calcium sorbents for long duration thermochemical energy storage

The transition to a flexible and reliable energy infrastructure, using electro-thermal energy generation technologies such as geothermal, concentrated solar power, and nuclear, usually demands simultaneous advancement of thermal energy storage (TES) to support on-demand electricity generation and industrial applications while mitigating the inherent intermittency of renewable energy sources and power outages from direct energy generation. Among TES technologies, thermochemical energy storage (TCES) based on calcium looping emerges as a compelling high-power energy storage candidate due to its high reaction enthalpy, compatibility with elevated operating temperatures, and abundance of low-cost materials. However, the long-term durability of calcium-based sorbents for TCES is hindered by surface sintering and particle aggregation, leading to performance degradation over repeated thermal cycles. This study explores a moisture hydration-based strategy to regenerate a degraded calcium sorbent and mitigate performance degradation for long duration TCES. The addition of moisture transforms calcium oxide into calcium hydroxide and produces intercalation water layers, associated with a regenerated surface area and reduced calcium oxide crystallite size. Both these effects are beneficial in restoring the sorbents' reactivity for carbonization. Additionally, an optimized hydration-assisted reactivation protocol balances the recovered energy storage capacity with heating penalty required for moisture removal from hydrated samples, resulting in an enhanced energy storage capacity up to 176% compared to benchmark sorbents that undergo cycling without reactivation after 60 cycles. In conclusion, these results highlight the potential of hydration-assisted reactivation to enhance the long-term performance of TCES, providing an effective pathway to advancing electro-thermal storage technologies.

36 MATERIALS SCIENCE↗