Search NASA⌕ Search

SEARCH · Search NASA

Results for “Gradient Limiters”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 253 records · Page 14

AO/NAO Response to Climate Change: Relative Importance of Low- and High-Latitude Temperature Changes - 2

Using a variety of GCM experiments with various versions of the GISS model, we investigate how different aspects of tropospheric climate changes affect the extratropical Arctic Oscillation (AO)/North Atlantic Oscillation (NAO) circulation indices. The results show that low altitude changes in the extratropical latitudinal temperature gradient can have a strong impact on eddy forcing of the extratropical zonal wind, in the sense that when this latitudinal temperature gradient increases, it helps force a more negative AO/NAO phase. In addition, local conditions at high latitudes can stabilize/destabilize the atmosphere, inducing negative/positive phase changes. To the extent that there is not a large temperature change in the tropical upper troposphere (either through reduced tropical sensitivity at the surface, or limited transport of this change to high levels), the changes in the low level temperature gradient can provide the dominate influence on the extratropical circulation, so that planetary wave meridional refraction and eddy angular momentum transport changes become uncorrelated with potential vorticity transports. In particular, the climate change that produces the most positive NAO phase change would have substantial warming in the tropical upper troposphere over the Pacific Ocean, with high latitude warming in the North Atlantic. An increase in positive phase of these circulation indices is still more likely than not, but it will depend on the degree of tropical and high latitude temperature response and the transport of low level warming into the upper troposphere. These are aspects that currently differ among the models used for predicting the effects of global warning, contributing to the lack of consensus of future changes in the AO/NAO.

Rind, D.↗

Physiological Response of Plants Grown on Porous Ceramic Tubes

This research involves the manipulation of the root-zone water potential for the purposes of discriminating the rate limiting step in the inorganic nutrient uptake mechanism utilized by higher plants. This reaction sequence includes the pathways controlled by the root-zone conditions such as water tension and gradient concentrations. Furthermore, plant based control mechanisms dictated by various protein productions are differentiated as well. For the nutrients limited by the environmental availability, the kinetics were modeled using convection and diffusion equations. Alternatively, for the nutrients dependent upon enzyme manipulations, the uptakes are modeled using Michaelis-Menten kinetics. In order to differentiate between these various mechanistic steps, an experimental apparatus known as the Porous Ceramic Tube - Nutrient Delivery System (PCT-NDS) was used. Manipulation of the applied suction pressure circulating a nutrient solution through this system imposes a change in the matric component of the water potential. This compensates for the different osmotic components of water potential dictated by nutrient concentration. By maintaining this control over the root-zone conditions, the rate limiting steps in the uptake of the essential nutrients into tomato plants (Lycopersicon esculentum cv. Cherry Elite) were differentiated. Results showed that the uptake of some nutrients were mass transfer limited while others were limited by the enzyme kinetics. Each of these were adequately modeled with calculations and discussions of the parameter estimations provided.

Tsao, David↗

Ultrastable cathodes enabled by compositional and structural dual-gradient design

Cathodes for next-generation batteries are pressed for higher voltage operation (≥4.5 V) to achieve high capacity with long cyclability and thermal tolerance. Current cathodes fail to meet these requirements owing to structural and electrochemical strains at high voltages, leading to fast capacity fading. Here, in this work, we present a cathode with a coherent architecture ranging from ordered to disordered frameworks with concentration gradient and controllable Ni oxidation activities, which can overcome voltage ceilings imposed by existing cathodes. This design enables simultaneous high-capacity and high-voltage operation at 4.5 V without capacity fading, and up to 4.7 V with negligible capacity decay. Multiscale diffraction and imaging techniques reveal the disordered surface is electrochemically and structurally indestructible, preventing surface parasitic reactions and phase transitions. Structural coherence from ordering to disordering limits lattice parameter changes, mitigating lattice strain and enhancing morphological integrity. The dual-gradient design also notably improves thermal stability, driving the advancement of high-performance cathode materials.

36 MATERIALS SCIENCE↗

Ion-wave current instabilities and anomalous resistivity.

A theory of ion-wave current instabilities which takes into account, in a self-consistent manner, the inhomogeneities generated by field-aligned currents in a collisionless plasma is presented. Diamagnetic current associated with the current-produced density gradient is included in the distribution. The theory predicts that for a given frequency, the current threshold for ion-wave current instabilities is, in general, much below the threshold of ion acoustic instability in a uniform plasma as given by Fried and Gould. The current threshold is essentially zero in the limit when the ion Landau damping effect is negligible, or equivalently, the ion-wave current instabilities are absolute if there are no limitations on the wavelength. This is true even in the absence of externally applied density gradients in contrast to Kadomtsev's drift-wave results. For dimensions of interest in laboratory plasmas, the predicted linear growth rate increases with increasing longitudinal wavelength and with decreasing wavelength parallel to the diamagnetic current. Under the conditions of an experiment on anomalous resistivity (the dimensions but not the geometry of the machine have been considered), there is good agreement between the predicted onset of ion-wave current instabilities and the experimental data on the onset of anomalous resistivity.

