Improved Gas Seal for Electrolytic Cells
Breakage by differential thermal expansion reduced. Cells for hot electrolysis of gases improved by design that reduces vulnerability of gas seals to breakage at operating temperature of about 1000 degrees C.
SEARCH · Search NASA
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.
Breakage by differential thermal expansion reduced. Cells for hot electrolysis of gases improved by design that reduces vulnerability of gas seals to breakage at operating temperature of about 1000 degrees C.
The objective of the High-Pressure Turbine Fabrication Program was to demonstrate the application and feasibility of Pratt & Whitney Aircraft-developed two-piece, single crystal casting and bonding technology on the turbine blade and vane configurations required for the high-pressure turbine in the Energy Efficient Engine. During the first phase of the program, casting feasibility was demonstrated. Several blade and vane halves were made for the bonding trials, plus solid blades and vanes were successfully cast for materials evaluation tests. Specimens exhibited the required microstructure and chemical composition. Bonding feasibility was demonstrated in the second phase of the effort. Bonding yields of 75 percent for the vane and 30 percent for the blade were achieved, and methods for improving these yield percentages were identified. A bond process was established for PWA 1480 single crystal material which incorporated a transient liquid phase interlayer. Bond properties were substantiated and sensitivities determined. Tooling die materials were identified, and an advanced differential thermal expansion tooling concept was incorporated into the bond process.
A theoretical basis was developed for the design of fasteners which are free of thermal stress. A fastener can be shaped to eliminate the thermal stress which would otherwise result from differential thermal expansion between dissimilar fastener and sheet materials for many combinations of isotropic and orthotropic materials. The resulting joint remains snug, yet free of thermal stress at any temperature, if the joint is uniform in temperature, if it is frictionless, and if the coefficients of thermal expansion of the materials do not change with temperature. In general, such a fastener has curved sides; however, if both materials have isotropic coefficients of thermal expansion, a conical fastener is free of thermal stress. Equations are presented for thermal stress free shapes at both initial and final temperature, and typical fastener shapes are shown.
The possible application of Barkhausen Noise Analysis to assess shrink fit stresses in steel bushings was investigated. Ten specimens of four different size NAS steel bushings were used in experiments to determine the relationship between the Barkhausen signal amplitude and the hoop-stress in the bushings. This relationship was investigated for specimens which were loaded by a simple clamping fixture and specimens subjected to actual thermal interference fits. The results show that while the relationship of Barkhausen signal amplitude to hoop stress is predictable for specimens loaded by the simple clamping fixture, the relationship was less predictable for actual thermal fit bushings. The variation in results could possibly be due to variable levels of axial stress produced by the differential thermal expansion of the steel and aluminum.
Most of the orbital resonances among the satellites of the major planets are thought to be assembled by differential tidal expansion of their orbits. Why this has not occurred for the Uranus system can be investigated by determining the resonances which would be encountered for various values of Uranus' tidal effective Q. The comparison and the possible escape of Ariel-Umbriel from the 5:3 resonance mean that it is not unreasonable that no orbital resonances are found among these satellites.
The brightness curve of a comet is analyzed in terms of porosity and nature of volatiles in its nucleus. Mobility of pores, densification, phase changes, differential thermal expansion and heat flow into and out of the nucleus are discussed leading to a method for estimating the effective heat conductivity and porosity of the nucleus. The method is applied to comets P/Giacobini-Zinner, P/Halley, P/Kopff, P/Encke, P/Tempel 2 and P/d'Arrest.
Thermal and mechanical properties of seal material used to advantage. Simple sizing tool compresses polychlorotrifluoroethylene seal to smaller diameter. Polymer seal held by aluminum rings, then compressed by differential thermal expansion between seal and rings. Inner diameter of seal reduced by small amount sufficient to enable remachining to specified size.
Smart structures deployed in low earth orbit will be exposed to a hostile environment which will include temperature extremes during each orbit as the platform moves from the day to the night side. The stresses due to thermal cycling may compromise the performance of embedded fiber optic strain sensors because of differential thermal expansion of the fiber and the composite material. The effects of elevated temperature and thermal cycling on the performance of a fiber optic strain sensor embedded in a graphite-epoxy tube have been investigated for temperatures from 65 to 220 F. The results indicate that the fiber optic strain sensor measurements correlate well with conventional resistance strain gages attached to the tube.
