Rapid Quantification of 237 U Specific Activity for Nuclear Forensics

Valdovinos, Hector Francisco; Glennon, Kevin James; Parsons-Davis, Tashi; Shusterman, Jennifer; Servis, Anna G.; Moody, Kenton J.; Gharibyan, Narek

doi:10.1021/acs.iecr.3c03247

DOE OSTI · 2281468

Rapid Quantification of 237 U Specific Activity for Nuclear Forensics

Valdovinos, Hector Francisco·Glennon, Kevin James·Parsons-Davis, Tashi·Shusterman, Jennifer·Servis, Anna G.·Moody, Kenton J.·Gharibyan, Narek

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Abstract

In the event of an unattributed nuclear explosion, rapid assessment of the short-lived uranium isotope activity and mass can provide valuable information for subsequent forensic analysis. Rapid analysis in the field is enabled by using microfluidic chemistry and deployable instrumentation. Here, this work presents a flow chemistry system, controlled in LabVIEW, that integrates three functionalities: (1) selective extraction of uranium from the sample matrix via a 3D-printed supported liquid membrane module; (2) UV–visible absorbance spectrophotometry to measure the total uranium concentration in the strip flow; and (3) a portable CdTe γ-ray spectrometer coupled to a 3D-printed flow cell to measure 237 U activity concentration in the strip solution. The system was calibrated using standard solutions, and its functionality was demonstrated using a solution of depleted uranium spiked with 237 U. Uranium concentrations of 40–5000 μg/mL were directly quantified online using a 100 mm optical flow cell, while concentrations of 0.5–10 μg/mL were quantified online using a colorimetric reagent. The mass concentration measurement takes approximately 60 min while the activity concentration via γ-ray spectrometry varies depending on the activity of 237 U, with 1 kBq/mL requiring about 30 min of acquisition time to obtain <10% uncertainty at 1σ. This platform provides a fieldable approach for quantifying uranium mass and radioactivity relevant to postdetonation nuclear debris.

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37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY 38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY 42 ENGINEERING absorption animal feed calibration reagents uranium

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Valdovinos, Hector Francisco, Glennon, Kevin James, Parsons-Davis, Tashi, Shusterman, Jennifer, Servis, Anna G., Moody, Kenton J., Gharibyan, Narek. 2023-12-19. Rapid Quantification of 237 U Specific Activity for Nuclear Forensics. https://doi.org/10.1021/acs.iecr.3c03247

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