Kan, J. R.↗

MESSENGER Searches for Less Abundant or Weakly Emitting Species in Mercury's Exosphere

Mercury's exosphere is composed of material that originates at the planet's surface, whether that material is native or delivered by the solar wind and micrometeoroids. Many exospheric species have been detected by remote sensing, including H and He by Mariner 10, Na, K, and Ca by ground-based observations, and H, Na, Ca, Mg, and Ca+ by the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft. Other exospheric species, including Fe, AI, Si, 0, S, Mn, CI, Ti, OH, and their ions, are expected to be present on the basis of MESSENGER surface measurements and models of Mercury's surface chemistry. Here we report on searches for these species made with the Ultraviolet and Visible Spectrometer (UVVS) channel of the Mercury Atmospheric and Surface Composition Spectrometer (MASCS). No obvious signatures of the listed species have yet been observed in Mercury's exosphere by the UVVS as of this writing. It is possible that detections are elusive because the optimum regions of the exosphere have not been sampled. The Sun-avoidance constraints on MESSENGER place tight limits on instrument boresight directions, and some regions are probed infrequently. If there are strong spatial gradients in the distribution of weakly emitting species, a high-resolution sampling of specific regions may be required to detect them. Summing spectra over time will also aid in the ability to detect weaker emission. Observations to date nonetheless permit strong upper limits to be placed on the abundances of many undetected species, in some cases as functions of time and space. As those limits are lowered with time, the absence of detections can provide insight into surface composition and the potential source mechanisms of exospheric material.

Vervack, Ronald J., Jr.↗

Accelerating resonant spectroscopy simulations using multishifted biconjugate gradient

Resonant spectroscopies, which involve intermediate states with finite lifetimes, provide important insights into collective excitations in quantum materials that are otherwise inaccessible. However, theoretical understanding in this area is often limited by the numerical challenges of solving Kramers-Heisenberg-type response functions for large-scale systems. To address this, we introduce a multishifted biconjugate gradient algorithm that exploits the shared structure of Krylov subspaces across spectra with varying incident energies, effectively reducing the computational complexity to that of linear spectroscopies. Both mathematical proofs and numerical benchmarks confirm that this algorithm substantially accelerates spectral simulations, achieving constant complexity independent of the number of incident energies, while ensuring accuracy and stability. This development provides a scalable, versatile framework for simulating advanced spectroscopies in quantum materials.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗

Zero Resistance Ammetry (ZRA) Measurements of Sediment Electrochemical Gradients, Old Woman Creek, Ohio, USA, June–November 2022

This dataset contains raw and processed zero resistance ammetry (ZRA) measurements collected from wetland sediments at Old Woman Creek, a freshwater estuary on Lake Erie, Ohio, USA, between June and November 2022. Measurements were obtained using a vertically deployed electrode array positioned at multiple depths within the sediment profile to capture electrochemical gradients associated with microbial activity and sediment geochemistry. The raw dataset consists of parsed instrument log files containing timestamps, electrode pair identifiers, and measured electrical potential (mV). The processed dataset includes standardized and quality-controlled values with instrument saturation limits removed and timestamps converted to ISO 8601 format. Electrode line identifiers were mapped to physical depths, enabling interpretation of depth-resolved electrochemical gradients. Instrument saturation values (−2048, −2047, 2047, and 2048 mV) were identified as measurement limits and excluded from quantitative analyses. All data parsing, processing, and quality control steps are documented in an accompanying R Markdown script, ensuring full reproducibility from raw instrument logs to final datasets.

EARTH SCIENCE > AGRICULTURE > SOILS > ELECTRICAL C↗

Static Subspace Approximation for Random Phase Approximation Correlation Energies: Applications to Materials for Catalysis and Electrochemistry