A model is described for predicting the wear behavior of whisker reinforced ceramics. The model was successfully applied to a silicon carbide whisker reinforced alumina ceramic composite subjected to sliding contact. The model compares the friction forces on the whiskers due to sliding, which act to pull or push them out of the matrix, to the clamping or compressive forces on the whiskers due to the matrix, which act to hold the whiskers in the composite. At low temperatures, the whiskers are held strongly in the matrix and are fractured into pieces during the wear process along with the matrix. At elevated temperatures differential thermal expansion between the whiskers and matrix can cause loosening of the whiskers and lead to pullout during the wear process and to higher wear. The model, which represents the combination of elastic stress analysis and a friction heating analysis, predicts a transition temperature at which the strength of the whiskers equals the clamping force holding them in the matrix. Above the transition the whiskers are pulled out of the matrix during sliding, and below the transition the whiskers are simply fractured. The existence of the transition gives rise to a dual wear mode or mechanism behavior for this material which was observed in laboratory experiments. The results from this model correlate well with experimentally observed behavior indicating that the model may be useful in obtaining a better understanding of material behavior and in making material improvements.
Proposed rectangular array of photodetectors in imaging spectrometer includes integral filter deposited directly on imaging array which would not become misaligned or misregistered as result of mechanical shock, vibration, or differential thermal expansion. Need for precise alignment and registration of filter cannot be over-emphasized.
A closed-cycle Linde-Hampson nitrogen liquefier was developed incorporating a new, non-clogging, demand flow Joule-Thomson nozzle. The flow area of the nozzle, a tapered annular orifice, is regulated by a very rugged load-sensitive differential thermal expansion scheme and by a manually adjustable micrometer mechanism. Labyrinth flow spoilers within the orifice provide turbulent voids which break up and clear contaminants from the flow. The system's four-stage compressor features sealed, oil-free compression spaces and a very compact nested piston configuration with a minimum of moving parts and drive complexity. The drive mechanism is a rolling Scotch yoke which minimizes piston side forces and seal wear for prolonged operating life. The closed-cycled system is controlled by an innovative load-responsive electronic feedback circuit which further reduces wear and input power.
A model is described for predicting the wear behavior of whisker reinforced ceramics. The model was successfully applied to a silicon carbide whisker reinforced alumina ceramic composite subjected to sliding contact. The model compares the friction forces on the whiskers due to sliding, which act to pull or push them out of the matrix, to the clamping or compressive forces on the whiskers due to the matrix, which act to hold the whiskers in the composite. At low temperatures, the whiskers are held strongly in the matrix and are fractured into pieces during the wear process along with the matrix. At elevated temperatures differential thermal expansion between the whiskers and matrix can cause loosening of the whiskers and lead to pullout during the wear process and to higher wear. The model, which represents the combination of elastic stress analysis and a friction heating analysis, predicts a transition temperature at which the strength of the whiskers equals the clamping force holding them in the matrix. Above the transition the whiskers are pulled out of the matrix during sliding, and below the transition the whiskers are simply fractured. The existence of the transition gives rise to a dual wear mode or mechanism behavior for this material which was observed in laboratory experiments. The results from this model correlate well with experimentally observed behavior indicating that the model may be useful in obtaining a better understanding of material behavior and in making material improvements.
With flexible leaded parts, the solder-joint failure process involves a complex interplay of creep and fatigue mechanisms. To better understand the role of creep in typical multi-hour cyclic loading conditions, a specialized non-linear finite-element creep simulation computer program has been formulated. The numerical algorithm includes the complete part-lead-solder-PWB system, accounting for strain-rate dependence of creep on applied stress and temperature, and the role of the part-lead dimensions and flexibility that determine the total creep deflection (solder strain range) during stress relaxation. The computer program has been used to explore the effects of various solder creep-fatigue parameters such as lead height and stiffness, thermal-cycle test profile, and part/board differential thermal expansion properties. One of the most interesting findings is the strong presence of unidirectional creep-ratcheting that occurs during thermal cycling due to temperature dominated strain-rate effects. To corroborate the solder fatigue model predictions, a number of carefully controlled thermal-cycle tests have been conducted using special bimetallic test boards.
Galileo Regio quadrangle, including most of Galileo Regio, contains two basic geologic units: older dark, furrowed, and heavily cratered material and younger light, grooved, relatively less-cratered material. Dark material dominates, the light material occurring to the W and SW in about five percent of the quadrangle. Dominant structural features, of uncertain origin, are the NW-trending arcuate furrows and associated orthogonal and oblique furrows in the dark material; grooves in the light material are not as well-ordered nor as intensely developed as elsewhere on Ganymede. Fifteen palimpsests, located partly or totally in the quadrangle and representing the period when the crust became sufficiently strong to record impact events, are subdivided into three relative-age classes, as are the numerous impact craters, some of which are dome, moat, and rampart-like. Galileo Regio is believed to have formed when, because of cooling, differentiation, and expansion, the thin, weak, icy lithosphere broke into blocks and light material filled the space between, or overspread those blocks that subsided, or both. Grooves formed in most of the light material and both light and dark material were cratered by impact, the most recent of which created bright-ray craters, the youngest features visible in the quadrangle.
Sapphire-dielectric-ring microwave resonator operating in "whispering-gallery" electromagnetic mode features differential-thermal-expansion design providing temperature compensation for ultrahigh frequency stability. Designed to minimize frequency fluctuations caused by temperature fluctuations at normal temperature equal to or even somewhat greater than temperature of liquid nitrogen. Ancillary equipment needed for operation smaller and less expensive, and liquid nitrogen used as coolant.
This paper describes the fabrication, testing, and analysis of a single axis piezoceramic gimbal. The fabrication process consist of pre-stressing a piezoceramic wafer using a high-temperature thermoplastic polyimide and a metal foil. The differential thermal expansion between the ceramic and metal induces a curvature. The pre-stressed, curved piezoceramic is mounted on a support mechanism and a mirror is attached to the piezoceramic. A plot of gimbal angle versus applied voltage to the piezoceramic is presented. A finite element analysis of the piezoceramic gimbal is described. The predicted gimbal angle versus applied voltage is compared to experimental results.
This paper describes the fabrication, testing, and analysis of a single axis piezoceramic gimbal. The fabrication process consists of pre-stressing a piezoceramic wafer using a high-temperature thermoplastic polyimide and a metal foil. The differential thermal expansion between the ceramic and metal induces a curvature. The pre-stressed, curved piezoceramic is mounted on a support mechanism and a mirror is attached to the piezoceramic. A plot of gimbal angle versus applied voltage to the piezoceramic is presented. A finite element analysis of the piezoceramic gimbal is described. The predicted gimbal angle versus applied voltage is compared to experimental results.
We performed finite element analyses on a model of the Phenolic Impregnated Carbon Ablator (PICA) heatshield from the Stardust sample return capsule (SRC) to predict the thermal stresses in the PICA material during reentry. The heatshield on the Stardust SRC was a 0.83 m sphere cone, fabricated from a single piece of 5.82 cm-thick PICA. The heatshield performed successfully during Earth reentry of the SRC in January 2006. Material response analyses of the full, axisymmetric PICA heatshield were run using the Two-Dimensional Implicit Ablation, Pyrolysis, and Thermal Response Program (TITAN). Peak surface temperatures were predicted to be 3385K, while the temperature at the PICA backface remained at the estimated initial cold-soak temperature of 278K. Surface recession and temperature distribution results from TITAN, at several points in the reentry trajectory, were mapped onto an axisymmetric finite element model of the heatshield. We used the finite element model to predict the thermal stresses in the PICA from differential thermal expansion. The predicted peak compressive stress in the PICA heatshield was 1.38 MPa. Although this level of stress exceeded the chosen design limit for compressive stresses in PICA tiles for the design of the Orion crew exploration vehicle heatshield, the Stardust heatshield exhibited no obvious mechanical failures from thermal stress. The analyses of the Stardust heatshield were used to assess and adjust the level of conservatism in the finite element analyses in support of the Orion heatshield design.