Modeling complex materials using high-fidelity, ab initio methods at low cost is a fundamental goal for quantum chemical software packages. The GW approximation and random phase approximation (RPA) provide a unified description of both electronic structure and total energies using the same physics in a many-body perturbative approach that can be more accurate than generalized-gradient density functional theory (DFT) methods. However, GW/RPA implementations have historically been limited to either specific materials classes or application toward small chemical systems. Here, the static subspace approximation allows for reduced cost full-frequency GW/RPA calculations and has previously been benchmarked thoroughly for GW calculations. Here, we describe our approach to including partial occupations of electronic orbitals in full-frequency GW and RPA calculations for the study of electrocatalysts. We benchmarked RPA total energy calculations using the subspace approximation across a diverse test suite of materials for a variety of computational parameters. The benchmarking quantifies the impact of different extrapolation procedures for representing the static polarizability at infinite screened cutoff, and shows that using screened cutoffs above 20-25 Ryd result in diminishing accuracy returns for predicting RPA total energies. Additionally, for moderately sized electrocatalytic models, 2-3 times fewer computational resources are used to compute RPA total energies by representing the static polarizability with 20-30% of the static subspace basis, with an error of approximately 0.01 eV or better in RPA adsorption energy calculations. Finally, we show that for these electrochemical models RPA can shift DFT adsorption energy shifts by up to 0.5 eV and that GW can frequently shift DFT eigenvalues of surface and adsorbate states by approximately 0.5-1 eV.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Development of a Traveling-Wave (TW) SRF cavity

Traveling-wave technology can push the accelerator field gradient of niobium SRF cavity to 70MV/m or higher beyond the fundamental limit of 50~60MV/m in Standing-Wave regime. The 1st demonstration of TW resonance excitation in a proof-of-principle 3-cell SRF cavity in 2K liquid helium was successfully carried out at Fermilab in collaboration with Euclid Techlabs. In parallel with that, to advancing TW technologies necessary more for future accelerator-scale one, Fermilab has proposed a preliminary RF design of a half-meter scale TW SRF cavity by considering the physical dimensions of existing SRF facilities and the lessons learned from the 3-cell,. It consists of a 7-cell structure and a power feedback waveguide (WG) loop with new RF configurations to control TW resonance. Development efforts toward a TW 7-cell has been in progress. Here we report the recent activities and progresses of those.

Furuta, F.↗

Mock-Up Waveguide Loop Development toward a Half-Meter Scale Traveling-Wave SRF Cavity

Mock-up waveguide loop development toward a half-meter scale traveling-wave SRF cavity ABSTRACT = Traveling-Wave (TW) technology can push the accelerator field gradient of niobium SRF cavity to 70MV/m or higher beyond the fundamental limit of 50~60MV/m in Standing-Wave regime. The success of TW resonance excitation in a proof-of-principle 3-cell SRF cavity in 2K liquid helium encouraged to advance TW technologies necessary more for future accelerator-scale one. Fermilab has proposed a preliminary RF design of a half-meter scale TW cavity by considering the physical dimensions of existing SRF facilities and the lessons learned from the 3-cell. It consists of a 7-cell structure and a power feedback waveguide (WG) loop with new TW excitation and control schemes such as, double directional coupler and two WG tuners. Mock-up waveguide loop development was launched under Fermilab LDRD program to demonstrate those new RF schemes at a room temperature. Fabrication drawings of a mock-up loop were completed. More details and plans of the development will be presented.

Furuta, Fumio [Fermilab]↗

Light Scattering Tests of Fundamental Theories of Transport Properties in the Critical Region

The objective of this program is to measure the decay rates of critical density fluctuations in a simple fluid (xenon) very near its liquid-vapor critical point using laser light scattering and photon correlation spectroscopy. Such experiments have been severely limited on Earth by the presence of gravity which causes large density gradients in the sample when the compressibility diverges approaching the critical point. The goal is to measure decay rates deep in the critical region where the scaled wavevector is the order of 1000. This will require loading the sample to 0.01% of the critical density and taking data as close as 3 microKelvin to the critical temperature (Tc = 289.72 K). Other technical problems have to be addressed such as multiple scattering and the effect of wetting layers. The ability to avoid multiple scattering by using a thin sample (100 microns) was demonstrated, as well as a temperature history which can avoid wetting layers satisfactory temperature control and measurement, and accurate sample loading. Thus the questions of experimental art are solved leaving the important engineering tasks of mounting the experiment to maintain alignment during flight and automating the state-of-the-art temperature bridges for microcomputer control of the experiment.

Gammon, R. W.↗

The dynamics of a space station tethered refueling facility

The fluid stored in a tethered orbital refueling facility is settled at the bottom of the storage tanks by gravity-gradient forces. The fluid motions (slosh) induced by outside disturbances must be limited to ensure the tank outlet is not uncovered during a fluid transfer. The dynamics of a LO2/LH2 TORF attached to the space station have been analyzed to identify design parameters necessary to limit fluid motion. Using the worst case disturbance of a shuttle docking at the space station, the fluid motion was found to be a function of tether length and allowable facility swing angle. Acceptable fluid behavior occurs for tether lengths of at least 1000 ft. To ensure motions induced by separate disturbances do not add to unacceptable values, a slosh damping coefficient of 5 percent is recommended.

Abbott, P.↗

Protein crystal growth - Growth kinetics for tetragonal lysozyme crystals

Results are reported from theoretical and experimental studies of the growth rate of lysozyme as a function of diffusion in earth-gravity conditions. The investigations were carried out to form a comparison database for future studies of protein crystal growth in the microgravity environment of space. A diffusion-convection model is presented for predicting crystal growth rates in the presence of solutal concentration gradients. Techniques used to grow and monitor the growth of hen egg white lysozyme are detailed. The model calculations and experiment data are employed to discuss the effects of transport and interfacial kinetics in the growth of the crystals, which gradually diminished the free energy in the growth solution. Density gradient-driven convection, caused by presence of the gravity field, was a limiting factor in the growth rate.

Pusey, M. L.↗

The energy input mechanism into the lower transition regions between stellar chromospheres and coronae

The ratio of the emission line fluxes for the C II and C IV lines in the lower transition regions (T = 30,000 to 100,000 K) between stellar chromospheres and transition layers is shown to depend mainly on the temperature gradient in the line emitting regions which can therefore be determined from this line ratio. From the observed constant (within the limits of observational error) ratio of the emission line fluxes of the C II (1335 A) and C IV (1550 A) lines it is concluded that the temperature gradients in the lower transition layers are similar for the large majority of stars independently of T sub eff, L, and degree of activity. This means that the temperature dependence of the damping length for the mechanical flux must be the same for all these stars. Since for different kinds of mechanical fluxes the dependence of the damping length on gas pressure and temperature is quite different, it is concluded that the same heating mechanism must be responsible for the heating of all the lower transition layers of these stars, regardless of their chromospheric activity. Only the amount of mechanical flux changes. The T Tauri stars are exceptions: their emission lines are probably mainly due to circumstellar material.

Boehm-Vitense, Erika↗

Low-speed flowfield characterization by infrared measurements of surface temperatures

An experimental program was aimed at identifying areas in low speed aerodynamic research where infrared imaging systems can make significant contributions. Implementing a new technique, a long electrically heated wire was placed across a laminar jet. By measuring the temperature distribution along the wire with the IR imaging camera, the flow behavior was identified. Furthermore, using Nusselt number correlations, the velocity distribution could be deduced. The same approach was used to survey wakes behind cylinders in a wind-tunnel. This method is suited to investigate flows with position dependent velocities, e.g., boundary layers, confined flows, jets, wakes, and shear layers. It was found that the IR imaging camera cannot accurately track high gradient temperature fields. A correlation procedure was devised to account for this limitation. Other wind-tunnel experiments included tracking the development of the laminar boundary layer over a warmed flat plate by measuring the chordwise temperature distribution. This technique was applied also to the flow downstream from a rearward facing step. Finally, the IR imaging system was used to study boundary layer behavior over an airfoil at angles of attack from zero up to separation. The results were confirmed with tufts observable both visually and with the IR imaging camera.

Gartenberg, E.↗

Risk of Skin Cancer from Space Radiation

We review the methods for estimating the probability of increased incidence of skin cancers from space radiation exposure, and describe some of the individual factors that may contribute to risk projection models, including skin pigment, and synergistic effects of combined ionizing and UV exposure. The steep dose gradients from trapped electrons, protons, and heavy ions radiation during EVA and limitations in EVA dosimetry are important factors for projecting skin cancer risk of astronauts. We estimate that the probability of increased skin cancer risk varies more than 10-fold for individual astronauts and that the risk of skin cancer could exceed 1 % for future lunar base operations for astronauts with light skin color and hair. Limitations in physical dosimetry in estimating the distribution of dose at the skin suggest that new biodosimetry methods be developed for responding to accidental overexposure of the skin during future space missions.

Cucinotta, Francis A.↗

Development of a half-meter scale Traveling-Wave (TW) SRF cavity

Traveling-wave technology can push the accelerator field gradient of niobium SRF cavity to 70MV/m or higher beyond the fundamental limit of 50~60MV/m in Standing-Wave regime. The 1st demonstration of TW resonance excitation in a proof-of-principle 3-cell SRF cavity in 2K liquid helium was successfully carried out at Fermilab in collaboration with Euclid Techlabs. In parallel with that, the RF design process of 0.5~1 meter scale TW cavity was begun at Fermilab for advancing TW technologies necessary more for future accelerator-scale one. Considering the physical dimensions of existing SRF facilities (for fabrication, processing, and cryogenic testing) and the lessons learned from the 3-cell, Fermilab has proposed a preliminary RF design of a half-meter scale TW SRF cavity. It consists of a 7-cell structure and a power feedback waveguide (WG) loop with new RF configurations to control TW resonance. Here we report a preliminary RF design, development plans, and activities.

43 PARTICLE ACCELERATORS↗